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Erschienen in: Journal of Materials Science: Materials in Electronics 17/2020

21.07.2020

Novel color tunable phosphors NaYGeO4: Tm3+, Tb3+, Eu3+ for ultraviolet excited white LEDs with good thermal stability

verfasst von: Wenyu Zhao, Xiaoyan Feng, Bin Fan

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 17/2020

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Abstract

Single-phased phosphors NaYGeO4: Eu3+, Tb3+, Tm3+ were synthesized by a high temperature solid-state reaction. Upon the excitation of 300–325 nm, the NaYGeO4: Eu3+, Tb3+, Tm3+ phosphors emit combining blue, green and red lights, coming from the characteristic emissions of Tm3+, Tb3+, Eu3+, respectively. Mechanisms of concentration quenching and energy transfer from Tb3+ to Eu3+ have been investigated. The emission color can be adjusted by tuning the doping contents appropriately. The optimal NaYGeO4: 0.12Eu3+, 0.07Tb3+, 0.03Tm3+ phosphor emits a warm white light with chromaticity coordinate of (0.3521, 0.3761), correlated color temperature of 4842 K, activation energy for thermal quenching effect of 0.213–0.225 eV and internal quantum efficiency of 40.2%. The obtained properties indicate that NaYGeO4: Eu3+, Tb3+, Tm3+ phosphor might be a promising single-phased white light emitting phosphor for UV-pumped white-LED.

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Metadaten
Titel
Novel color tunable phosphors NaYGeO4: Tm3+, Tb3+, Eu3+ for ultraviolet excited white LEDs with good thermal stability
verfasst von
Wenyu Zhao
Xiaoyan Feng
Bin Fan
Publikationsdatum
21.07.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 17/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04003-4

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