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Erschienen in: Cellulose 3/2008

01.06.2008

Oxidation and sulfonation of cellulosics

verfasst von: Jianguo Zhang, Nan Jiang, Zheng Dang, Thomas J. Elder, Arthur J. Ragauskas

Erschienen in: Cellulose | Ausgabe 3/2008

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Abstract

Bleached hardwood (HW) kraft pulp and derived nanocellulosic structures were modified by a periodate oxidation followed by treatment with sodium bisulfite to yield the corresponding C2/3 sulfonates. The impact of this oxidative–reductive protocol on the chemical and physical properties of cellulose was evaluated by determining physical dimensions, functional groups, and their water absorbency properties. It was found that the water absorbency of cellulosic material can be enhanced by 8.0–199.0% with this oxidation/sulfonation protocol. Distinct differences were observed between sulfonated pulp fibers and nanocellulosic structures, with the latter exhibiting relatively higher water retention values (WRV).

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Metadaten
Titel
Oxidation and sulfonation of cellulosics
verfasst von
Jianguo Zhang
Nan Jiang
Zheng Dang
Thomas J. Elder
Arthur J. Ragauskas
Publikationsdatum
01.06.2008
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 3/2008
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-007-9193-1

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