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05.06.2020 | Original Research

Novel Brønsted–Lewis acidic di-cationic ionic liquid for efficient conversion carbohydrate to platform compound

verfasst von: Weihao Guo, Minghui Zuo, Jian Zhao, Chao Li, Qiaoliang Xu, Chunzhao Xu, Hongfeng Wu, Zhizhong Sun, Wenyi Chu

Erschienen in: Cellulose | Ausgabe 12/2020

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Abstract

A series of Brønsted–Lewis acidic di-cationic ionic liquids (BLAILs) were synthesized and the catalytic properties of glucose conversion to 5-hydroxymethylfurfural (5-HMF) were investigated. The experimental results showed that the ionic liquid with aluminum trichloride as Lewis acid anion (BLAIL-5) exhibited good catalytic performance. Under the best reaction conditions, the yield of the glucose conversion into 5-HMF and 5-EMF were 71% and 66%, respectively. In addition, the yield of cellulose to 5-HMF is 41%. The optimized catalytic system could be reused for 5 times without significant catalytic performance loss. In addition, the mechanism of BLAIL-5 promoting glucose conversion to 5-HMF was studied by density functional theory calculation (DFT).

Vorheriger Artikel Rapid allylation of cellulose without heating in tetra-n-butylphosphonium hydroxide aqueous solution

Nächster Artikel Facile fabrication of durable acaricidal nanofibers effective against Dermatophagoides farinae via emulsion electrospinning of eugenol-encapsulated cellulose acetate

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Titel: Novel Brønsted–Lewis acidic di-cationic ionic liquid for efficient conversion carbohydrate to platform compound
verfasst von: Weihao Guo
Minghui Zuo
Jian Zhao
Chao Li
Qiaoliang Xu
Chunzhao Xu
Hongfeng Wu
Zhizhong Sun
Wenyi Chu
Publikationsdatum: 05.06.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 12/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03275-7

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