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Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 6/2016

25.04.2016

Performance of New Pb-Bi Alloys for Pb-Acid Battery Applications: EIS and Polarization Study

verfasst von: Leandro C. Peixoto, Ausdinir D. Bortolozo, Amauri Garcia, Wislei R. Osório

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 6/2016

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Abstract

The present investigation is focused on the evaluation of electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization results, associated with resulting microstructural features of two distinct as-cast Pb-Bi alloys (i.e., 1 and 2.5 wt.% Bi). EIS, potentiodynamic polarization curves, and equivalent circuits are used to analyze the corrosion behavior. The electrochemical parameters show that the corrosion resistance increases when the matrix microstructure is characterized by coarser cells when compared with finer ones. However, when a coarse cellular array is associated with increase in Bi content caused by macrosegregation during casting, the corrosion resistance decreases significantly. Bismuth modifies the anode/cathode area ratio increasing drastically the corrosion action.
Vorheriger Artikel Effect of Heat Treatment on Microstructure and Hot Impact Toughness of Various Zones of P91 Welded Pipes
Nächster Artikel Effect of Micro- and Nano-SiC Particulate Reinforcements in Magnesium-Based Metal Matrix Composites

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Literatur
1.
R.L. Cui and S.G. Wu, Lead Alloys for Maintenance-Free and Sealed Lead/Acid Batteries, J. Power Sources, 1993, 46, p 327–333CrossRef
2.
R.D. Prengaman, The Metallurgy and Performance of Cast and Rolled Lead Alloys for Battery Grids, J. Power Sources, 1997, 67, p 267–278CrossRef
3.
R.D. Prengaman, Challenges from Corrosion-Resistant Grid Alloys in Lead Acid Battery Manufacturing, J. Power Sources, 2001, 95, p 224–233CrossRef
4.
A. El-Sayed, E.M.M. Ibrahim, H.S. Mohran, M. Ismael, and H.A. Shilkamy, Effect of Indium Alloying with Lead on the Mechanical Properties and Corrosion Resistance of Lead-Indium Alloys in Sulfuric Acid Solution, Metall. Mater. Trans. A, 2015, 46A, p 1995–2006CrossRef
5.
A. El-Sayed, H.S. Mohran, H.M.A. El-Lateef, and H.A. Shilkamy, Effect of Indium Alloying with Lead Together with the Addition of Phosphoric Acid in Electrolyte to Improve Lead-Acid Battery Performance, J. Solid State Electrochem., 2015, 19, p 1463–1478CrossRef
6.
Y.B. Zhou, C.X. Yang, W.F. Zhou, and H.T. Liu, Comparison of Pb–Sm–Sn and Pb–Ca–Sn Alloys for the Positive Grids in a Lead Acid Battery, J. Alloys Compd., 2004, 365, p 108–111CrossRef
7.
H.T. Liu, J. Yang, H.H. Liang, J.H. Zhuang, and W.F. Zhou, Effect of Cerium on the Anodic Corrosion of Pb–Ca–Sn Alloy in Sulfuric Acid Solution, J. Power Sources, 2001, 93, p 230–233CrossRef
8.
E. Bashtavelova and A. Winsel, The PbO2 Agglomerate-of-Spheres: Investigation of Four Grid Materials, J. Power Sources, 1997, 67, p 93–103CrossRef
9.
P.C. Frost, Developments in Lead–Acid Batteries: A Lead Producer’s Perspective, J. Power Sources, 1999, 78, p 256–266CrossRef
10.
B. Rezaei and S. Damiri, Effect of Solidification Temperature of Lead Alloy Grids on the Electrochemical Behavior of Lead-Acid Battery, J. Solid State Electrochem., 2005, 9, p 590–594CrossRef
11.
W. Zhang and G. Houlachi, Electrochemical Studies of the Performance of Different Pb–Ag Anodes During and After Zinc Electrowinning, Hydrometallurgy, 2010, 104, p 129–135CrossRef
12.
W.R. Osório, D.M. Rosa, and A. Garcia, The Roles of Cellular and Dendritic Microstructural Morphologies on the Corrosion Resistance of Pb–Sb Alloys for Lead Acid Battery Grids, J. Power Sources, 2008, 175, p 595–603CrossRef
13.
L.C. Peixoto, W.R. Osório, and A. Garcia, Microstructure and Electrochemical Corrosion Behavior of a Pb–1 wt%Sn Alloy for Lead-Acid Battery Components, J. Power Sources, 2009, 192, p 724–729CrossRef
14.
W.R. Osório, L.C. Peixoto, and A. Garcia, Comparison of Electrochemical Performance of As-Cast Pb–1 wt.% Sn and Pb–1 wt.% Sb Alloys for Lead-Acid Battery Components, J. Power Sources, 2010, 195, p 1726–1730CrossRef
15.
L.C. Peixoto, W.R. Osório, and A. Garcia, The Interrelation Between Mechanical Properties, Corrosion Resistance and Microstructure of Pb–Sn Casting Alloys for Lead-Acid Battery Components, J. Power Sources, 2010, 195, p 621–630CrossRef
16.
W.R. Osório, L.C. Peixoto, and A. Garcia, The Effects of Ag Content and Dendrite Spacing on the Electrochemical Behavior of Pb-Ag Alloys for Pb-Acid Battery Components, J. Power Sources, 2013, 238, p 324–335CrossRef
17.
M.J. Koop, D.A. Rand, and B. Culpin, A Guide to the Influence of Bismuth on Lead/Acid Battery Performance, J. Power Sources, 1993, 45, p 365–377CrossRef
18.
M.J. Koop, D.F.A. Koch, and D.A. Rand, Influence of Bismuth on the Corrosion of Lead in 5 M H2SO4, J. Power Sources, 1991, 34, p 369–380CrossRef
19.
D. Pavlov, V. Naidenov, and S. Ruevski, Influence of H2SO4 Concentration on Lead-Acid Battery Performance. H-Type and P-Type Batteries, J. Power Sources, 2006, 161, p 658–665CrossRef
20.
D. Pavlov, G. Petkova, and T. Rogachev, Influence of H2SO4 Concentration on the Performance of Lead-Acid Battery Negative Plates, J. Power Sources, 2008, 175, p 586–594CrossRef
21.
M. Aziz-Kerrzo, K.G. Conroy, A.M. Fenelon, S.T. Farell, and C.B. Breslin, Electrochemical Studies on the Stability and Corrosion Resistance of Titanium-Based Implant Materials, Biomaterial, 2001, 22, p 1531–1539CrossRef
22.
D.Q. Martins, W.R. Osório, M.E.P. Souza, R. Caram, and A. Garcia, Effects of Zr Content on Microstructure and Corrosion Resistance of Ti–30Nb–Zr Casting Alloys for Biomedical Applications, Electrochim. Acta, 2008, 53, p 2809–2817CrossRef
23.
Z.Y. Liu, L. Lu, Y.Z. Huang, C.W. Dua, and X.G. Li, Mechanistic Aspect of Non-steady Electrochemical Characteristic During Stress Corrosion Cracking of an X70 Pipeline Steel in Simulated Underground Water, Corrosion (Houston), 2014, 70, p 678–685. doi:10.​5006/​1153 CrossRef
24.
W.H. Mulder and J.H. Sluyters, An Explanation of Depressed Semi-Circular Arcs in Impedance Plots for Irreversible Electrode Reactions, Electrochim. Acta, 1988, 33, p 303–310CrossRef
25.
S.J. Xia and W.F. Zhou, The Reduction Process of the Anodic Pb(ii) Oxide Film on Lead + Bismuth Alloy in Sulfuric Acid Solution, Electrochim. Acta, 1995, 40, p 181–187CrossRef
26.
S. Gudic, I. Smoljko, and M. Kliskic, The Effect of Small Addition of Tin and Indium on the Corrosion Behavior of Aluminium in Chloride Solution, J. Alloys Compd., 2010, 505, p 54–63CrossRef
27.
D. Pavlov, Processes in Solid State at Anodic Oxidation of a Lead Electrode in H2SO4 Solution and Their Dependence on the Oxide Structure and Properties, Electrochim. Acta, 1978, 23, p 845–854CrossRef
28.
D. Pavlov, S. Gancheva, and P. Andreev, Effect of Hydrogen and Oxygen on Stability of Expanders and Performance of Lead/Acid Batteries, J. Power Sources, 1993, 46, p 349–359CrossRef
29.
N. Papageorgiou and M. Skyllas-Kazacos, Effect of Bismuth on the Corrosion Behaviour of Lead in Sulphuric Acid, J. Power Sources, 1991, 36, p 57–67CrossRef
30.
W.R. Osório, L.C. Peixoto, and A. Garcia, Electrochemical and Mechanical Behavior of Lead-Silver and Lead-Bismuth Casting Alloys for Lead-Acid Battery Components, Metall. Mater. Trans. A, 2015, 46, p 4255–4267CrossRef
31.
H. Safak, Development of Lead Alloys for Valve-Regulated Lead-Acid (VRLA) Batteries, Doctoral dissertation in Metallurgical and Materials Engineering, Middle East Technical University, 2010.
32.
S. Webster, P.J. Mitchell, N.A. Hampson, and J. Dyson, A Short Review of Electrocrystallization and Its Applications to the Lead-Acid Battery, Surf. Technol., 1984, 23, p 105–116CrossRef
33.
D.A.J. Rand, J. Garche, P.T. Moseley, and C.D. Parker, Valve-Regulated Lead-Acid Batteries, Chapter 3, D. Pavlov, Elsevier, p 37–108, 2004. ISBN: 978-0-444-50746-4
Metadaten
Titel
Performance of New Pb-Bi Alloys for Pb-Acid Battery Applications: EIS and Polarization Study
verfasst von
Leandro C. Peixoto
Ausdinir D. Bortolozo
Amauri Garcia
Wislei R. Osório
Publikationsdatum
25.04.2016
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 6/2016
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-016-2059-7

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