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Journal of Materials Science
Erschienen in: Journal of Materials Science 17/2017

11.05.2017 | Chemical routes to materials

One-pot synthesis of Ni-SSZ-13 zeolite using a nickel-amine complex as an efficient organic template

verfasst von: Yucun Cui, Xueting Tong, Ying Li, Mingjiong Chen, Wenyong Zhou, Silin Ren, Lei Li, Zheng Yan, Longfeng Zhu

Erschienen in: Journal of Materials Science | Ausgabe 17/2017

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Abstract

We show that a nickel-amine complex (nickel-diethylenetriamine, Ni-DETA) is an efficient organic template for the one-pot synthesis of Ni-SSZ-13 zeolite. The effects of the reaction compositions, including the molar ratios of SiO2/Al2O3, H2O/Al2O3, Ni-DETA/Al2O3, and Na2O/Al2O3, on the synthesis of the pure product were investigated using different temperatures and synthesis times. Physicochemical characterizations, including XRD, SEM, and 27Al NMR, show that the zeolitic product has good crystallinity, uniform crystals, and contains a tetrahedral Al3+ species. The N2 sorption isotherms, TG–DTA curves, IR spectra, and UV–Vis spectra show that Ni-DETA acts as a template in the product obtained. Interestingly, Ni-SSZ-13 zeolite is obtained by the conversion of Ni-Y zeolite produced in the crystallization process.
Vorheriger Artikel Phase transitions, dielectric properties and valence of magnetic ions in PbFe0.5−x Cr x Nb0.5O3 multiferroic ceramics
Nächster Artikel Rational synthesis and tailored optical and magnetic characteristics of Fe3O4–Au composite nanoparticles

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Metadaten
Titel
One-pot synthesis of Ni-SSZ-13 zeolite using a nickel-amine complex as an efficient organic template
verfasst von
Yucun Cui
Xueting Tong
Ying Li
Mingjiong Chen
Wenyong Zhou
Silin Ren
Lei Li
Zheng Yan
Longfeng Zhu
Publikationsdatum
11.05.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 17/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1171-x

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