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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 18/2019

22.08.2019

Ni(OH)2@hollow carbon spheres/sulfur composites as cathode materials for high-performance Li–S batteries

verfasst von: Jinguo Zhao

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 18/2019

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Abstract

Hollow carbon spheres (HCS) with Ni(OH)2 nanoparticles loaded on their inner walls (NH@HCS) have been designed as sulfur host materials for the lithium–sulfur (Li–S) battery. The SiO2/Ni(OH)2@PDA composite is firstly synthesized by depositing Ni(OH)2 on silica spheres and then coating carbon precursor of polydopamine (PDA) shell. Then, the process of carbonization and KOH etching transforms the PDA into carbon and removes the silica core, respectively. Finally, sulfur is impregnated into the NH@HCS by heat treatment to obtain NH@HCS–S composites. Through experimental studies, it is demonstrated that the hybrid sulfur host formed by carbon spheres and hydroxide nickel hydroxide embraces high electronic conductivity as well as strong physical absorption and chemical affinity.
Vorheriger Artikel Photoluminescence properties of single component double-color-emitting phosphor Ca5(PO4)3Br:Eu2+,Mn2+ for white LEDs
Nächster Artikel Poly(vinyl pyrrolidone)-assisted hydrothermal synthesis of Pb(Zr0.52Ti0.48)O3 nanocrystals

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Literatur
1.
A. Manthiram, S.H. Chung, C. Zu, Lithium-sulfur batteries: progress and prospects. Adv. Mater. 27, 1980–2006 (2015)CrossRef
2.
H. Wu, J. Geng, H. Ge, Z. Guo, Y. Wang, G. Zheng, Egg-derived mesoporous carbon microspheres as bifunctional oxygen evolution and oxygen reduction electrocatalysts. Adv. Energy Mater. 6(20), 1600794 (2016)CrossRef
3.
Y. Zhong, S. Wang, Y. Sha, M. Liu, R. Cai, L. Li, Z. Shao, Trapping sulfur in hierarchically porous, hollow indented carbon spheres: a high-performance cathode for lithium–sulfur batteries. J. Mater. Chem. A 4, 9526–9535 (2016)CrossRef
4.
G. Zheng, Q. Zhang, J.J. Cha, Y. Yang, W. Li, Z.W. Seh, Y. Cui, Amphiphilic surface modification of hollow carbon nanofibers for improved cycle life of lithium sulfur batteries. Nano Lett. 13, 1265–1270 (2013)CrossRef
5.
X. Ji, K.T. Lee, L.F. Nazar, A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nat. Mater. 8, 500–506 (2009)CrossRef
6.
B. Zhang, X. Qin, G.R. Li, X.P. Gao, Enhancement of long stability of sulfur cathode by encapsulating sulfur into micropores of carbon spheres. Energy Environ. Sci. 3, 1531 (2010)CrossRef
7.
S.Y. Yuan, J.L. Bao, L.N. Wang, Y.Y. Xia, D.G. Truhlar, Y.G. Wang, Graphene-supported nitrogen and boron rich carbon layer for improved performance of lithium-sulfur batteries due to enhanced chemisorption of lithium polysulfides. Adv. Energy Mater. 6, 1501733 (2016)CrossRef
8.
P.G. Bruce, S.A. Freunberger, L.J. Hardwick, J.M. Tarascon, Li-O2 and Li-S batteries with high energy storage. Nat. Mater. 11, 19 (2012)CrossRef
9.
H.L. Wu, L. Xia, J. Ren, Q.J. Zheng, C.G. Xu, D.M. Lin, A high-efficiency N/P co-doped graphene/CNT@ porous carbon hybrid matrix as cathode host for high performance lithium-sulfur batteries. J. Mater. Chem. A 5, 20458–20472 (2017)CrossRef
10.
Z. Yuan, H.J. Peng, T.Z. Hou, J.Q. Huang, C.M. Chen, D.W. Wang, X.B. Cheng, F. Wei, Q. Zhang, Powering lithium-sulfur battery performance by propelling polysulfide redox at sulfiphilic hosts. Nano Lett. 16, 519–527 (2016)CrossRef
11.
X. Liang, C. Hart, Q. Pang, A. Garsuch, T. Weiss, L.F. Nazar, A highly efficient polysulfide mediator for lithium-sulfur batteries. Nat. Commun. 6, 5682 (2015)CrossRef
12.
H. Zhang, L. Zhou, X. Huang, H. Song, C. Yu, Encapsulation of selenium sulfide in double-layered hollow carbon spheres as advanced electrode material for lithium storage. Nano Res. 9, 3725–3734 (2016)CrossRef
13.
S. Niu, W. Lv, C. Zhang, Y.T. Shi, J.F. Zhao, B.H. Li, Q.H. Yang, F.Y. Kang, One-pot self-assembly of graphene/carbon nanotube/sulfur hybrid with three dimensionally interconnected structure for lithium–sulfur batteries. J. Power Sources 295, 182–189 (2015)CrossRef
14.
K. Xi, P.R. Kidambi, R. Chen, C.L. Gao, X.Y. Peng, C. Ducoti, S. Hofmann, R.V. Kumar, Binder free three-dimensional sulphur/few-layer graphene foam cathode with enhanced high-rate capability for rechargeable 24 lithium sulphur batteries. Nanoscale 6, 5746–5753 (2014)CrossRef
15.
L. Miao, W. Wang, K. Yuan, Y. Yang, A. Wang, A lithium–sulfur cathode with high sulfur loading and high capacity per area: a binder-free carbon fiber cloth–sulfur material. Chem. Commun. 50, 13231 (2014)CrossRef
16.
Y. Wei, Y. Tao, Z. Kong, L. Liu, J. Wang, W. Qiao, L. Ling, D. Long, Unique electrochemical behavior of heterocyclic selenium–sulfur cathode materials in ether-based electrolytes for rechargeable lithium batteries. Energy Storage Mater. 5, 171–179 (2016)CrossRef
17.
H. Wang, C. Zhang, Z. Chen, H.K. Liu, Z. Guo, Large-scale synthesis of ordered mesoporous carbon fiber and its application as cathode material for lithium-sulfur batteries. Carbon 81, 782–787 (2015)CrossRef
18.
C. Zhang, H.B. Wu, C. Yuan, Z. Guo, X.W. Lou, Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries. Angew. Chem. Int. Ed. 124, 9730 (2012)CrossRef
19.
Y.C. Yan, T.Y. Lei, Y. Jiao, C.Y. Wu, J. Xiong, TiO2 nanowire array as a polar absorber for high-performance lithium-sulfur batteries. Electrochim. Acta 264, 20–25 (2018)CrossRef
20.
Y. Zhao, W. Zhu, G.Z. Chen, E.J. Cairns, Polypyrrole/TiO2 nanotube arrays with coaxial heterogeneous structure as sulfur hosts for lithium sulfur batteries. J. Power Sources 327, 447–456 (2016)CrossRef
21.
J. Yao, T. Mei, Z.Q. Cui, Z.H. Yu, K. Xu, X.B. Wang, Hollow carbon spheres with TiO2 encapsulated sulfur and polysulfides for long-cycle lithium-sulfur batteries. Chem. Eng. J. 330, 644–650 (2017)CrossRef
22.
B. Ding, L.F. Shen, G.Y. Xu, P. Nie, X.G. Zhang, Encapsulating sulfur into mesoporous TiO2 host as a high performance cathode for lithium–sulfur battery. Electrochim. Acta 107, 78–84 (2013)CrossRef
23.
J.Y. Hwang, H.M. Kim, S.K. Lee, J.H. Lee, A. Abouimrane, M.A. Khaleel, I. Belharouak, A. Manthiram, Y.K. Sun, High-energy, high-rate, lithium-sulfur batteries: synergetic effect of hollow TiO2-webbed carbon nanotubes and a dual functional carbon-paper interlayer. Adv. Energy Mater. 6, 1501480 (2016)CrossRef
24.
H. Tang, S.S. Yao, S.K. Xue, M.Q. Liu, L.L. Chen, M.X. Jing, X.Q. Shen, T.B. Li, K.S. Xiao, S.B. Qin, In-situ synthesis of carbon@Ti4O7 non-woven fabric as a multi-functional interlayer for excellent lithium-sulfur battery. Electrochim. Acta 263, 158–167 (2018)CrossRef
25.
H. Wei, E.F. Rodriguez, A.S. Best, A.F. Hollenkamp, D.H. Chen, R.A. Caruso, Chemical bonding and physical trapping of sulfur in mesoporous magnéli Ti4O7 microspheres for high-performance Li–S battery. Adv. Energy Mater. 7, 1601616 (2017)CrossRef
26.
Y.J. Zhang, S.S. Yao, R.Y. Zhuang, K.J. Luan, X.Y. Qian, J. Xiang, X.Q. Shen, T.B. Li, K.S. Xiao, S.B. Qin, Shape-controlled synthesis of Ti4O7 nanostructures under solvothermal-assisted heat treatment and its application in lithium-sulfur batteries. J. Alloys Compd. 729, 1136–1144 (2017)CrossRef
27.
Z. Li, J.T. Zhang, X.W. Lou, Hollow carbon nanofibers filled with MnO2 nanosheets as efficient sulfur hosts for lithium–sulfur batterie. Angew. Chem. Int. Ed. 54, 12886–12890 (2015)CrossRef
28.
M.F. Chen, Q. Lu, S.X. Jiang, C. Huang, X.Y. Wang, B. Wu, K.X. Xiang, Y.T. Wu, MnO2 nanosheets grown on the internal/external surface of N-doped hollow porous carbon nanospheres as the sulfur host of advanced lithium-sulfur batteries. Chem. Eng. J. 335, 831–842 (2018)CrossRef
29.
L. Li, Z.A. Hu, N. An, Y.Y. Yang, Z.M. Li, H.Y. Wu, Facile synthesis of MnO2/CNTs composite for supercapacitor electrodes with long cycle stability. J. Phys. Chem. C 118, 22865–22872 (2014)CrossRef
30.
X.G. Han, Y.H. Xu, X.Y. Chen, Y.C. Chen, N. Weadock, J.Y. Wan, H.L. Zhu, Y.L. Liu, H.Q. Li, G. Rubloff, C.S. Wang, L.B. Hu, Reactivation of dissolved polysulfides in Li-S batteries based on atomic layer deposition of Al2O3 in nanoporous carbon cloth. Nano Energy 2, 1197–1206 (2013)CrossRef
31.
J.S. Chen, Y. Gui, D.J. Blackwood, A versatile ionic liquid-assisted approach to synthesize hierarchical structures of β-Ni(OH)2 nanosheets for high performance pseudocapacitor. Electrochim. Acta 188, 863–870 (2016)CrossRef
32.
Z.W. Seh, W.Y. Li, J.J. Cha, G.Y. Zheng, Y. Yang, M.T. McDowell, P.C. Hsu, Y. Cui, Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries. Nat. Commun. 4, 1331–1337 (2013)CrossRef
33.
S. Wei, L. Ma, K.E. Hendrickson, Z. Tu, L.A. Archer, Metal-sulfur battery cathodes based on PAN-sulfur composites. J. Am. Chem. Soc. 137, 12143–12152 (2015)CrossRef
34.
X.Q. Niu, X.L. Wang, D. Xie, D.H. Wang, Y.D. Zhang, Y. Li, T. Yu, J.P. Tu, Nickel hydroxide-modified sulfur/carbon composite as a high performance cathode material for lithium sulfur battery. ACS Appl. Mater. Int. 7, 16715–16722 (2015)CrossRef
35.
L.M. Jin, F. He, W.L. Cai, J.X. Huang, B.H. Liu, Z.P. Li, Preparation, characterization and application of modified macroporous carbon with CoeN site for long-life lithium-sulfur battery. J. Power Sources 328, 536–542 (2016)CrossRef
36.
J. Li, J.Q. Guo, L. Zeng, Y.J. Huang, R.F. Peng, Improving lithium–sulfur battery performance by using ternary hybrid cathode material. RSC Adv. 6, 26630–26636 (2016)CrossRef
37.
X. Song, T. Gao, S.Q. Wang, Y. Bao, G.P. Chen, L.X. Ding, H.H. Wang, Free-standing sulfur host based on titanium-dioxide-modified porouscarbon nanofibers for lithium-sulfur batteries. J. Power Sources 356, 172–180 (2017)CrossRef
Metadaten
Titel
Ni(OH)2@hollow carbon spheres/sulfur composites as cathode materials for high-performance Li–S batteries
verfasst von
Jinguo Zhao
Publikationsdatum
22.08.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 18/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02062-w

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