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2019 | OriginalPaper | Buchkapitel

1. Organic and Carbon Gels: From Laboratory to Industry?

verfasst von : Ana Arenillas, J. Angel Menéndez, Gudrun Reichenauer, Alain Celzard, Vanessa Fierro, Francisco José Maldonado Hodar, Esther Bailόn-Garcia, Nathalie Job

Erschienen in: Organic and Carbon Gels

Verlag: Springer International Publishing

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Abstract

Since the first report on organic gels based on the polycondensation of resorcinol with formaldehyde presented by Pekala in 1989, the number of publications, on both organic gels and carbon gels has experimented an enormous increase to the point where nowadays are published every year more than a hundred papers covering topics ranging from variations in the synthesis to the potential applications of this vast family of porous materials. This is due to the fact that, by controlling the synthesis conditions, it is possible to obtain materials with a suitable porosity for a specific application and even also with predetermined chemical properties, something that is practically impossible to achieve with any other porous materials. However, even after almost 30 years of continuous researching at laboratory scale, their industrial production and commercialization are still marginal compared with that of competitive materials. This chapter summarizes how the physicochemical properties of organic and carbon gels can be designed by controlling all the variables involved in the synthesis process. The chapter also addresses the most challenging problem of their mass production, i.e., scaling-up of production methods currently used in the labs.

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Literatur
1.
Zurück zum Zitat J.A. Menéndez, I. Martín Gullón, Types of absorbents and their production, in Activated Carbon Surfaces in Environmental Remediation, Interface Science and Technology, ed. by T. Bandosz, vol. 7, (Elsevier, Oxford, 2006), pp. 1–47CrossRef J.A. Menéndez, I. Martín Gullón, Types of absorbents and their production, in Activated Carbon Surfaces in Environmental Remediation, Interface Science and Technology, ed. by T. Bandosz, vol. 7, (Elsevier, Oxford, 2006), pp. 1–47CrossRef
2.
Zurück zum Zitat R.W. Pekala, Organic aerogels from the polycondensation of resorcinol with formaldehyde. J. Mater. Sci. 24, 3221–3227 (1989)CrossRef R.W. Pekala, Organic aerogels from the polycondensation of resorcinol with formaldehyde. J. Mater. Sci. 24, 3221–3227 (1989)CrossRef
3.
Zurück zum Zitat N. Job, A. Thery, R. Pirard, et al., Carbon aerogels, cryogels and xerogels: influence of the drying method on the textural properties of porous carbon materials. Carbon 43, 2481–2494 (2005)CrossRef N. Job, A. Thery, R. Pirard, et al., Carbon aerogels, cryogels and xerogels: influence of the drying method on the textural properties of porous carbon materials. Carbon 43, 2481–2494 (2005)CrossRef
4.
Zurück zum Zitat L. Zubizarreta, A. Arenillas, A. Domínguez, et al., Development of microporous carbon xerogels by controlling synthesis conditions. J. Non-Cryst. Solids 354, 817–825 (2008)CrossRef L. Zubizarreta, A. Arenillas, A. Domínguez, et al., Development of microporous carbon xerogels by controlling synthesis conditions. J. Non-Cryst. Solids 354, 817–825 (2008)CrossRef
5.
Zurück zum Zitat J. Aleman, A.V. Chadwick, J. He, et al., Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials. Pure Appl. Chem. 79, 1801–1829 (2007)CrossRef J. Aleman, A.V. Chadwick, J. He, et al., Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials. Pure Appl. Chem. 79, 1801–1829 (2007)CrossRef
6.
Zurück zum Zitat A.A. Smitha, M.S.A. Lekshmi, V. Sekkar, et al., Microporous carbon aerogel prepared through ambient pressure drying route as anode material for lithium ion cells. Polym. Adv. Technol. 28, 1945–1950 (2017)CrossRef A.A. Smitha, M.S.A. Lekshmi, V. Sekkar, et al., Microporous carbon aerogel prepared through ambient pressure drying route as anode material for lithium ion cells. Polym. Adv. Technol. 28, 1945–1950 (2017)CrossRef
8.
Zurück zum Zitat A.M. Elkhatat, S.A. Al-Muhtaseb, Advances in tailoring resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 23, 2887–2903 (2011)CrossRef A.M. Elkhatat, S.A. Al-Muhtaseb, Advances in tailoring resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 23, 2887–2903 (2011)CrossRef
9.
Zurück zum Zitat I.D. Alonso-Buenaposada, N. Rey-Raap, E.G. Calvo, et al., Acid-based resorcinol-formaldehyde xerogels synthesized by microwave heating. J. Sol-Gel Sci. Technol. 84, 60–69 (2017)CrossRef I.D. Alonso-Buenaposada, N. Rey-Raap, E.G. Calvo, et al., Acid-based resorcinol-formaldehyde xerogels synthesized by microwave heating. J. Sol-Gel Sci. Technol. 84, 60–69 (2017)CrossRef
10.
Zurück zum Zitat S. Mulik, C. Sotiriou-Leventis, Resorcinol-formaldehyde aerogels, in Aerogels Handbook. Advances in Sol-Gel Derived Materials and Technologies, ed. by M. Aegerter, N. Leventis, M. Koebel, (Springer, New York, 2011), pp. 215–234 S. Mulik, C. Sotiriou-Leventis, Resorcinol-formaldehyde aerogels, in Aerogels Handbook. Advances in Sol-Gel Derived Materials and Technologies, ed. by M. Aegerter, N. Leventis, M. Koebel, (Springer, New York, 2011), pp. 215–234
11.
Zurück zum Zitat E.G. Calvo, J.A. Menéndez, A. Arenillas, Influence of alkaline compounds on the porosity of resorcinol-formaldehyde xerogels. J. Non-Cryst. Solids 452, 286–290 (2016)CrossRef E.G. Calvo, J.A. Menéndez, A. Arenillas, Influence of alkaline compounds on the porosity of resorcinol-formaldehyde xerogels. J. Non-Cryst. Solids 452, 286–290 (2016)CrossRef
12.
Zurück zum Zitat D. Fairen-Jimenez, F. Carrasco-Marín, C. Moreno-Castilla, Porosity and surface area of monolithic carbon aerogels prepared using alkaline carbonates and organic acids as polymerization catalyst. Carbon 44, 2301–2307 (2006)CrossRef D. Fairen-Jimenez, F. Carrasco-Marín, C. Moreno-Castilla, Porosity and surface area of monolithic carbon aerogels prepared using alkaline carbonates and organic acids as polymerization catalyst. Carbon 44, 2301–2307 (2006)CrossRef
13.
Zurück zum Zitat N. Job, C.J. Gommes, R. Pirard, et al., Effect of the counter-ion of the basification agent on the porous texture of organic and carbon xerogels. J. Non-Cryst. Solids 354, 4698–4701 (2008)CrossRef N. Job, C.J. Gommes, R. Pirard, et al., Effect of the counter-ion of the basification agent on the porous texture of organic and carbon xerogels. J. Non-Cryst. Solids 354, 4698–4701 (2008)CrossRef
14.
Zurück zum Zitat R.J. Konwar, M. De, Effects of synthesis parameters on zeolite templated carbon for hydrogen storage application. Microporous Mesoporous Mater. 175, 16–24 (2013)CrossRef R.J. Konwar, M. De, Effects of synthesis parameters on zeolite templated carbon for hydrogen storage application. Microporous Mesoporous Mater. 175, 16–24 (2013)CrossRef
15.
Zurück zum Zitat T. Segakweng, N.M. Musyoka, J. Ren, et al., Comparison of MOF-5 and Cr-MOF-derived carbons for hydrogen storage application. Res. Chem. Intermed. 42, 4951–4961 (2016)CrossRef T. Segakweng, N.M. Musyoka, J. Ren, et al., Comparison of MOF-5 and Cr-MOF-derived carbons for hydrogen storage application. Res. Chem. Intermed. 42, 4951–4961 (2016)CrossRef
16.
Zurück zum Zitat R. Xu, M. Prodanovic, Effect of pore geometry on nitrogen sorption isotherms interpretation: a pore network modeling study. Fuel 225, 243–255 (2018)CrossRef R. Xu, M. Prodanovic, Effect of pore geometry on nitrogen sorption isotherms interpretation: a pore network modeling study. Fuel 225, 243–255 (2018)CrossRef
17.
Zurück zum Zitat I.D. Alonso-Buenaposada, A. Arenillas, M.A. Montes-Morán, et al., Superhydrophobic and breathable resorcinol-formaldehyde xerogels. J. Non-Cryst. Solids 471, 202–208 (2017)CrossRef I.D. Alonso-Buenaposada, A. Arenillas, M.A. Montes-Morán, et al., Superhydrophobic and breathable resorcinol-formaldehyde xerogels. J. Non-Cryst. Solids 471, 202–208 (2017)CrossRef
18.
Zurück zum Zitat F. Béguin, A. Balducci, E. Frackowiak, Carbons and electrolytes for advanced supercapacitors. Adv. Mater. 26, 2219–2251 (2014)CrossRef F. Béguin, A. Balducci, E. Frackowiak, Carbons and electrolytes for advanced supercapacitors. Adv. Mater. 26, 2219–2251 (2014)CrossRef
19.
Zurück zum Zitat S.A. Al-Muhtased, J.A. Ritter, Preparation and properties of resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 15, 101–114 (2003)CrossRef S.A. Al-Muhtased, J.A. Ritter, Preparation and properties of resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 15, 101–114 (2003)CrossRef
20.
Zurück zum Zitat C. Scherdel, R. Gayer, G. Reichenauer, Porous organic and carbon xerogels derived from alkaline aqueous phenol-formaldehyde solutions. J. Porous. Mater. 136, 837–844 (2012) C. Scherdel, R. Gayer, G. Reichenauer, Porous organic and carbon xerogels derived from alkaline aqueous phenol-formaldehyde solutions. J. Porous. Mater. 136, 837–844 (2012)
21.
Zurück zum Zitat Y.F. Lin, J.L. Chen, Magnetic mesoporous Fe/carbon aerogel structures with enhanced arsenic removal efficiency. J. Colloid Interface Sci. 420, 74–79 (2014)CrossRef Y.F. Lin, J.L. Chen, Magnetic mesoporous Fe/carbon aerogel structures with enhanced arsenic removal efficiency. J. Colloid Interface Sci. 420, 74–79 (2014)CrossRef
22.
Zurück zum Zitat S. Chandra, S. Bag, R. Bhar, Effect of transition and non-transition metals during the synthesis of carbon xerogels. Microporous Mesoporous Mater. 138, 149–156 (2011)CrossRef S. Chandra, S. Bag, R. Bhar, Effect of transition and non-transition metals during the synthesis of carbon xerogels. Microporous Mesoporous Mater. 138, 149–156 (2011)CrossRef
23.
Zurück zum Zitat Y. Zhu, H. Hu, W.C. Li, Cresol-formaldehyde based carbon aerogel as electrode material for electrochemical capacitor. J. Power Sources 162, 738–742 (2006)CrossRef Y. Zhu, H. Hu, W.C. Li, Cresol-formaldehyde based carbon aerogel as electrode material for electrochemical capacitor. J. Power Sources 162, 738–742 (2006)CrossRef
24.
Zurück zum Zitat B. Grzyb, C. Hildenbrand, S. Berthon-Fabry, et al., Functionalization and chemical characterization of cellulose-derived carbon aerogels. Carbon 48, 2297–2307 (2010)CrossRef B. Grzyb, C. Hildenbrand, S. Berthon-Fabry, et al., Functionalization and chemical characterization of cellulose-derived carbon aerogels. Carbon 48, 2297–2307 (2010)CrossRef
25.
Zurück zum Zitat A. Szczurek, G. Amaral-Labat, V. Fierro, et al., The use of tannin to prepare carbon gels. Part I: carbon aerogels. Carbon 49, 2773–2784 (2011)CrossRef A. Szczurek, G. Amaral-Labat, V. Fierro, et al., The use of tannin to prepare carbon gels. Part I: carbon aerogels. Carbon 49, 2773–2784 (2011)CrossRef
26.
Zurück zum Zitat G. Amaral-Labat, L.I. Grishechko, V. Fierro, et al., Tannin-based xerogels with distinctive porous structures. Biomass Bioenergy 56, 437–445 (2013)CrossRef G. Amaral-Labat, L.I. Grishechko, V. Fierro, et al., Tannin-based xerogels with distinctive porous structures. Biomass Bioenergy 56, 437–445 (2013)CrossRef
27.
Zurück zum Zitat R. Saliger, V. Bock, R. Petricevic, et al., Carbon aerogels from dilute catalysis of resorcinol with formaldehyde. J. Non-Cryst. Solids 221, 144–150 (1997)CrossRef R. Saliger, V. Bock, R. Petricevic, et al., Carbon aerogels from dilute catalysis of resorcinol with formaldehyde. J. Non-Cryst. Solids 221, 144–150 (1997)CrossRef
28.
Zurück zum Zitat H. Tamon, H. Ishizaka, M. Mikami, et al., Porous structure of organic and carbon aerogels synthesized by sol-gel polycondensation of resorcinol with formaldehyde. Carbon 35, 791–796 (1997)CrossRef H. Tamon, H. Ishizaka, M. Mikami, et al., Porous structure of organic and carbon aerogels synthesized by sol-gel polycondensation of resorcinol with formaldehyde. Carbon 35, 791–796 (1997)CrossRef
29.
Zurück zum Zitat N. Job, F. Sabatier, J.P. Pirard, et al., Towards the production of carbon xerogel monoliths by optimizing convective drying conditions. Carbon 44, 2534–2542 (2006)CrossRef N. Job, F. Sabatier, J.P. Pirard, et al., Towards the production of carbon xerogel monoliths by optimizing convective drying conditions. Carbon 44, 2534–2542 (2006)CrossRef
30.
Zurück zum Zitat F. Perez-Caballero, A.L. Peikolainen, M. Uibu, et al., Preparation of carbon aerogels from 5-methylresorcinol-formaldehyde gels. Microporous Mesoporous Mater. 108, 230–236 (2008)CrossRef F. Perez-Caballero, A.L. Peikolainen, M. Uibu, et al., Preparation of carbon aerogels from 5-methylresorcinol-formaldehyde gels. Microporous Mesoporous Mater. 108, 230–236 (2008)CrossRef
31.
Zurück zum Zitat Y. Lee, J.S. Yoon, D.J. Suh, et al., 5-hydroxymethylfurfural as a potential monomer for the preparation of carbon aerogel. Mater. Chem. Phys. 136, 837–844 (2012)CrossRef Y. Lee, J.S. Yoon, D.J. Suh, et al., 5-hydroxymethylfurfural as a potential monomer for the preparation of carbon aerogel. Mater. Chem. Phys. 136, 837–844 (2012)CrossRef
32.
Zurück zum Zitat B.B. Garcia, D. Liu, S. Sepehri, et al., Hexamethylenetetramine multiple catalysis as a porosity and pore size modifier in carbon cryogels. J. Non-Cryst. Solids 356, 1620–1625 (2010)CrossRef B.B. Garcia, D. Liu, S. Sepehri, et al., Hexamethylenetetramine multiple catalysis as a porosity and pore size modifier in carbon cryogels. J. Non-Cryst. Solids 356, 1620–1625 (2010)CrossRef
33.
Zurück zum Zitat R. Kocklenberg, B. Mathieu, S. Blacher, et al., Texture control of freeze-dried resorcinol-formaldehyde gels. J. Non-Cryst. Solids 225, 8–13 (1998)CrossRef R. Kocklenberg, B. Mathieu, S. Blacher, et al., Texture control of freeze-dried resorcinol-formaldehyde gels. J. Non-Cryst. Solids 225, 8–13 (1998)CrossRef
34.
Zurück zum Zitat E.G. Calvo, E.J. Juarez-Perez, J.A. Menendez, et al., Fast microwave-assisted synthesis of tailored mesoporous carbon xerogels. J. Colloid Interface Sci. 357, 541–547 (2011)CrossRef E.G. Calvo, E.J. Juarez-Perez, J.A. Menendez, et al., Fast microwave-assisted synthesis of tailored mesoporous carbon xerogels. J. Colloid Interface Sci. 357, 541–547 (2011)CrossRef
35.
Zurück zum Zitat S. Berthon, O. Barbieri, F. Ehrburger-Dolle, et al., DLS and SAXS investigations of organic gels and aerogels. J. Non-Cryst. Solids 285, 154–161 (2001)CrossRef S. Berthon, O. Barbieri, F. Ehrburger-Dolle, et al., DLS and SAXS investigations of organic gels and aerogels. J. Non-Cryst. Solids 285, 154–161 (2001)CrossRef
36.
Zurück zum Zitat W. Kicinski, M. Szala, M. Nita, Structurally tailored carbon xerogels produced through a sol-gel process in a water-methanol-inorganic salt solution. J. Sol-Gel Sci. Technol. 58, 102–113 (2011)CrossRef W. Kicinski, M. Szala, M. Nita, Structurally tailored carbon xerogels produced through a sol-gel process in a water-methanol-inorganic salt solution. J. Sol-Gel Sci. Technol. 58, 102–113 (2011)CrossRef
37.
Zurück zum Zitat G. Qin, S. Guo, Preparation of RF organic aerogels and carbon aerogels by alcoholic sol-gel process. Carbon 39, 1935–1937 (2001)CrossRef G. Qin, S. Guo, Preparation of RF organic aerogels and carbon aerogels by alcoholic sol-gel process. Carbon 39, 1935–1937 (2001)CrossRef
38.
Zurück zum Zitat S. Mulik, C. Sotiriou-Leventis, L.N. Leventis, Time-efficient acid-catalyzed synthesis of resorcinol-formaldehyde aerogels. Chem. Mater. 19, 6138–6144 (2007)CrossRef S. Mulik, C. Sotiriou-Leventis, L.N. Leventis, Time-efficient acid-catalyzed synthesis of resorcinol-formaldehyde aerogels. Chem. Mater. 19, 6138–6144 (2007)CrossRef
39.
Zurück zum Zitat C.I. Merzbacher, S.R. Meier, J.R. Pierce, et al., Carbon aerogels as broadband non-reflective materials. J. Non-Cryst. Solids 285, 210–215 (2001)CrossRef C.I. Merzbacher, S.R. Meier, J.R. Pierce, et al., Carbon aerogels as broadband non-reflective materials. J. Non-Cryst. Solids 285, 210–215 (2001)CrossRef
40.
Zurück zum Zitat J. Laskowski, B. Milow, L. Ratke, Subcritically dried resorcinol-formaldehyde aerogels from a base-acid catalyzed synthesis route. Microporous Mesoporous Mater. 197, 308–315 (2014)CrossRef J. Laskowski, B. Milow, L. Ratke, Subcritically dried resorcinol-formaldehyde aerogels from a base-acid catalyzed synthesis route. Microporous Mesoporous Mater. 197, 308–315 (2014)CrossRef
41.
Zurück zum Zitat R. Brandt, R. Petricevic, H. Probstle, et al., Acetic acid catalyzed carbon aerogels. J. Porous. Mater. 10, 171–178 (2003)CrossRef R. Brandt, R. Petricevic, H. Probstle, et al., Acetic acid catalyzed carbon aerogels. J. Porous. Mater. 10, 171–178 (2003)CrossRef
42.
Zurück zum Zitat S. Morales-Torres, F.J. Maldonado-Hodar, A.F. Perez-Cadenas, et al., Textural and mechanical characteristics of carbon aerogels synthesized by polymerization of resorcinol and formaldehyde using alkali carbonates as basification agents. Phys. Chem. Chem. Phys. 12, 10365–10372 (2010)CrossRef S. Morales-Torres, F.J. Maldonado-Hodar, A.F. Perez-Cadenas, et al., Textural and mechanical characteristics of carbon aerogels synthesized by polymerization of resorcinol and formaldehyde using alkali carbonates as basification agents. Phys. Chem. Chem. Phys. 12, 10365–10372 (2010)CrossRef
43.
Zurück zum Zitat N. Rey-Raap, J.A. Menéndez, A. Arenillas, RF xerogels with tailored porosity over the entire nanoscale. Microporous Mesoporous Mater. 195, 266–275 (2014)CrossRef N. Rey-Raap, J.A. Menéndez, A. Arenillas, RF xerogels with tailored porosity over the entire nanoscale. Microporous Mesoporous Mater. 195, 266–275 (2014)CrossRef
44.
Zurück zum Zitat C. Moreno-Castilla, F.J. Maldonado-Hodar, Carbon aerogels for catalysis applications: an overview. Carbon 43, 455–465 (2005)CrossRef C. Moreno-Castilla, F.J. Maldonado-Hodar, Carbon aerogels for catalysis applications: an overview. Carbon 43, 455–465 (2005)CrossRef
45.
Zurück zum Zitat I. Matos, S. Fernandes, L. Guerreiro, et al., The effect of surfactants on the porosity of carbon xerogels. Microporous Mesoporous Mater. 92, 38–46 (2006)CrossRef I. Matos, S. Fernandes, L. Guerreiro, et al., The effect of surfactants on the porosity of carbon xerogels. Microporous Mesoporous Mater. 92, 38–46 (2006)CrossRef
46.
Zurück zum Zitat N. Job, R. Pirard, J. Marien, et al., Porous carbon xerogels with texture tailored by pH control during sol-gel process. Carbon 42, 619–628 (2004)CrossRef N. Job, R. Pirard, J. Marien, et al., Porous carbon xerogels with texture tailored by pH control during sol-gel process. Carbon 42, 619–628 (2004)CrossRef
47.
Zurück zum Zitat S.J. Taylor, M.D. Haw, J. Sefcik, et al., Gelation mechanism of resorcinol-formaldehyde gels investigated by dynamic light scattering. Langmuir 30, 10231–10240 (2014)CrossRef S.J. Taylor, M.D. Haw, J. Sefcik, et al., Gelation mechanism of resorcinol-formaldehyde gels investigated by dynamic light scattering. Langmuir 30, 10231–10240 (2014)CrossRef
48.
Zurück zum Zitat N. Rey-Raap, J.A. Menéndez, A. Arenillas, Simultaneous adjustment of the main chemical variables to fine-tune the porosity of carbon xerogels. Carbon 78, 490–499 (2014)CrossRef N. Rey-Raap, J.A. Menéndez, A. Arenillas, Simultaneous adjustment of the main chemical variables to fine-tune the porosity of carbon xerogels. Carbon 78, 490–499 (2014)CrossRef
49.
Zurück zum Zitat F. Wang, L.F. Yao, J. Shen, et al., The effect of different ratio in carbon aerogel on pore structure in ambient dry. Adv. Mater. Res. 941-944, 450–453 (2014)CrossRef F. Wang, L.F. Yao, J. Shen, et al., The effect of different ratio in carbon aerogel on pore structure in ambient dry. Adv. Mater. Res. 941-944, 450–453 (2014)CrossRef
50.
Zurück zum Zitat L. Zubizarreta, A. Arenillas, J.A. Menéndez, et al., Microwave drying as an effective method to obtain porous carbon xerogels. J. Non-Cryst. Solids 354, 4024–4026 (2008)CrossRef L. Zubizarreta, A. Arenillas, J.A. Menéndez, et al., Microwave drying as an effective method to obtain porous carbon xerogels. J. Non-Cryst. Solids 354, 4024–4026 (2008)CrossRef
51.
Zurück zum Zitat N. Rey-Raap, A. Arenillas, J.A. Menéndez, A visual validation of the combined effect of pH and dilution on the porosity of carbon xerogels. Microporous Mesoporous Mater. 223, 89–93 (2016)CrossRef N. Rey-Raap, A. Arenillas, J.A. Menéndez, A visual validation of the combined effect of pH and dilution on the porosity of carbon xerogels. Microporous Mesoporous Mater. 223, 89–93 (2016)CrossRef
52.
Zurück zum Zitat F.J. Maldonado-Hodar, M.A. Ferro-Garcia, J. Rivera-Utrilla, et al., Synthesis and textural characteristics of organic aerogels, transition-metal-containing organic aerogels and their carbonized derivatives. Carbon 37, 1199–1205 (1999)CrossRef F.J. Maldonado-Hodar, M.A. Ferro-Garcia, J. Rivera-Utrilla, et al., Synthesis and textural characteristics of organic aerogels, transition-metal-containing organic aerogels and their carbonized derivatives. Carbon 37, 1199–1205 (1999)CrossRef
53.
Zurück zum Zitat I.D. Alonso-Buenaposada, N. Rey-Raap, E.G. Calvo, et al., Effect of methanol content in commercial formaldehyde solutions on the porosity of RF carbon xerogels. J. Non-Cryst. Solids 426, 13–18 (2015)CrossRef I.D. Alonso-Buenaposada, N. Rey-Raap, E.G. Calvo, et al., Effect of methanol content in commercial formaldehyde solutions on the porosity of RF carbon xerogels. J. Non-Cryst. Solids 426, 13–18 (2015)CrossRef
54.
Zurück zum Zitat I.D. Alonso-Buenaposada, L. Garrido, M.A. Montes-Morán, et al., An underrated variable essential for tailoring the structure of xerogel: the methanol content of commercial formaldehyde solutions. J. Sol-Gel Sci. Technol. 83, 478–488 (2017)CrossRef I.D. Alonso-Buenaposada, L. Garrido, M.A. Montes-Morán, et al., An underrated variable essential for tailoring the structure of xerogel: the methanol content of commercial formaldehyde solutions. J. Sol-Gel Sci. Technol. 83, 478–488 (2017)CrossRef
55.
Zurück zum Zitat M.A. Worsley, J.H. Satcher Jr., T.F. Baumann, Influence of sodium dodecylbenzene sulfonate on the structure and properties of carbon aerogels. J. Non-Cryst. Solids 356, 172–174 (2010)CrossRef M.A. Worsley, J.H. Satcher Jr., T.F. Baumann, Influence of sodium dodecylbenzene sulfonate on the structure and properties of carbon aerogels. J. Non-Cryst. Solids 356, 172–174 (2010)CrossRef
56.
Zurück zum Zitat N. Rey-Raap, A. Szczurek, V. Fierro, et al., Advances in tailoring the porosity of tannin-based carbon xerogels. Ind. Crop. Prod. 82, 100–106 (2016)CrossRef N. Rey-Raap, A. Szczurek, V. Fierro, et al., Advances in tailoring the porosity of tannin-based carbon xerogels. Ind. Crop. Prod. 82, 100–106 (2016)CrossRef
57.
Zurück zum Zitat N. Rey-Raap, A. Szczurek, V. Fierro, et al., Towards a feasible and scalable production of bio-xerogels. J. Colloid Interface Sci. 456, 138–144 (2015)CrossRef N. Rey-Raap, A. Szczurek, V. Fierro, et al., Towards a feasible and scalable production of bio-xerogels. J. Colloid Interface Sci. 456, 138–144 (2015)CrossRef
58.
Zurück zum Zitat F.J. Maldonado-Hodar, C. Moreno-Castilla, J. Rivera-Utrilla, et al., Catalytic graphitization of carbon aerogels by transition metals. Langmuir 16, 4367–4373 (2000)CrossRef F.J. Maldonado-Hodar, C. Moreno-Castilla, J. Rivera-Utrilla, et al., Catalytic graphitization of carbon aerogels by transition metals. Langmuir 16, 4367–4373 (2000)CrossRef
59.
Zurück zum Zitat N. Job, S.D. Lambert, A. Zubiaur, et al., Design of Pt/carbon xerogel catalysts for PEM fuel cells. Catalysts 5, 40–57 (2015)CrossRef N. Job, S.D. Lambert, A. Zubiaur, et al., Design of Pt/carbon xerogel catalysts for PEM fuel cells. Catalysts 5, 40–57 (2015)CrossRef
60.
Zurück zum Zitat K. Guo, H. Song, X. Chen, et al., Graphene oxide as an anti-shrinkage additive for resorcinol-formaldehyde composite aerogels. Phys. Chem. Chem. Phys. 16, 11603–11608 (2014)CrossRef K. Guo, H. Song, X. Chen, et al., Graphene oxide as an anti-shrinkage additive for resorcinol-formaldehyde composite aerogels. Phys. Chem. Chem. Phys. 16, 11603–11608 (2014)CrossRef
61.
Zurück zum Zitat M. Canal-Rodríguez, A. Arenillas, N. Rey-Raap, et al., Graphene-doped carbon xerogel combining high electrical conductivity and surface area for optimized aqueous supercapacitors. Carbon 118, 291–298 (2017)CrossRef M. Canal-Rodríguez, A. Arenillas, N. Rey-Raap, et al., Graphene-doped carbon xerogel combining high electrical conductivity and surface area for optimized aqueous supercapacitors. Carbon 118, 291–298 (2017)CrossRef
62.
Zurück zum Zitat I.D. Alonso-Buenaposada, A. Arenillas, et al., On the desiccant capacity of the mesoporous RF-xerogels. Microporous Mesoporous Mater. 248, 1–6 (2017)CrossRef I.D. Alonso-Buenaposada, A. Arenillas, et al., On the desiccant capacity of the mesoporous RF-xerogels. Microporous Mesoporous Mater. 248, 1–6 (2017)CrossRef
63.
Zurück zum Zitat I.D. Alonso-Buenaposada, M.A. Montes-Morán, J.A. Menéndez, et al., Synthesis of hydrophobic resorcinol-formaldehyde xerogels by grafting with silanes. React. Funct. Polym. 120, 92–97 (2017)CrossRef I.D. Alonso-Buenaposada, M.A. Montes-Morán, J.A. Menéndez, et al., Synthesis of hydrophobic resorcinol-formaldehyde xerogels by grafting with silanes. React. Funct. Polym. 120, 92–97 (2017)CrossRef
64.
Zurück zum Zitat A.H. Moreno, A. Arenillas, E.G. Calvo, et al., Carbonization of resorcinol-formaldehyde organic xerogels: effect of temperature, particle size and heating rate on the porosity of carbon xerogels. J. Anal. Appl. Pyrolysis 100, 111–116 (2013)CrossRef A.H. Moreno, A. Arenillas, E.G. Calvo, et al., Carbonization of resorcinol-formaldehyde organic xerogels: effect of temperature, particle size and heating rate on the porosity of carbon xerogels. J. Anal. Appl. Pyrolysis 100, 111–116 (2013)CrossRef
65.
Zurück zum Zitat M. Enterria, J.L. Figueiredo, Nanostructured mesoporous carbons: tuning texture and surface chemistry. Carbon 108, 79–102 (2016)CrossRef M. Enterria, J.L. Figueiredo, Nanostructured mesoporous carbons: tuning texture and surface chemistry. Carbon 108, 79–102 (2016)CrossRef
66.
Zurück zum Zitat C. Lin, J.A. Ritter, Carbonization and activation of sol-gel derived carbon xerogels. Carbon 38, 849–861 (2000)CrossRef C. Lin, J.A. Ritter, Carbonization and activation of sol-gel derived carbon xerogels. Carbon 38, 849–861 (2000)CrossRef
67.
Zurück zum Zitat L. Zubizarreta, A. Arenillas, J.P. Pirard, et al., Tailoring the textural properties of activated carbon xerogels by chemical activation with KOH. Microporous Mesoporous Mater. 115, 480–490 (2008)CrossRef L. Zubizarreta, A. Arenillas, J.P. Pirard, et al., Tailoring the textural properties of activated carbon xerogels by chemical activation with KOH. Microporous Mesoporous Mater. 115, 480–490 (2008)CrossRef
68.
Zurück zum Zitat F.L. Conceicao, P.M. Carrott, M.M.L. Carrott, New carbon materials with high porosity in the nm range obtained by chemical activation with phosphoric acid of resorcinol-formaldehyde aerogels. Carbon 47, 1874–1877 (2009)CrossRef F.L. Conceicao, P.M. Carrott, M.M.L. Carrott, New carbon materials with high porosity in the nm range obtained by chemical activation with phosphoric acid of resorcinol-formaldehyde aerogels. Carbon 47, 1874–1877 (2009)CrossRef
69.
Zurück zum Zitat M. Wiener, G. Reichenauer, Microstructure of porous carbons derived from phenolic resin-impact of annealing at temperatures up to 2000°C analyzed by complementary characterization methods. Microporous Mesoporous Mater. 203, 116–122 (2015)CrossRef M. Wiener, G. Reichenauer, Microstructure of porous carbons derived from phenolic resin-impact of annealing at temperatures up to 2000°C analyzed by complementary characterization methods. Microporous Mesoporous Mater. 203, 116–122 (2015)CrossRef
70.
Zurück zum Zitat J.A. Menéndez, A. Arenillas, I. Díaz, et al., Use of an organic xerogel as a desiccant, Patent WO2017149189 J.A. Menéndez, A. Arenillas, I. Díaz, et al., Use of an organic xerogel as a desiccant, Patent WO2017149189
71.
Zurück zum Zitat A. Arenillas, J.A. Menéndez, N. Rey-Raap, et al., Use of an inorganic xerogel as heat insulator, Patent WO2017153624 A. Arenillas, J.A. Menéndez, N. Rey-Raap, et al., Use of an inorganic xerogel as heat insulator, Patent WO2017153624
72.
Zurück zum Zitat A. Demilecamps, M. Alves, A. Rigacci, et al., Nanostructured interpenetrated organic-inorganic aerogels with thermal superinsulating properties. J. Non-Cryst. Solids 452, 259–265 (2016)CrossRef A. Demilecamps, M. Alves, A. Rigacci, et al., Nanostructured interpenetrated organic-inorganic aerogels with thermal superinsulating properties. J. Non-Cryst. Solids 452, 259–265 (2016)CrossRef
73.
Zurück zum Zitat F. Svec, Y. Lv, Advances and recent trends in the field of monolithic columns for chromatography. Anal. Chem. 87, 250–273 (2015)CrossRef F. Svec, Y. Lv, Advances and recent trends in the field of monolithic columns for chromatography. Anal. Chem. 87, 250–273 (2015)CrossRef
74.
Zurück zum Zitat L.A. Ramirez-Montoya, A. Concheso, I.D. Alonso-Buenaposada, et al., Protein adsorption and activity on carbon xerogels with narrow pore size distributions covering a wide mesoporous range. Carbon 118, 743–751 (2017)CrossRef L.A. Ramirez-Montoya, A. Concheso, I.D. Alonso-Buenaposada, et al., Protein adsorption and activity on carbon xerogels with narrow pore size distributions covering a wide mesoporous range. Carbon 118, 743–751 (2017)CrossRef
75.
Zurück zum Zitat B.S. Girgis, I.Y. Sherif, A.A. Attia, et al., Textural and adsorption characteristics of carbon xerogel adsorbents for removal of Cu (II) ions from aqueous solutions. J. Non-Cryst. Solids 358, 741–747 (2012)CrossRef B.S. Girgis, I.Y. Sherif, A.A. Attia, et al., Textural and adsorption characteristics of carbon xerogel adsorbents for removal of Cu (II) ions from aqueous solutions. J. Non-Cryst. Solids 358, 741–747 (2012)CrossRef
76.
Zurück zum Zitat E.G. Calvo, F. Lufrano, P. Staiti, et al., Carbon xerogel and manganese oxide capacitive materials for advanced supercapacitors. Int. J. Electrochem. Sci. 6, 596–612 (2011) E.G. Calvo, F. Lufrano, P. Staiti, et al., Carbon xerogel and manganese oxide capacitive materials for advanced supercapacitors. Int. J. Electrochem. Sci. 6, 596–612 (2011)
77.
Zurück zum Zitat M. Mirzaeian, P.J. Hall, Preparation of controlled porosity carbon aerogels for energy storage in rechargeable lithium oxygen batteries. Electrochim. Acta 54, 7444–7451 (2009)CrossRef M. Mirzaeian, P.J. Hall, Preparation of controlled porosity carbon aerogels for energy storage in rechargeable lithium oxygen batteries. Electrochim. Acta 54, 7444–7451 (2009)CrossRef
78.
Zurück zum Zitat M. Canal-Rodríguez, J.A. Menéndez, A. Arenillas, Performance of carbon xerogel-graphene hybrids as electrodes in aqueous supercapacitors. Electrochim. Acta 276, 28–36 (2018)CrossRef M. Canal-Rodríguez, J.A. Menéndez, A. Arenillas, Performance of carbon xerogel-graphene hybrids as electrodes in aqueous supercapacitors. Electrochim. Acta 276, 28–36 (2018)CrossRef
79.
Zurück zum Zitat N. Rey-Raap, E.G. Calvo, J.M. Bermúdez, et al., An electrical conductivity translator for carbons. Measurement 56, 215–218 (2014)CrossRef N. Rey-Raap, E.G. Calvo, J.M. Bermúdez, et al., An electrical conductivity translator for carbons. Measurement 56, 215–218 (2014)CrossRef
80.
Zurück zum Zitat N. Rey-Raap, A. Arenillas, J.A. Menéndez, Carbon gels and their applications: a review of patents, in Submicron Porous Materials, ed. by P. Bettotti, (Springer, New York, 2017), pp. 25–52CrossRef N. Rey-Raap, A. Arenillas, J.A. Menéndez, Carbon gels and their applications: a review of patents, in Submicron Porous Materials, ed. by P. Bettotti, (Springer, New York, 2017), pp. 25–52CrossRef
Metadaten
Titel
Organic and Carbon Gels: From Laboratory to Industry?
verfasst von
Ana Arenillas
J. Angel Menéndez
Gudrun Reichenauer
Alain Celzard
Vanessa Fierro
Francisco José Maldonado Hodar
Esther Bailόn-Garcia
Nathalie Job
Copyright-Jahr
2019
DOI
https://doi.org/10.1007/978-3-030-13897-4_1

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