Due to the strongly coupled THMC processes that occur in fill mass, the consolidation behavior of CPB in a slurry state is a very complex process compared to that of conventional geomaterials, such as natural soils. A multiphysics model for the consolidation behavior of CPB must satisfy the principle of pore space continuity (Cui and Fall
2016a), which requires that the pore space changes associated with the CPB skeleton and solid phase must be consistent with the volume changes in the pore water and pore air. Hence, based on the principle of pore space continuity, a consolidation equation based on multiphysics can be derived as follows and is elaborated in detail in Cui and Fall (
2015a,
2016a):
$$\begin{aligned} \left\{ {\left[ {SP_{w} + \left( {1 - S} \right)P_{a} } \right]\frac{1 - 2\upsilon }{E}\frac{{\partial \alpha_{Biot} }}{\partial \xi } - \left\{ {\frac{{\sigma + \alpha_{Biot} \left[ {SP_{w} + \left( {1 - S} \right)P_{a} } \right]}}{E}} \right\}\left\{ {\frac{{9\left[ {1 - 2\upsilon } \right]}}{E}\frac{\partial E}{\partial \xi } + 18\frac{\partial \upsilon }{\partial \xi }} \right\}} \right. \hfill \\ \left. { - \alpha_{Biot} \left( {P_{a} - P_{w} } \right)\frac{1 - 2\upsilon }{E}\left\{ {\left[ {1 - S_{e} \left( {P_{w} ,P_{a} ,\xi } \right)} \right]\frac{{\partial \theta_{r} }}{\partial \xi } + \left( {n - \theta_{r} } \right)\frac{{\partial S_{e} }}{\partial \xi }} \right\} - \frac{{{{\left( {v_{ch - w} + v_{ab - w} } \right)R_{{{{n - w} \mathord{\left/ {\vphantom {{n - w} {hc}}} \right. \kern-0pt} {hc}}}} } \mathord{\left/ {\vphantom {{\left( {v_{ch - w} + v_{ab - w} } \right)R_{{{{n - w} \mathord{\left/ {\vphantom {{n - w} {hc}}} \right. \kern-0pt} {hc}}}} } {\left( {1 - n} \right)}}} \right. \kern-0pt} {\left( {1 - n} \right)}}}}{{\left( {{w \mathord{\left/ {\vphantom {w c}} \right. \kern-0pt} c}} \right)v_{w} + v_{c} + \left( {{1 \mathord{\left/ {\vphantom {1 {C_{m} }}} \right. \kern-0pt} {C_{m} }} - 1} \right)v_{tailings} }}} \right\}\frac{\partial \xi }{\partial t} \hfill \\ + \frac{1 - 2\upsilon }{E}\frac{\partial \sigma }{\partial t} + \alpha_{Biot} \frac{1 - 2\upsilon }{E}\left\{ {S - \left( {P_{a} - P_{w} } \right)\left( {n - \theta_{r} } \right)\frac{{\partial S_{e} }}{{\partial P_{w} }}} \right\}\frac{{\partial P_{w} }}{\partial t} + \frac{{\partial \lambda_{p} }}{\partial t}\frac{{\partial Q_{CTB} }}{{\partial I_{1} }} + \alpha_{Ts} \frac{\partial T}{\partial t} \hfill \\ + \alpha_{Biot} \frac{1 - 2\upsilon }{E}\left\{ {\left( {1 - S} \right) - \left( {P_{a} - P_{w} } \right)\left( {n - \theta_{r} } \right)\frac{{\partial S_{e} }}{{\partial P_{a} }}} \right\}\frac{{\partial P_{a} }}{\partial t} \hfill \\ = - \left\{ {\left( {1 - n} \right) + \alpha_{Biot} \left( {P_{a} - P_{w} } \right)\frac{1 - 2\upsilon }{{n^{2} E}}\left[ {n\left( {1 - n} \right)S_{e} + \left( {1 - S_{e} } \right)\theta_{r} } \right]} \right\}\frac{\partial n}{\partial t} \hfill \\ \end{aligned}$$
(1)
where
\(S\) is the degree of saturation;
\(P_{w}\) and
\(P_{a}\) denote the PWP and pore-air pressure, respectively;
\(\upsilon\) and
\(E\) denote the Poisson’s ratio and elastic modulus, respectively;
\(\alpha_{Biot}\) is the Biot’s coefficient;
\(\xi\) is the degree of binder hydration;
\(\sigma\) is a total stress tensor;
\(S_{e}\) is the effective degree of saturation;
\(\theta_{r}\) is the residual water content;
\(n\) refers to the CPB porosity;
\(v_{w}\),
\(v_{ch - w}\),
\(v_{ab - w}\),
\(v_{tailings}\) and
\(v_{c}\) denote the specific volume of the capillary water, chemically consumed water, physically adsorbed water, tailings and cement respectively;
\(R_{n - w/hc}\) means the mass ratio of the chemically consumed water and hydrated cement;
\({w \mathord{\left/ {\vphantom {w c}} \right. \kern-0pt} c}\) is the water to cement ratio;
\(C_{m}\) is the binder content;
\(t\) refers to the elapsed time;
\(\lambda_{p}\) denotes a non-negative plastic multiplier;
\(Q_{CTB}\) is a plastic potential function;
\(I_{1}\) represents the first stress invariant; and
\(\alpha_{Ts}\) refers to a coefficient of the thermal expansion of the solid phase in the CPB. The determination of the model parameters mentioned above is given in Cui and Fall (
2015a,
2016a).
As demonstrated in the consolidation model (i.e., Eq. (
1)), the chemical process is incorporated into the volume changes in CPB through the variable
\(\xi\), namely, the degree of binder hydration. To characterize the progress of the hydration reaction in CPB, the following exponential equation proposed by Schindler and Folliard (
2003) is adopted:
$$\xi \left( t \right) = \left( {\frac{1.031 \cdot w/c}{0.194 + w/c} + 0.5 \cdot X_{FA} + 0.30 \cdot X_{slag} } \right) \cdot \exp \left\{ { - \left\{ {{\tau \mathord{\left/ {\vphantom {\tau {\int\limits_{0}^{t} {\exp \left[ {\frac{{E_{a} }}{R}\left( {\frac{1}{{T_{r} }} - \frac{1}{T}} \right)} \right]} dt}}} \right. \kern-0pt} {\int\limits_{0}^{t} {\exp \left[ {\frac{{E_{a} }}{R}\left( {\frac{1}{{T_{r} }} - \frac{1}{T}} \right)} \right]} dt}}} \right\}^{\beta } } \right\}$$
(2)
with
$$E_{a} \left( T \right) = \left\{ \begin{aligned} 33,500 + 1,470 \times \left( {293.15 - T} \right)\quad T < 293.15K \\ 33,500 \, \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad T \ge 293.15K \hfill \\ \end{aligned} \right.$$
where
\(\tau\) and
\(\beta\) respectively represent the time parameter (hours), and hydration shape parameter,
\(T_{r}\) refers to the reference temperature (K),
\(R\) is the ideal gas constant (8.314 J/mol/K),
\(E_{a}\) refers to the apparent activation energy (J/mol), and
\(X_{slag}\) and
\(X_{FA}\) denote the weight proportion of the blast furnace slag and fly ash relative to the total binder mass, respectively. In accordance with the definition of the degree of binder hydration (i.e., Eq. (
2)), the influence of temperature, mixture recipe and elapsed time are incorporated to determine the progression of the hydration reaction.