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2018 | OriginalPaper | Buchkapitel

On-Surface Coupling Reactions with Extrinsic Catalysts

verfasst von : Wei Zhao, Lei Dong, Ran Zhang, Nian Lin

Erschienen in: On-Surface Synthesis II

Verlag: Springer International Publishing

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Abstract

On-surface coupling reactions have opened a novel route toward synthesizing various organic nanostructures on surfaces. In this chapter, we discuss the catalytic effects of Cu and Pd deposits in the on-surface Ullmann coupling and Sonogashira cross-coupling reactions. The stepwise reaction paths, intermediates, and activation energies are deliberated at a single molecular level using scanning tunneling microscopy (STM). Such studies offer mechanistic insights into the on-surface coupling reactions catalyzed by extrinsic metals.

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Vorheriges Kapitel On-Surface Synthesis of Two-Dimensional Polymers: Rational Design and Electronic Properties

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Titel: On-Surface Coupling Reactions with Extrinsic Catalysts
verfasst von: Wei Zhao
Lei Dong
Ran Zhang
Nian Lin
Verlag: Springer International Publishing
Buch: On-Surface Synthesis II
Print ISBN: 978-3-319-75809-1

Electronic ISBN: 978-3-319-75810-7

Copyright-Jahr: 2018
DOI: https://doi.org/10.1007/978-3-319-75810-7_9

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