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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 13/2020

18.05.2020

Novel synthesis of poly(2-acryloyloxyethyl ferrocenecarboxylate) as quasi-reversible redox-active gel polymer electrolytes

verfasst von: Zhenguo Gao, Jiaoqiang Zhang, Ke Li, Di Lan, Zehao Zhao, Kaichang Kou

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 13/2020

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Abstract

In this research, the electrochemical behavior of poly(2-acryloyloxyethyl ferrocenecarboxylate) (PAEFc) synthesized via an atom transfer radical polymerization (ATRP) strategy was investigated in a series of tetrabutylammonium perchlorate (TBAP)/acetonitrile vs. Ag/AgNO3 system. In comparison, series of PAEFc electrolyte with specific molecular weight and depositing concentration were analyzed via cyclic voltammetry (CV) method. Furthermore, chronocoulometry (CC) technology has been employed on the dynamic electron/mass transfer mechanism and the determination of kinetic parameters (diffusion coefficients, reaction rate constant, etc.). Finally, it is demonstrated that anodic and cathodic process of PAEFc was controlled by diffusion and adsorption–diffusion, respectively. Meanwhile, the kinetic parameters of the typical quasi-reversible redox process were obtained, of which the apparent activation energy (Ea) and pre-exponential factor (A) were 121.38 kJ mol−1 4.28 × 1018 s−1, respectively.
Vorheriger Artikel Influence of SiO2 nanoparticles on morphology, optical, and conductivity properties of Poly (ethylene oxide)
Nächster Artikel Study of low temperature-dependent structural, dielectric, and ferroelectric properties of BaxSr(1−x)TiO3 (x = 0.5, 0.6, 0.7) ceramics

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Metadaten
Titel
Novel synthesis of poly(2-acryloyloxyethyl ferrocenecarboxylate) as quasi-reversible redox-active gel polymer electrolytes
verfasst von
Zhenguo Gao
Jiaoqiang Zhang
Ke Li
Di Lan
Zehao Zhao
Kaichang Kou
Publikationsdatum
18.05.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 13/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03592-4

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