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22.05.2019 | Original Research

One-step fabrication of flexible, durable and fluorine-free superhydrophobic cotton fabrics for efficient oil/water separation

verfasst von: Zhonghua Mai, Xin Shu, Guoqing Li, Dongzhi Chen, Min Liu, Weilin Xu, Hongwei Zhang

Erschienen in: Cellulose | Ausgabe 10/2019

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Abstract

Fabrication of superhydrophobic cotton fabrics commonly suffers from disadvantages such as extensive usage of toxic and expensive fluorinated adhesives, tedious and time-consuming treatment processes, poor durability and compromised mechanical properties. Herein, this work offers a one-step approach for fabricating eco-friendly, fluorine-free, flexible and robust functional cotton fabrics by immersion in composite coatings containing polydimethylsiloxane (PDMS) and calcite particles. Results demonstrate that the PDMS/calcite coatings not only enhance mechanical properties of cotton fabrics, but also impart cotton fabrics with excellent superhydrophobic and tunable comfort properties in comparison with the reference materials. Notably, the cotton fabrics treated with the PDMS/calcite coatings also show excellent oil/water separation efficiency of up to 99% after 10 cycles, robust water laundering stability and self-cleaning ability. Therefore, this novel straightforward, cost-efficient, eco-friendly and durable PDMS/calcite composite coating for cotton fabric has great potential in diverse applications including self-cleaning apparel, water-proof wall covering and continuous oil clean-up.

Vorheriger Artikel A reactive fluorine-free, efficient superhydrophobic and flame-retardant finishing agent for cotton fabrics

Nächster Artikel Sol–gel finishing of bamboo fabric with nanoparticles for water repellency, soil release and UV resistant characteristics

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Cao C et al (2016) Robust fluorine-free superhydrophobic PDMS–ormosil@fabrics for highly effective self-cleaning and efficient oil–water separation. J Mater Chem A 4:12179–12187. https://doi.org/10.1039/C6TA04420D CrossRef

Chen D, Chen F, Hu X, Zhang H, Yin X, Zhou Y (2015a) Thermal stability, mechanical and optical properties of novel addition cured PDMS composites with nano-silica sol and MQ silicone resin. Compos Sci Technol 117:307–314. https://doi.org/10.1016/j.compscitech.2015.07.003 CrossRef

Chen D, Chen F, Zhang H, Yin X, Liu X, Zhou Y (2015b) Preparation and characterization of novel addition cured polydimethylsiloxane nanocomposites using nano-silica sol as reinforcing filler. Polym Int 64:1741–1746. https://doi.org/10.1002/pi.4974 CrossRef

Chen S, Li X, Li Y, Sun J (2015c) Intumescent flame-retardant and self-healing superhydrophobic coatings on cotton fabric. ACS Nano 9:4070–4076. https://doi.org/10.1021/acsnano.5b00121 CrossRefPubMed

Chen D, Chen F, Zhang H, Yin X, Zhou Y (2016a) Preparation and characterization of novel hydrophobic cellulose fabrics with polyvinylsilsesquioxane functional coatings. Cellulose 23:941–953. https://doi.org/10.1007/s10570-015-0820-y CrossRef

Chen J et al (2016b) The facile preparation of self-cleaning fabrics. Compos Sci Technol 122:1–9. https://doi.org/10.1016/j.compscitech.2015.11.015 CrossRef

Chen D, Sun W, Qian C, Wong APY, Reyes LM, Ozin GA (2017) UV-Blocking photoluminescent silicon nanocrystal/polydimethylsiloxane composites. Adv Opt Mater 5:1700237. https://doi.org/10.1002/adom.201700237 CrossRef

Chen D et al (2018) UV-blocking, superhydrophobic and robust cotton fabrics fabricated using polyvinylsilsesquioxane and nano-TiO₂. Cellulose 25:3635–3647. https://doi.org/10.1007/s10570-018-1790-7 CrossRef

Cheng Y et al (2018) Progress in TiO₂ nanotube coatings for biomedical applications: a review. J Mater Chem B 6:1862–1886. https://doi.org/10.1039/C8TB00149A CrossRef

Cheng M et al (2019a) Preparation and properties of pH-responsive reversible-wettability biomass cellulose-based material for controllable oil/water separation. Carbohydr Polym 203:246–255. https://doi.org/10.1016/j.carbpol.2018.09.051 CrossRefPubMed

Cheng Q-Y, Guan C-S, Li Y-D, Zhu J, Zeng J-B (2019b) Robust and durable superhydrophobic cotton fabrics via a one-step solvothermal method for efficient oil/water separation. Cellulose. https://doi.org/10.1007/s10570-019-02267-6 CrossRef

Deng Z-Y, Wang W, Mao L-H, Wang C-F, Chen S (2014) Versatile superhydrophobic and photocatalytic films generated from TiO₂–SiO₂@PDMS and their applications on fabrics. J Mater Chem A 2:4178–4184. https://doi.org/10.1039/C3TA14942K CrossRef

Dixon C, Lamanna J, Wheeler AR (2017) Printed microfluidics. Adv Funct Mater 27:1604824. https://doi.org/10.1002/adfm.201604824 CrossRef

French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896. https://doi.org/10.1007/s10570-013-0030-4 CrossRef

Gao S et al (2017) Facile construction of robust fluorine-free superhydrophobic TiO₂@fabrics with excellent anti-fouling, water–oil separation and UV-protective properties. Mater Des 128:1–8. https://doi.org/10.1016/j.matdes.2017.04.091 CrossRef

Gao S, Dong X, Huang J, Li S, Li Y, Chen Z, Lai Y (2018) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil–water separation. Chem Eng J 333:621–629. https://doi.org/10.1016/j.cej.2017.10.006 CrossRef

Ge M et al (2018) Rational design of materials interface at nanoscale towards intelligent oil–water separation. Nanoscale Horiz 3:235–260. https://doi.org/10.1039/c7nh00185a CrossRef

Gore PM, Kandasubramanian B (2018) Heterogeneous wettable cotton based superhydrophobic Janus biofabric engineered with PLA/functionalized-organoclay microfibers for efficient oil–water separation. J Mater Chem A 6:7457–7479. https://doi.org/10.1039/c7ta11260b CrossRef

Gu J et al (2017) Functionalization of biodegradable PLA nonwoven fabric as superoleophilic and superhydrophobic material for efficient oil absorption and oil/water separation. ACS Appl Mater Interfaces 9:5968–5973. https://doi.org/10.1021/acsami.6b13547 CrossRefPubMed

Gupta RK, Dunderdale GJ, England MW, Hozumi A (2017) Oil/water separation techniques: a review of recent progresses and future directions. J Mater Chem A 5:16025–16058. https://doi.org/10.1039/C7TA02070H CrossRef

Hong SK, Bae S, Jeon H, Kim M, Cho SJ, Lim G (2018) An underwater superoleophobic nanofibrous cellulosic membrane for oil/water separation with high separation flux and high chemical stability. Nanoscale 10:3037–3045. https://doi.org/10.1039/C7NR08199E CrossRefPubMed

Jing X, Guo Z (2018) Biomimetic super durable and stable surfaces with superhydrophobicity. J Mater Chem A 6:16731–16768. https://doi.org/10.1039/C8TA04994G CrossRef

Li L, Li B, Dong J, Zhang J (2016a) Roles of silanes and silicones in forming superhydrophobic and superoleophobic materials. J Mater Chem A 4:13677–13725. https://doi.org/10.1039/C6TA05441B CrossRef

Li Y, Ge B, Men X, Zhang Z, Xue Q (2016b) A facile and fast approach to mechanically stable and rapid self-healing waterproof fabrics. Compos Sci Technol 125:55–61. https://doi.org/10.1016/j.compscitech.2016.01.021 CrossRef

Li S, Huang J, Chen Z, Chen G, Lai Y (2017a) A review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications. J Mater Chem A 5:31–55. https://doi.org/10.1039/C6TA07984A CrossRef

Li Y, Zhang Z, Wang M, Men X, Xue Q (2017b) One-pot fabrication of nanoporous polymer decorated materials: from oil-collecting devices to high-efficiency emulsion separation. J Mater Chem A 5:5077–5087. https://doi.org/10.1039/C7TA00297A CrossRef

Lin W et al (2018) Preparation of highly hydrophobic and anti-fouling wood using poly(methylhydrogen)siloxane. Cellulose 25:7341–7353. https://doi.org/10.1007/s10570-018-2074-y CrossRef

Liu L, Yuan W (2018) A hierarchical functionalized biodegradable PLA electrospun nanofibrous membrane with superhydrophobicity and antibacterial properties for oil/water separation. New J Chem 42:17615–17624. https://doi.org/10.1039/C8NJ03112F CrossRef

Liu D, Zhang M, He L, Chen Y, Lei W (2017a) Layer-by-layer assembly fabrication of porous boron nitride coated multifunctional materials for water cleaning. Adv Mater Interfaces 4:1700392. https://doi.org/10.1002/admi.201700392 CrossRef

Liu M, Hou Y, Li J, Tie L, Peng Y, Guo Z (2017b) Inorganic adhesives for robust, self-healing, superhydrophobic surfaces. J Mater Chem A 5:19297–19305. https://doi.org/10.1039/C7TA06001G CrossRef

Liu Z, Yu J, Lin W, Yang W, Li R, Chen H, Zhang X (2018) Facile method for the hydrophobic modification of filter paper for applications in water–oil separation. Surf Coat Technol 352:313–319. https://doi.org/10.1016/j.surfcoat.2018.08.026 CrossRef

Long M et al (2017) A robust superhydrophobic PDMS@ZnSn(OH)₆ coating with under-oil self-cleaning and flame retardancy. J Mater Chem A 5:22761–22771. https://doi.org/10.1039/C7TA06190K CrossRef

Ma Q et al (2017) Preparation of superhydrophilic and underwater superoleophobic nanofiber-based meshes from waste glass for multifunctional oil/water separation. Small 13:1700391. https://doi.org/10.1002/smll.201700391 CrossRef

Mai Z et al (2018) Multifunctionalization of cotton fabrics with polyvinylsilsesquioxane/ZnO composite coatings. Carbohydr Polym 199:516–525. https://doi.org/10.1016/j.carbpol.2018.07.052 CrossRefPubMed

Muresan EI, Balan G, Popescu V (2013) Durable hydrophobic treatment of cotton fabrics with glycidyl stearate. Ind Eng Chem Res 52:6270–6276. https://doi.org/10.1021/ie400235u CrossRef

Peng C, Chen Z, Tiwari MK (2018) All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance. Nat Mater 17:355–360. https://doi.org/10.1038/s41563-018-0044-2 CrossRefPubMed

Przybylak M, Maciejewski H, Dutkiewicz A, Dabek I, Nowicki M (2016) Fabrication of superhydrophobic cotton fabrics by a simple chemical modification. Cellulose 23:2185–2197. https://doi.org/10.1007/s10570-016-0940-z CrossRef

Qian H et al (2017) Dual-action smart coatings with a self-healing superhydrophobic surface and anti-corrosion properties. J Mater Chem A 5:2355–2364. https://doi.org/10.1039/C6TA10903A CrossRef

Reddy N, Salam A, Yang YQ (2008) Effect of structures and concentrations of softeners on the performance properties and durability to laundering of cotton fabrics. Ind Eng Chem Res 47:2502–2510. https://doi.org/10.1021/ie071564f CrossRef

Sasaki K, Tenjimbayashi M, Manabe K, Shiratori S (2016) Asymmetric superhydrophobic/superhydrophilic cotton fabrics designed by spraying polymer and nanoparticles. ACS Appl Mater Interfaces 8:651–659. https://doi.org/10.1021/acsami.5b09782 CrossRefPubMed

Singh AK, Singh JK (2017) Fabrication of durable superhydrophobic coatings on cotton fabrics with photocatalytic activity by fluorine-free chemical modification for dual-functional water purification. New J Chem 41:4618–4628. https://doi.org/10.1039/c7nj01042g CrossRef

Tang X et al (2017) A facile procedure to modify filter paper for oil–water separation. RSC Adv 7:30495–30499. https://doi.org/10.1039/C7RA03754F CrossRef

Tang X, Wang X, Tang C, Ma J, Zhang S, Li Z, Dong F (2019) PDA-assisted one-pot fabrication of bioinspired filter paper for oil–water separation. Cellulose 26:1355–1366. https://doi.org/10.1007/s10570-018-2144-1 CrossRef

Wang L, Xi GH, Wan SJ, Zhao CH, Liu XD (2014) Asymmetrically superhydrophobic cotton fabrics fabricated by mist polymerization of lauryl methacrylate. Cellulose 21:2983–2994. https://doi.org/10.1007/s10570-014-0275-6 CrossRef

Wang Z, Liu G, Huang S (2016) In situ generated Janus fabrics for the rapid and efficient separation of oil from oil-in-water emulsions. Angew Chem 55:14610–14613. https://doi.org/10.1002/anie.201607581 CrossRef

Wu M, Ma B, Pan T, Chen S, Sun J (2016) Silver-nanoparticle-colored cotton fabrics with tunable colors and durable antibacterial and self-healing superhydrophobic properties. Adv Funct Mater 26:569–576. https://doi.org/10.1002/adfm.201504197 CrossRef

Wu C et al (2017) Fabrication of ZIF-8@SiO₂ micro/nano hierarchical superhydrophobic surface on AZ31 magnesium alloy with impressive corrosion resistance and abrasion resistance. ACS Appl Mater Interfaces 9:11106–11115. https://doi.org/10.1021/acsami.6b16848 CrossRefPubMed

Xiong D, Liu G, Duncan EJS (2012) Diblock-copolymer-coated water- and oil-repellent cotton fabrics. Langmuir 28:6911–6918. https://doi.org/10.1021/la300634v CrossRefPubMed

Xu Z, Zhao Y, Wang H, Zhou H, Qin C, Wang X, Lin T (2016) Fluorine-free superhydrophobic coatings with pH-induced wettability transition for controllable oil–water separation. ACS Appl Mater Interfaces 8:5661–5667. https://doi.org/10.1021/acsami.5b11720 CrossRefPubMed

Yang M, Liu W, Jiang C, He S, Xie Y, Wang Z (2018) Fabrication of superhydrophobic cotton fabric with fluorinated TiO₂ sol by a green and one-step sol–gel process. Carbohydr Polym 197:75–82. https://doi.org/10.1016/j.carbpol.2018.05.075 CrossRefPubMed

Yong J, Chen F, Yang Q, Huo J, Hou X (2017) Superoleophobic surfaces. Chem Soc Rev 46:4168–4217. https://doi.org/10.1039/C6CS00751A CrossRefPubMed

Yuan Z et al (2014) Preparation of a polydimethylsiloxane (PDMS)/CaCO₃ based superhydrophobic coating. Surf Coat Technol 254:97–103. https://doi.org/10.1016/j.surfcoat.2014.05.068 CrossRef

Yuan R et al (2017) Facile fabrication approach for a novel multifunctional superamphiphobic coating based on chemically grafted montmorillonite/Al₂O₃-polydimethylsiloxane binary nanocomposite. J Polym Res. https://doi.org/10.1007/s10965-017-1222-7 CrossRef

Zahid M, Heredia-Guerrero JA, Athanassiou A, Bayer IS (2017) Robust water repellent treatment for woven cotton fabrics with eco-friendly polymers. Chem Eng J 319:321–332. https://doi.org/10.1016/j.cej.2017.03.006 CrossRef

Zhang Y, Li Y, Shao J, Zou C (2015) Fabrication of superhydrophobic fluorine-free films on cotton fabrics through plasma-induced grafting polymerization of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane. Surf Coat Technol 276:16–22. https://doi.org/10.1016/j.surfcoat.2015.06.050 CrossRef

Zhang H et al (2016) Robust, self-healing, superhydrophobic coatings highlighted by a novel branched thiol-ene fluorinated siloxane nanocomposites. Compos Sci Technol 137:78–86. https://doi.org/10.1016/j.compscitech.2016.10.023 CrossRef

Zhang F, Ren H, Shen L, Tong G, Deng Y (2017a) Micro–nano structural engineering of filter paper surface for high selective oil–water separation. Cellulose 24:2913–2924. https://doi.org/10.1007/s10570-017-1292-z CrossRef

Zhang S, Huang J, Cheng Y, Yang H, Chen Z, Lai Y (2017b) Bioinspired surfaces with superwettability for anti-icing and ice-phobic application: concept, mechanism, and design. Small 13:1701867. https://doi.org/10.1002/smll.201701867 CrossRef

Zhang W et al (2018) Alloyed multi-shell quantum dots with tunable dual emission. J Mater Chem C 6:11280–11286. https://doi.org/10.1039/C8TC03331E CrossRef

Zhao J et al (2014) Biomimetic and bioinspired membranes: preparation and application. Prog Polym Sci 39:1668–1720. https://doi.org/10.1016/j.progpolymsci.2014.06.001 CrossRef

Zhou H, Wang H, Niu H, Gestos A, Wang X, Lin T (2012) Fluoroalkyl silane modified silicone rubber/nanoparticle composite: a super durable, robust superhydrophobic fabric coating. Adv Mater 24:2409–2412. https://doi.org/10.1002/adma.201200184 CrossRefPubMed

Titel: One-step fabrication of flexible, durable and fluorine-free superhydrophobic cotton fabrics for efficient oil/water separation
verfasst von: Zhonghua Mai
Xin Shu
Guoqing Li
Dongzhi Chen
Min Liu
Weilin Xu
Hongwei Zhang
Publikationsdatum: 22.05.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 10/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02515-9

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