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1999 | OriginalPaper | Buchkapitel

New insight into propene polymerization promoted by heterogeneous Ziegler-Natta catalysts

verfasst von : Vincenzo Busico, Roberta Cipullo, Guglielmo Monaco, Giovanni Talarico, Michele Vacatello, John C. Chadwick, Anna Laura Segre, Olof Sudmeijer

Erschienen in: Metalorganic Catalysts for Synthesis and Polymerization

Verlag: Springer Berlin Heidelberg

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The configurational analysis of polypropylenes made with coordination catalysts has received a tremendous impulse by the recent application of high-field 13C NMR techniques. In particular, unprecedented determinations of stereosequence distribution at heptad/nonad level have made more realistic and sophisticated models of chain propagation applicable for the first time in a statistically significant manner. In this presentation, the most recent applications to «high-yield» MgCl2-supported Ziegler-Natta catalysts are illustrated

Metadaten
Titel
New insight into propene polymerization promoted by heterogeneous Ziegler-Natta catalysts
verfasst von
Vincenzo Busico
Roberta Cipullo
Guglielmo Monaco
Giovanni Talarico
Michele Vacatello
John C. Chadwick
Anna Laura Segre
Olof Sudmeijer
Copyright-Jahr
1999
Verlag
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-642-60178-1_7

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