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Cellulose

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23.05.2018 | Original Paper

Optimization of carboxymethylation reaction as a pretreatment for production of cellulose nanofibrils

verfasst von: Wanhee Im, Seakho Lee, Araz Rajabi Abhari, Hye Jung Youn, Hak Lae Lee

Erschienen in: Cellulose | Ausgabe 7/2018

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Abstract

We investigated the optimal reaction conditions for carboxymethylation as a pretreatment method for the production of cellulose nanofibrils (CNF). The influence of the reaction sequence, solvent composition, and presence of water in the reaction medium on the carboxymethylation of pulp was studied. We also investigated the effects of water in the reaction medium on CNF properties. The most effective carboxymethylation of pulp was achieved with non-solvent exchanged pulp and isopropanol. An increase in pulp consistency increased the carboxyl group content. The optimum reaction condition used only one-third the amounts of monochloroacetic acid and sodium hydroxide for the same level of carboxymethylation. The number of passes required for mechanical fibrillation of the pulp, the morphology and dispersion instability of CNF were all strongly influenced by the carboxyl content introduced during the carboxymethylation reaction. The number of mechanical treatment steps required to produce CNF decreased as the carboxyl content increased. Pulp with a high carboxyl content resulted in a more stable suspension due to the increased electrostatic repulsion between the fibrils.

Vorheriger Artikel Electrochemical chiral sensor based on cellulose nanocrystals and multiwall carbon nanotubes for discrimination of tryptophan enantiomers

Nächster Artikel Comparison of the surface constitutions of hemicelluloses on lignocellulosic nanofibers prepared from softwood and hardwood

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Titel: Optimization of carboxymethylation reaction as a pretreatment for production of cellulose nanofibrils
verfasst von: Wanhee Im
Seakho Lee
Araz Rajabi Abhari
Hye Jung Youn
Hak Lae Lee
Publikationsdatum: 23.05.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 7/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1853-9

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