Origin of high fluoride in groundwater in the North Gujarat-Cambay region, India

This paper reports on the origin of high fluoride in a regional alluvial aquifer system under water stress in the North Gujarat-Cambay (NGC) region in western India. This region is severely affected by endemic fluorosis due to ingestion of groundwater containing excessive fluoride. With an objective to understand factors controlling high fluoride concentration in groundwater of this region, 225 groundwater samples have been analysed for various chemical parameters. Samples were collected from different depth zones tapping shallow dug wells, geothermal springs, hand-pumps and tubewells, including free flowing artesian wells up to 450 m depth from the aquifers in the Quaternary alluvial formation covering most of the study area. No relation was found between fluoride concentration and depth of sampled groundwater. However, certain sub-aquifer zones have been identified within the Cambay Basin where groundwater contains relatively high fluoride concentration. In general, areas of high fluoride overlap areas with high electrical conductivity (EC). On the west flank of the Cambay Basin in the low lying belt linking Little Rann of Kachchh-Nalsarovar-Gulf of Khambhat (LRK-NS-GK), high fluoride and EC in shallow aquifers originate from evaporative enrichment. On the east flank of Cambay Basin, some high fluoride pockets are observed which are probably due to preferential dissolution of high fluoride bearing minerals. On this flank high fluoride is also associated with thermal springs. Within the Cambay Basin, alternating belts of low and high fluoride concentrations are ascribed to groundwater recharge during the past wet and arid climatic phases, respectively. This is based on groundwater radiocarbon age contours of ~20 ka overlapping the high fluoride belt.