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2017 | OriginalPaper | Buchkapitel

9. Permeation and Permeation Barrier

verfasst von : Yuji Hatano

Erschienen in: Tritium: Fuel of Fusion Reactors

Verlag: Springer Japan

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Abstract

Because of their small sizes in molecular and atomic forms, hydrogen isotopes easily dissolve in a solid material and permeate through it. The permeation through a container material is a critical issue against safe confinement of tritium. On the other hand, it is common to employ a permeation technique for the separation of hydrogen isotopes from other gaseous species. In this chapter, elemental processes of permeation of hydrogen isotopes through metals and ceramics are explained together with the possible isotope effects on them. Fundamental equations describing the hydrogen permeation through materials under the exposure to gas and plasma are given. The hydrogen permeation under the corrosive environment is also discussed. Characteristics of hydrogen dissolution, diffusion, and permeation in metallic and ceramic materials important for fusion are summarized together with the peculiarity of the hydrogen permeation under the fusion reactor environments.

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Vorheriges Kapitel Tritium Measurement II—Tritium in Plasma

Nächstes Kapitel Contamination and Decontamination

A. Sieverts, Über Lösungen von Gasen in metallen. Z. Elektrochem. 16, 707–713 (1910). doi:10.1002/bbpc.19100161706

F. Waelbroeck, P. Wienhold, J. Winter, E. Rota, T. Banno, Influence of bulk and surface phenomena on the hydrogen permeation through metals. KFA Jülich Report Jül-1966 (1984), Jülich

M.A. Pick, K. Sonnenberg, A model for atomic hydrogen-metal interactions—application to recycling, recombination and permeation. J. Nucl. Mater. 131, 208–220 (1985). doi:10.1016/0022-3115(85)90459-3 CrossRef

A.I. Livshits, M.E. Notkin, A.A. Sammartsev, Physico-chemical origin of superpermeability—Large-scale effects of surface chemistry on “hot” hydrogen permeation and absorption in metals. J. Nucl. Mater. 170, 79–94 (1990). doi:10.1016/0022-3115(90)90329-L CrossRef

P.M. Richards, Surface-limited hydrogen release and uptake in metals. J. Nucl. Mater. 152, 246–258 (1988). doi:10.1016/0022-3115(88)90333-9 CrossRef

Y. Fukai, The Metal-Hydrogen System Basic Bulk Properties (Springer, Berlin Heidelberg, 1993)CrossRef

F. Reiter, K.S. Forcey, G. Gervasini, A compilation of tritium-material interaction parameters in fusion reactor materials, EUR 15217 EN (1993)

E. Serra, G. Benamati, O.V. Ogorodnikova, Hydrogen isotopes transport parameters in fusion reactor materials. J. Nucl. Mater. 255, 105–115 (1998). doi:10.1016/S0022-3115(98)00038-5 CrossRef

O.W. Richardson, J, Nicol, T. Parnel, The diffusion of hydrogen through hot platinum. Philos. Mag. 8(1904), 1–29. doi:10.1080/14786440409463168

10.

J. Crank, The Mathematics of Diffusion (Oxford University Press, Oxford, 1975)MATH

11.

I. Ali-Khan, K.J. Dietz, F.G. Waelbroeck, P. Wienhold, The rate of hydrogen release out of clean metallic surfaces. J. Nucl. Mater. 76–77, 337–343 (1978). doi:10.1016/0022-3115(78)90167-8 CrossRef

12.

R. Lässer, Tritium and Helium-3 in Metals (Springer-Verlag, Berlin Heidelberg, 1989)CrossRef

13.

J.D. Garcia, J.E. Mace, Energy level and line tables for one-electron atomic spectra. J. Opt. Soc. Am. 55, 654–661 (1965). doi:10.1364/JOSA.55.000654 CrossRef

14.

F. Waelbroeck, I. Ali-Khan, K.J. Dietz, P. Wienhold, Hydrogen solubilisation into and permeation through wall materials. J. Nucl. Mater. 85–86, 345–349 (1979). doi:10.1016/0022-3115(79)90514-2 CrossRef

15.

Y. Hatano, K. Watanabe, A.I. Livshits, A. Busnyuk, V. Alimov, Y. Nakamura, K. Hashizume, Effects of bulk impurity concentration on the reactivity of metal surface: Sticking of hydrogen molecules and atoms to polycrystalline Nb containing oxygen. J Chem Phys 127, 204707 (2007). doi:10.1063/1.2804874 CrossRef

16.

Y. Hatano, H. Nakamura, H. Furuya, M. Sugisaki, Influence of surface impurities on plasma-driven permeation of deuterium through nickel. J. Vac. Sci. Technol. A 16, 2078–2083 (1998). doi:10.1116/1.581313 CrossRef

17.

B.L. Doyle, A simple theory for maximum h inventory and release: a new transport parameter. J. Nucl. Mater. 111–112, 628–635 (1982). doi:10.1016/0022-3115(82)90277-X CrossRef

18.

D.K. Brice, B.L. Doyle, Simultaneous gas- and plasma-driven hydrogen transport in solids. J. Vac. Sci. Technol. A 5, 2311–2314 (1987). doi:10.1116/1.574442 CrossRef

19.

B. Cox, Hydrogen absorption by Zircaloy-2 and some other alloys during corrosion in steam. J. Electrochem. Soc. 109, 6–12 (1962). doi:10.1149/1.2425334 CrossRef

20.

T. Hayashi, K. Isobe, H. Nakamura, K. Kobayashi, Y. Oya, K. Okuno, M. Oyaizu, Y. Edao, T. Yamanishi, Hydrogen isotope behavior transferring through water metal boundary. Fusion Sci. Technol. 60, 369–372 (2011)

21.

T. Hayashi, H. Nakamura, K. Isobe, K. Kobayashi, M. Oyaizu, T. Yamanishi, Y. Oya, K. Okuno, Hydrogen isotope permeation from cooling water through various metal piping. Fusion Eng. Des. 87, 1333–1337 (2012). doi:10.1016/j.fusengdes.2012.03.009 CrossRef

22.

T. Hayashi, K. Isobe, H. Nakamura, K. Kobayashi, Y. Oya, K. Okuno, M. Oyaizu, Y. Edao, T. Yamanishi, Hydrogen isotope behavior on a water–metal boundary with simultaneous transfer from and to the metal surface. Fusion Eng. Des. 87, 1520–1523 (2012). doi:10.1016/j.fusengdes.2014.03.069 CrossRef

23.

M. Oyaizu, K. Isobe, H. Nakamura, T. Hayashi, T. Yamanishi, Permeation behavior of tritium through F82H steel. J. Nucl. Mater. 417, 1143–1146 (2011). doi:10.1016/j.jnucmat.2011.03.002 CrossRef

24.

L.S. Darken, R.P. Smith, Behaviour of hydrogen in steel during and after immersion in acid. Corrosion 5, 1–16 (1949). doi:10.5006/0010-9312-5.1.1 CrossRef

25.

F. Dean, Hydrogen flux measurements in petrochemical application, in Techniques for Corrosion Monitoring, ed. by L. Yang (Woodhead Publishing, Cambridge, 2008)

26.

M.A.W. Devanathan, Z. Stachurski, The adsorption and diffusion of electrolytic hydrogen in palladium. Proc. Roy. Soc. A 270, 90–102 (1962). doi:10.1098/rspa.1962.0205 CrossRef

27.

K. Fujita, Y.C. Huang, M. Tada, The studies on the equilibria of Ta-H, Nb-H, and V-H systems. J. Jpn. Inst. Met. 43, 601–610 (1979)

28.

Z.H. Qi, J. Völkl, R. Lässer, H. Wenzl, Tritium diffusion in V, Nb and Ta. J. Phys. F 13, 2053–2063 (1983). doi:10.1088/0305-4608/13/10/015 CrossRef

29.

T. Eguchi, S. Morozumi, Diffusion of hydrogen at high temperatures in the group V transition metals and alloying effect on the diffusion. J. Jpn. Inst. Met. 41, 795–802 (1977)

30.

R.W. Powers, M.V. Doyle, Diffusion of interstitial solutes in the group V transition metals. J. Appl. Phys. 30, 514–524 (1959). doi:10.1063/1.1702398 CrossRef

31.

P.E. Pawel, T.S. Lundy, The diffusion of Nb⁹⁵ and Ta¹⁸² in tantalum. J. Phys. Chem. Solids 26, 937–942 (1965). doi:10.1016/0022-3697(65)90180-0 CrossRef

32.

P. Jung, Compositional variation of hydrogen permeability in ferritic alloys and steels. J. Nucl. Mater. 238, 189–197 (1996). doi:10.1016/S0022-3115(96)00448-5 CrossRef

33.

O.G. Romanenko, I.L. Tazhibaeva, V.P. Shestakov, AKh Klepikov, Y.V. Chikhray, A.V. Golossanov, B.N. Kolbasov, Hydrogen gas driven permeation through vanadium alloy VCr6Ti5. J. Nucl. Mater. 233–237, 376–380 (1996). doi:10.1016/S0022-3115(96)00034-7 CrossRef

34.

R.E. Buxbaum, R. Subramanian, J.H. Park, D.L. Smith, Hydrogen transport and embrittlement for palladium coated vanadium—chromium—titanium alloys. J. Nucl. Mater. 233–237, 510–512 (1996). doi:10.1016/S0022-3115(96)00239-5 CrossRef

35.

I.V. Shkolnik, T.V. Kulsartov, I.L. Tazhibaeva, V.P. Shestakov, Investigation of the surface element composition influence on hydrogen permeability through vanadium alloy VCr4Ti4. Fusion Sci. Technol. 34, 868–871 (1998)

36.

R. Frauenfelder, Solution and diffusion of hydrogen in tungsten. J Vac Sci Technol 6, 388–397 (1969). doi:10.1116/1.1492699 CrossRef

37.

A.P. Zakharov, V.M. Sharapov, E.I. Evko, Hydrogen permeability of mono- and poly- crystals of molybdenum and tungsten. Fiz.-Khim. Mekh. Mater. 9, 29–33 (1973)

38.

G. Benamati, E. Serra, C.H. Wu, Hydrogen and deuterium transport and inventory parameters through W and W-alloys for fusion reactor applications. J. Nucl. Mater. 283–287, 1033–1037 (2000). doi:10.1016/S0022-3115(00)00202-6 CrossRef

39.

R.A. Anderl, D.F. Holland, G.R. Longhurst, R.J. Pawelko, C.L. Tybus, C.H. Sellers, Deuterium transport and trapping in polycrystalline tungsten. Fusion Technol. 21, 745–752 (1992)

40.

Yu. Gasparyan, M. Rasinski, M. Mayer, A. Pisarev, J. Roth, Deuterium ion-driven permeation and bulk retention in tungsten. J. Nucl. Mater. 417, 540–544 (2011). doi:10.1016/j.jnucmat.2010.12.119 CrossRef

41.

H.T. Lee, E. Markina, Y. Otsuka, Y. Ueda, Deuterium ion-driven permeation in tungsten with different microstructures. Phys. Scr. T145, 014045 (2011). doi:10.1088/0031-8949/2011/T145/014045 CrossRef

42.

H.Y. Peng, H.T. Lee, Y. Otsuka, Y. Ueda, Ion-driven permeation of deuterium in tungsten by deuterium and carbon-mixed ion irradiation. Phys. Scr. T145, 014046 (2011). doi:10.1088/0031-8949/2011/T145/014046 CrossRef

43.

H.T. Lee, H. Tanaka, Y. Otsuka, Y. Ueda, Ion-driven permeation of deuterium through tungsten under simultaneous helium and deuterium irradiation. J. Nucl. Mater. 415, S696–S700 (2011). doi:10.1016/j.jnucmat.2010.12.023 CrossRef

44.

Y. Ueda, H.T. Lee, H.Y. Peng, Y. Otsuka, Deuterium permeation in tungsten by mixed ion irradiation. Fusion Eng. Des. 87, 1356–1362 (2012). doi:10.1016/j.fusengdes.2012.03.006 CrossRef

45.

H.Y. Peng, H.T. Lee, Y. Otsuka, Y. Ueda, Effect of tungsten and carbon surface mixed layer on deuterium permeation in tungsten. J. Nucl. Mater. 438, S1063–S1066 (2013). doi:10.1016/j.jnucmat.2013.01.233 CrossRef

46.

H.T. Lee, M. Ishida, Y. Otsuka, Y. Ueda, The influence of nitrogen on deuterium permeation through tungsten. Phys. Scr. T159, 014021 (2014). doi:10.1088/0031-8949/2014/T159/014021 CrossRef

47.

T. Tanabe, Review of hydrogen retention in tungsten. Phys. Scr. T159, 014044 (2014). doi:10.1088/0031-8949/2014/T159/014044 CrossRef

48.

H. Nakamura, T. Hayashi, T. Kakuta, T. Suzuki, M. Nishi, Tritium permeation behavior implanted into pure tungsten and its isotope effect. J. Nucl. Mater. 297, 285–291 (2001). doi:10.1016/S0022-3115(01)00635-3 CrossRef

49.

J.L. Maienschein, F.E. McMurphy, V.L. Duval, Increase of tritium permeation through resistant metals at 323 K by lattice defects. Fusion Technol. 14, 701–706 (1988)

50.

K. Ikeda, T. Otsuka, T. Tanabe, Determination of hydrogen diffusivity and permeability in W near room temperature applying a tritium tracer technique. J. Nucl. Mater. 415, S684–S687 (2011). doi:10.1016/j.jnucmat.2010.12.007 CrossRef

51.

K. Ikeda, T. Otsuka, T. Tanabe, Hydrogen permeation in metals near room temperature by a tritium tracer technique. J. Nucl. Mater. 417, 568–571 (2011). doi:10.1016/j.jnucmat.2010.12.116 CrossRef

52.

G.W. Hollenberg, E.P. Simonen, G. Kalinin, A. Terlain, Tritium/hydrogen barrier development. Fusion Eng. Des. 28, 190–208 (1995). doi:10.1016/0920-3796(95)90039-X CrossRef

53.

R.A. Causey, R.A. Karnesky, C.S. Marchi, Tritium barriers and tritium diffusion in fusion reactors. Compr. Nucl. Mater. 4, 511–549 (2012). doi:10.1016/B978-0-08-056033-5.00116-6 CrossRef

54.

G.A. Esteban, A. Perujo, F. Legarda, L.A. Sedano, B. Riccardi, Deuterium transport in SiC_f/SiC composites. J. Nucl. Mater. 307–311, 1430–1435 (2002). doi:10.1016/S0022-3115(02)01282-5 CrossRef

55.

T. Chikada, A. Suzuki, T. Kobayashi, H. Maier, T. Terai, T. Muroga, Microstructure change and deuterium permeation behavior of erbium oxide coating. J. Nucl. Mater. 417, 1241–1244 (2011). doi:10.1016/j.jnucmat.2010.12.283 CrossRef

56.

R. Sato, T. Chikada, H. Matsuzaki, A. Suzuki, T. Terai, K. Sugiyama, Measurement of hydrogen isotope concentration in erbium oxide coatings. Fusion Eng. Des. 89, 1375–1379 (2014). doi:10.1016/j.fusengdes.2014.01.074 CrossRef

57.

G.W. Samsonow, W.W. Morosow, Carbohydride der Übergangsmetalle. Monats Chem. 102, 1667–1678 (1971)CrossRef

58.

A. Gringoz, N. Glandut, S. Valette, Electrochemical hydrogen storage in TiC_0.6, not in TiC_0.9. Electrochem. Commun. 11, 2044–2047 (2009). doi:10.1016/j.elecom.2009.08.049 CrossRef

59.

T. Chikada, A. Suzuki, C. Adelhelm, T. Terai, T. Muroga, Surface behaviour in deuterium permeation through erbium oxide coatings. Nucl. Fusion 51, 063023 (2011). doi:10.1088/0029-5515/51/6/063023 CrossRef

60.

Y. Hatano, K. Zhang, K. Hashizume, Fabrication of ZrO₂ coatings on ferritic steel by wet-chemical methods as a tritium permeation barrier. Phys. Scr. T145, 014044 (2011). doi:10.1088/0031-8949/2011/T145/014044 CrossRef

61.

P.G. Shewmon, Diffusion in Solids (McGraw-Hill, New York, 1963)

62.

M. Sugisaki, H. Furuya, H. Sekiya, K. Hashizume, Thermal diffusion of tritium and protium in alpha phase of zirconium. Fusion Technol. 14, 723–728 (1988)

63.

Y. Hatano, M. Shimada, VKh Alimov, J. Shi, M. Hara, T. Nozaki, Y. Oya, M. Kobayashi, K. Okuno, T. Oda, G. Cao, N. Yoshida, N. Futagami, K. Sugiyama, J. Roth, B. Tyburska-Püschel, J. Dorner, I. Takagi, M. Hatakeyama, H. Kurishita, M.A. Sokolov, Trapping of hydrogen isotopes in radiation defects formed in tungsten by neutron and ion irradiations. J. Nucl. Mater. 438, S114–S119 (2013). doi:10.1016/j.jnucmat.2013.01.018 CrossRef

64.

Y. Hatano, M. Shimada, T. Otsuka, Y. Oya, VKh Alimov, M. Hara, J. Shi, M. Kobayashi, T. Oda, G. Cao, K. Okuno, T. Tanaka, K. Sugiyama, J. Roth, B. Tyburska-Püschel, J. Dorner, N. Yoshida, N. Futagami, H. Watanabe, M. Hatakeyama, H. Kurishita, M. Sokolov, Y. Katoh, Deuterium trapping at defects created with neutron and ion irradiations in tungsten. Nucl. Fusion 53, 073006 (2013). doi:10.1088/0029-5515/53/7/073006 CrossRef

65.

Y. Chen, M.M. Abraham, H.T. Tohver, Radiation-induced diffusion of hydrogen and deuterium in MgO. Phys. Rev. Lett. 37, 1757–1760 (1976). doi:10.1103/PhysRevLett.37.1757 CrossRef

66.

Y. Chen, R. Gonzalez, K.L. Tsang, Diffusion of deuterium and hydrogen in rutile TiO₂ crystals at low temperatures. Phys. Rev. Lett. 53, 1077–1079 (1984). doi:10.1103/PhysRevLett.53.1077 CrossRef

67.

R.G. Macaulay-Newcombe, D.A. Thompson, Ion beam analysis of deuterium-implanted Al₂O₃ and tungsten. J. Nucl. Mater. 258–263, 1109–1113 (1998). doi:10.1016/S0022-3115(98)00098-1 CrossRef

68.

R.A. Strehlow, H.C. Savage, The permeation of hydrogen isotopes through structural metals at low pressures and through metals with oxide film barriers. Nucl. Technol. 22, 127–137 (1974)

69.

A.S. Zarchy, R.C. Axtmann, Tritium permeation through 304 stainless steel at ultra-low pressures. J. Nucl. Mater. 79, 110–117 (1979). doi:10.1016/0022-3115(79)90437-9 CrossRef

Titel: Permeation and Permeation Barrier
verfasst von: Yuji Hatano
Verlag: Springer Japan
Buch: Tritium: Fuel of Fusion Reactors
Print ISBN: 978-4-431-56458-4

Electronic ISBN: 978-4-431-56460-7

Copyright-Jahr: 2017
DOI: https://doi.org/10.1007/978-4-431-56460-7_9