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Clean Technologies and Environmental Policy

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23.02.2018 | Original Paper

Novel mesoporous Fe₃O₄/SiO₂/CTAB–SiO₂ as an effective adsorbent for the removal of amoxicillin and tetracycline from water

verfasst von: Raziyeh Zandipak, Soheil Sobhanardakani

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 4/2018

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Abstract

The current study was carried out to investigate the efficiency of using magnetic mesoporous of cetyltrimethylammonium bromide-functionalized silica-coated magnetite for removing amoxicillin (AMX) and tetracycline (TC) from tap water, river water, and medical wastewater as real samples. The properties of the synthesized adsorbent were characterized through transmission electron microscopy (TEM), scanning electron microscopy, X-ray diffraction spectrometry, Fourier transform infrared spectroscopy, vibrating sample magnetometry, pH_pzc, and also Brunauer, Emmett, and Teller (BET) methods. The BET surface area and the average diameter of mesoporous Fe₃O₄/SiO₂/CTAB–SiO₂ in accordance with TEM were 157.8 m² g⁻¹ and around 55 nm, respectively. In batch tests, the adsorption parameters, including the initial concentration, contact time, pH of solution, ionic strength, and adsorbent dose, were analysed. The experimental adsorption data were modelled using different classical and recently developed models. According to the results, the maximum adsorption capacities of AMX and TC on mesoporous Fe₃O₄/SiO₂/CTAB–SiO₂ were found to be 362.66 and 220.70 mg g⁻¹, respectively. Also, the results indicated that AMX and TC loaded on the adsorbent could be easily desorbed with 0.1 mol L⁻¹ HNO₃⁺ acetonitrile (1:1, v/v) and the adsorbent showed good reusability for the adsorption of the drugs studied.

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Ahmadi M, Madrakian T, Afkhami A (2016) Solid phase extraction of amoxicillin using dibenzo-18-crown-6 modified magnetic-multiwalled carbon nanotubes prior to its spectrophotometric determination. Talanta 148:122–128CrossRef

Azizian S (2004) Kinetic models of sorption: a theoretical analysis. J Colloid Interface Sci 276:47–52CrossRef

Azizian S, Haerifar M, Basiri-Parsa J (2007) Extended geometric method: a simple approach to derive adsorption rate constants of Langmuir–Freundlich kinetics. Chemosphere 68:2040–2046CrossRef

Bao S, Tang L, Li K, Ning P, Peng J, Guo H, Zhu T, Liu Y (2016) Highly selective removal of Zn(II) ion from hot-dip galvanizing pickling waste with amino-functionalized Fe₃O₄@SiO₂ magnetic nano-adsorbent. J Colloid Interface Sci 462:235–242CrossRef

Brouers F, Sotolongo O, Marquez F, Pirard JP (2005) Microporous and heterogeneous surface adsorption isotherms arising from Levy distributions. Phys A Stat Mech Appl 349:271–282CrossRef

Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319CrossRef

Cao D, Jin X, Gan L, Wang T, Chen Z (2016) Removal of phosphate using iron oxide nanoparticles synthesized by eucalyptus leaf extract in the presence of CTAB surfactant. Chemosphere 159:23–31CrossRef

Chayid MA, Ahmed MJ (2015) Amoxicillin adsorption on microwave prepared activated carbon from Arundo donax Linn: isotherms, kinetics, and thermodynamics studies. J Environ Chem Eng 3:1592–1601CrossRef

Chen Y, Wang F, Duan L, Yang H, Gao J (2016) Tetracycline adsorption onto rice husk ash, an agricultural waste: its kinetic and thermodynamic studies. J Mol Liq 222:487–494CrossRef

Choina J, Bagabas A, Fischer C, Flechsig GU, Kosslick H, Alshammari A, Schulz A (2015) The influence of the textural properties of ZnO nanoparticles on adsorption and photocatalytic remediation of water from pharmaceuticals. Catal Today 241:47–54CrossRef

Dordio A, Miranda S, Ramalho JP, Carvalho AP (2017) Mechanisms of removal of three widespread pharmaceuticals by two clay materials. J Hazard Mater 323(A):575–583CrossRef

Freundlich H, Heller W (1939) The adsorption of cis- and trans-azobenzene. J Am Chem Soc 61:2228–2230CrossRef

Guo J, Chen S, Liu L, Li B, Yang P, Zhang L, Feng Y (2012) Adsorption of dye from wastewater using chitosan–CTAB modified bentonites. J Colloid Interface Sci 382:61–66CrossRef

Haerifar M, Azizian S (2012) Fractal-like adsorption kinetics at the solid/solution interface. J Phys Chem C 116:13111–13119CrossRef

Haerifar M, Azizian S (2013) An exponential kinetic model for adsorption at solid/solution interface. Chem Eng J 215:65–71CrossRef

Hu D, Wang L (2016) Adsorption of amoxicillin onto quaternized cellulose from flax noil: kinetic, equilibrium and thermodynamic study. J Taiwan Inst Chem Eng 64:227–234CrossRef

Kerkez-Kuyumcu Ö, Bayazit ŞS, Salam MA (2016) Antibiotic amoxicillin removal from aqueous solution using magnetically modified graphene nanoplatelets. J Ind Eng Chem 36:198–205CrossRef

Lai L, Xie Q, Chi L, Gu W, Wu D (2016) Adsorption of phosphate from water by easily separable Fe₃O₄@SiO₂ core/shell magnetic nanoparticles functionalized with hydrous lanthanum oxide. J Colloid Interface Sci 465:76–82CrossRef

Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403CrossRef

Mane VS, Mall ID, Srivastava VC (2007) Kinetic and equilibrium isotherm studies for the adsorptive removal of Brilliant Green dye from aqueous solution by rice husk ash. J Environ Manage 84:390–400CrossRef

Marczewski A (2010) Application of mixed order rate equations to adsorption of methylene blue on mesoporous carbons. Appl Surf Sci 256:5145–5152CrossRef

McKie MJ, Andrews SA, Andrews RC (2016) Conventional drinking water treatment and direct biofiltration for the removal of pharmaceuticals and artificial sweeteners: a pilot-scale approach. Sci Total Environ 544:10–17CrossRef

Moussavi G, Alahabadi A, Yaghmaeian K, Eskandari M (2013) Preparation, characterization and adsorption potential of the NH₄ Cl-induced activated carbon for the removal of amoxicillin antibiotic from water. Chem Eng J 217:119–128CrossRef

Ou J, Mei M, Xu X (2016) Magnetic adsorbent constructed from the loading of amino functionalized Fe₃O₄ on coordination complex modified polyoxometalates nanoparticle and its tetracycline adsorption removal property study. J Solid State Chem 238:182–188CrossRef

Plazinski W, Rudzinski W, Plazinska A (2009) Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Adv Colloid Interface Sci 152:2–13CrossRef

Sobhanardakani S, Zandipak R (2015) 2, 4-Dinitrophenylhydrazine functionalized sodium dodecyl sulfate-coated magnetite nanoparticles for effective removal of Cd(II) and Ni(II) ions from water samples. Environ Monit Assess 187:1–14CrossRef

Sobhanardakani S, Zandipak R (2017) Synthesis and application of TiO₂/SiO₂/Fe₃O₄ nanoparticles as novel adsorbent for removal of Cd(II), Hg(II) and Ni(II) ions from water samples. Clean Technol Environ Policy. https://doi.org/10.1007/s10098-017-1374-5

Sobhanardakani S, Zandipak R, Sahraei R (2013) Removal of Janus Green dye from aqueous solutions using oxidized multi-walled carbon nanotubes. Toxicol Environ Chem 95:909–918CrossRef

Sobhanardakani S, Farmany A, Abbasi S (2014) A new modified multiwalled carbon nanotube paste electrode for quantification of tin in fruit juice and bottled water samples. J Ind Eng Chem 20(5):3214–3216CrossRef

Temkin M, Pyzhev V (1940) Recent modifications to Langmuir isotherms. Acta Physiochim URSS 12:217–225

Wang J, Zheng S, Shao Y, Liu J, Xu Z, Zhu D (2010) Amino-functionalized Fe₃O₄@SiO₂ core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal. J Colloid Interface Sci 349:293–299CrossRef

Zandipak R, Sobhanardakani S (2016) Synthesis of NiFe₂O₄ nanoparticles for removal of anionic dyes from aqueous solution. Desalination Water Treat 57:11348–11360CrossRef

Zhang S, Zhang Y, Liu J, Xu Q, Xiao H, WangX XuH, Zhou J (2013) Thiol modified Fe₃O₄@SiO₂ as a robust, high effective, and recycling magnetic sorbent for mercury removal. Chem Eng J 226:30–38CrossRef

Zhang S, Dong Y, Yang Z, Yang W, Wu J, Dong C (2016) Adsorption of pharmaceuticals on chitosan-based magnetic composite particles with core-brush topology. Chem Eng J 304:325–334CrossRef

Titel: Novel mesoporous Fe3O4/SiO2/CTAB–SiO2 as an effective adsorbent for the removal of amoxicillin and tetracycline from water
verfasst von: Raziyeh Zandipak
Soheil Sobhanardakani
Publikationsdatum: 23.02.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Clean Technologies and Environmental Policy / Ausgabe 4/2018
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI: https://doi.org/10.1007/s10098-018-1507-5

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