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Erschienen in:
1989 | OriginalPaper | Buchkapitel
Organometallic Transformations via C-H Bond Activation
verfasst von : William D. Jones, Valerie L. Chandler, Robert P. Duttweiler Jr., Frank J. Feher, Edward T. Hessell, Grace C. Hsu, Walter P. Kosar
Erschienen in: Organometallics in Organic Synthesis 2
Verlag: Springer Berlin Heidelberg
Enthalten in: Professional Book Archive
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The recent use of transition metal complexes to activate carbon-hydrogen bonds has allowed the conversion of hydrocarbons into functionalized organic molecules. New examples are described in which the adducts resulting from C-H bond oxidative addition are reacted with acetylenes and isocyanides. The complexes described include (C5Me5)Rh(PMe3)(R)H (R = H, CH3, Ph), (C5Me5)Rh(CNR)2, RhCl(PR3)2(CNR’), Fe(PMe3)2(CNR)3, and Ru(dmpe)2(naphthyl)H. Both aldimines and indoles are formed catalytically with these complexes.