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Erschienen in: International Journal of Plastics Technology 1/2017

24.04.2017 | Research Article

Phase morphology, mechanical, dynamic mechanical, crystallization, and thermal degradation properties of PP and PP/PS blends modified with SEBS elastomer

verfasst von: Jyotishkumar Parameswaranpillai, Seno Jose, Suchart Siengchin, Nishar Hameed

Erschienen in: International Journal of Plastics Technology | Ausgabe 1/2017

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Abstract

Binary and ternary blends comprised of polypropylene (PP), polystyrene (PS) and polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene (SEBS) were prepared. The effect of phase composition of minor components on the morphology, mechanical, viscoelastic, crystallization, and thermal degradation properties was studied. Binary blends exhibited inferior properties, typical of immiscible and incompatible multi-phase systems and showed matrix-droplet phase morphologies. Ternary blends, especially those with greater concentration of SEBS minor phase, exhibited interesting properties. Scanning electron micrographs of SEBS compatibilized PP/PS blends, did not show any PS particle pulling out of the PP matrix, indicating good compatibility of SEBS with PP/PS blends. Dynamic mechanical analysis also supported the heterogeneous phase structure of the blends. Thermogravimetry and differential scanning calorimetry showed that addition of PS and SEBS decreased the thermal stability of PP marginally, but shows slight variations in melting and crystallization behavior.

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Literatur
1.
Zurück zum Zitat Utracki Leszek A, Mukhopadhyay P, Gupta RK (2014) Chapter 1, Polymer blends introduction. In: Utracki Leszek A, Wilkie Charles A (eds) Polymer blends handbook, 2nd edn. Springer, NY Utracki Leszek A, Mukhopadhyay P, Gupta RK (2014) Chapter 1, Polymer blends introduction. In: Utracki Leszek A, Wilkie Charles A (eds) Polymer blends handbook, 2nd edn. Springer, NY
2.
Zurück zum Zitat Vuluga Z, Panaitescu DM, Radovici C, Nicolae C, Iorga MD (2012) Effect of SEBS on morphology, thermal, and mechanical properties of PP/organoclay nanocomposites. Polym Bull 69:1073–1091CrossRef Vuluga Z, Panaitescu DM, Radovici C, Nicolae C, Iorga MD (2012) Effect of SEBS on morphology, thermal, and mechanical properties of PP/organoclay nanocomposites. Polym Bull 69:1073–1091CrossRef
3.
Zurück zum Zitat Azizi A, Arefazar A, Jazani OM (2013) Effects of core-shell particles on fracture micromechanisms of PP/PC/SEBS ternary blends. Polym Plast Technol Eng 52:1595–1603CrossRef Azizi A, Arefazar A, Jazani OM (2013) Effects of core-shell particles on fracture micromechanisms of PP/PC/SEBS ternary blends. Polym Plast Technol Eng 52:1595–1603CrossRef
4.
Zurück zum Zitat Drozdov AD, Sanporean CG, Christiansen JDC (2014) Enhancement of mechanical properties of polypropylene by blending with styrene- (ethylene-butylene)-styrene tri-block copolymer. J Polym Eng 34:765–774CrossRef Drozdov AD, Sanporean CG, Christiansen JDC (2014) Enhancement of mechanical properties of polypropylene by blending with styrene- (ethylene-butylene)-styrene tri-block copolymer. J Polym Eng 34:765–774CrossRef
5.
Zurück zum Zitat Sharma R, Maiti SN (2014) Effects of crystallinity of PP and flexibility of SEBS-g-MA copolymer on the mechanical properties of PP/SEBS-g-MA blends. Polym Plast Technol Eng 53:229–238CrossRef Sharma R, Maiti SN (2014) Effects of crystallinity of PP and flexibility of SEBS-g-MA copolymer on the mechanical properties of PP/SEBS-g-MA blends. Polym Plast Technol Eng 53:229–238CrossRef
6.
Zurück zum Zitat Azizi A, Arefazar A, Jazani OM (2014) Fracture micromechanisms of polypropylene/polycarbonate/poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PP/PC/SEBS) ternary blends: the effects of SEBS content. J Macromol Sci B Phys 53:1103–1115CrossRef Azizi A, Arefazar A, Jazani OM (2014) Fracture micromechanisms of polypropylene/polycarbonate/poly(styrene-b-(ethylene-co-butylene)-b-styrene) (PP/PC/SEBS) ternary blends: the effects of SEBS content. J Macromol Sci B Phys 53:1103–1115CrossRef
7.
Zurück zum Zitat Sharma R, Maiti SN (2015) Effects of crystallinity of polypropylene (PP) on the mechanical properties of PP/styrene-ethylene-butylene-styrene-g-maleic anhydride (SEBS-g-MA)/teak wood flour (TWF) composites. Polym Bull 72:627–643CrossRef Sharma R, Maiti SN (2015) Effects of crystallinity of polypropylene (PP) on the mechanical properties of PP/styrene-ethylene-butylene-styrene-g-maleic anhydride (SEBS-g-MA)/teak wood flour (TWF) composites. Polym Bull 72:627–643CrossRef
8.
Zurück zum Zitat Lyu S (2003) Block copolymers suppressing droplet coalescence through stopping film rupture. Macromolecules 36:10052–10055CrossRef Lyu S (2003) Block copolymers suppressing droplet coalescence through stopping film rupture. Macromolecules 36:10052–10055CrossRef
9.
Zurück zum Zitat Sundararaj U (2006) Phase morphology development in polymer blends: processing and experimental aspects. In: Harrats C, Thomas S, Groeninckx G (eds) Micro- and nanostructured multiphase polymer blend systems: phase morphology and interfaces. Taylor & Francis Group, Boca Raton, pp 133–164 Sundararaj U (2006) Phase morphology development in polymer blends: processing and experimental aspects. In: Harrats C, Thomas S, Groeninckx G (eds) Micro- and nanostructured multiphase polymer blend systems: phase morphology and interfaces. Taylor & Francis Group, Boca Raton, pp 133–164
10.
Zurück zum Zitat Huang H (2011) Macro-micro and nanostructured morphologies of multiphase polymer systems, Chapter 6. In: Boudenne A, Ibos L, Candau Y, Thomas S (eds) Handbook of multiphase polymer systems, vol 1. Wiley, New York, pp 151–249 Huang H (2011) Macro-micro and nanostructured morphologies of multiphase polymer systems, Chapter 6. In: Boudenne A, Ibos L, Candau Y, Thomas S (eds) Handbook of multiphase polymer systems, vol 1. Wiley, New York, pp 151–249
11.
Zurück zum Zitat Jose S, Thomas S, Biju PK, Kargr-Kocsis J (2013) Mechanical and dynamic mechanical properties of polyolefin blends: effect of blend ratio and copolymer monomer fraction on the compatibilisation efficiency of random copolymers. J Polym Res 20:303–316CrossRef Jose S, Thomas S, Biju PK, Kargr-Kocsis J (2013) Mechanical and dynamic mechanical properties of polyolefin blends: effect of blend ratio and copolymer monomer fraction on the compatibilisation efficiency of random copolymers. J Polym Res 20:303–316CrossRef
12.
Zurück zum Zitat Parameswarnpillai J, Joseph G, Chellappan RV, Zachakariah AK, Hameed N (2015) The effect of polypropylene-graft-maleic anhydride on the morphology and dynamic mechanical properties of polypropylene/polystyrene blends. J Polym Res 22:1–11CrossRef Parameswarnpillai J, Joseph G, Chellappan RV, Zachakariah AK, Hameed N (2015) The effect of polypropylene-graft-maleic anhydride on the morphology and dynamic mechanical properties of polypropylene/polystyrene blends. J Polym Res 22:1–11CrossRef
13.
Zurück zum Zitat Parameswaranpillai J, Joseph G, Jose S, Hameed N (2015) Phase morphology, thermomechanical, and crystallization behavior of uncompatibilized and PP-g-MAH compatibilized polypropylene/polystyrene blends. J Appl Polym Sci 132:42100CrossRef Parameswaranpillai J, Joseph G, Jose S, Hameed N (2015) Phase morphology, thermomechanical, and crystallization behavior of uncompatibilized and PP-g-MAH compatibilized polypropylene/polystyrene blends. J Appl Polym Sci 132:42100CrossRef
14.
Zurück zum Zitat Dı´az MF, Barbosa SE, Capiati NJ (2005) Improvement of mechanical properties for PP/PS blends by in situ compatibilization. Polymer 46:6096–6101CrossRef Dı´az MF, Barbosa SE, Capiati NJ (2005) Improvement of mechanical properties for PP/PS blends by in situ compatibilization. Polymer 46:6096–6101CrossRef
15.
Zurück zum Zitat Waldman WR, De Paoli MA (2008) Photodegradation of polypropylene/polystyrene blends: styrene–butadiene–styrene compatibilisation effect. Polym Degrad Stabil 93:273–280CrossRef Waldman WR, De Paoli MA (2008) Photodegradation of polypropylene/polystyrene blends: styrene–butadiene–styrene compatibilisation effect. Polym Degrad Stabil 93:273–280CrossRef
16.
Zurück zum Zitat Al-Saleh MH, Sundararaj U (2008) Nanostructured carbon black filled polypropylene/polystyrene blends containing styrene–butadiene–styrene copolymer: influence of morphology on electrical resistivity. Eur Polym J 44:1931–1939CrossRef Al-Saleh MH, Sundararaj U (2008) Nanostructured carbon black filled polypropylene/polystyrene blends containing styrene–butadiene–styrene copolymer: influence of morphology on electrical resistivity. Eur Polym J 44:1931–1939CrossRef
17.
Zurück zum Zitat Li Y, Hu S, Sheng J (2007) Evolution of phase dimensions and interfacial morphology of polypropylene/polystyrene compatibilized blends during mixing. Eur Polym J 43:561–572CrossRef Li Y, Hu S, Sheng J (2007) Evolution of phase dimensions and interfacial morphology of polypropylene/polystyrene compatibilized blends during mixing. Eur Polym J 43:561–572CrossRef
18.
Zurück zum Zitat Lin BH, Du MC, Zhu YJ, Liang YW (2014) Non-isothermal crystallization behavior and kinetics of compatibilized β nucleated polypropylene/polystyrene blends. Adv Mater Res 893:291–294CrossRef Lin BH, Du MC, Zhu YJ, Liang YW (2014) Non-isothermal crystallization behavior and kinetics of compatibilized β nucleated polypropylene/polystyrene blends. Adv Mater Res 893:291–294CrossRef
19.
Zurück zum Zitat de Freitas CA, Valera TS, de Souza AMC, Demarquette NR (2007) Morphology of compatibilized ternary blends. Macromol Symp 247:260–270CrossRef de Freitas CA, Valera TS, de Souza AMC, Demarquette NR (2007) Morphology of compatibilized ternary blends. Macromol Symp 247:260–270CrossRef
20.
Zurück zum Zitat Wang D, Li Y, Xie XM, Guo BH (2011) Compatibilization and morphology development of immiscible ternary polymer blends. Polymer 52:191–200CrossRef Wang D, Li Y, Xie XM, Guo BH (2011) Compatibilization and morphology development of immiscible ternary polymer blends. Polymer 52:191–200CrossRef
21.
Zurück zum Zitat Le Corroller P, Favis BD (2011) Effect of viscosity in ternary polymer blends displaying partial wetting phenomena. Polymer 52:3827–3834CrossRef Le Corroller P, Favis BD (2011) Effect of viscosity in ternary polymer blends displaying partial wetting phenomena. Polymer 52:3827–3834CrossRef
22.
Zurück zum Zitat Ravati S, Favis BD (2013) Tunable morphologies for ternary blends with poly(butylene succinate): partial and complete wetting phenomena. Polymer 54:3271–3281CrossRef Ravati S, Favis BD (2013) Tunable morphologies for ternary blends with poly(butylene succinate): partial and complete wetting phenomena. Polymer 54:3271–3281CrossRef
23.
Zurück zum Zitat Rastin H, Jafari SH, Saeb MR, Khonakdar HA, Wagenknecht U, Heinrich G (2014) On the reliability of existing theoretical models in anticipating type of morphology and domain size in HDPE/PA-6/EVOH ternary blends. Eur Polym J 53:1–12CrossRef Rastin H, Jafari SH, Saeb MR, Khonakdar HA, Wagenknecht U, Heinrich G (2014) On the reliability of existing theoretical models in anticipating type of morphology and domain size in HDPE/PA-6/EVOH ternary blends. Eur Polym J 53:1–12CrossRef
24.
Zurück zum Zitat Kolahchi AR, Ajji A, Carreau PJ (2014) Surface morphology and properties of ternary polymer blends: effect of the migration of minor components. J Phys Chem B 118:6316–6323CrossRef Kolahchi AR, Ajji A, Carreau PJ (2014) Surface morphology and properties of ternary polymer blends: effect of the migration of minor components. J Phys Chem B 118:6316–6323CrossRef
25.
Zurück zum Zitat Dou R, Wang W, Zhou Y, Li L, Gong L, Yin B, Yang M (2013) Effect of core-shell morphology evolution on the rheology, crystallization, and mechanical properties of PA6/EPDM-g-MA/HDPE ternary blend. J Appl Polym Sci 129:253–262CrossRef Dou R, Wang W, Zhou Y, Li L, Gong L, Yin B, Yang M (2013) Effect of core-shell morphology evolution on the rheology, crystallization, and mechanical properties of PA6/EPDM-g-MA/HDPE ternary blend. J Appl Polym Sci 129:253–262CrossRef
26.
Zurück zum Zitat Abreu FOMS, Forte MMC, Liberman SA (2005) SBS and SEBS block copolymers as impact modifiers for polypropylene compounds. J Appl Polym Sci 95:254–263CrossRef Abreu FOMS, Forte MMC, Liberman SA (2005) SBS and SEBS block copolymers as impact modifiers for polypropylene compounds. J Appl Polym Sci 95:254–263CrossRef
27.
Zurück zum Zitat Parameswaranpillai J, Joseph G, Shinu KP, Sreejesh PR, Jose S, Salim NV, Hameed N (2015) The role of SEBS in tailoring the interface between the polymer matrix and exfoliated graphene nanoplatelets in hybrid composites. Mater Chem Phys 163:182–189CrossRef Parameswaranpillai J, Joseph G, Shinu KP, Sreejesh PR, Jose S, Salim NV, Hameed N (2015) The role of SEBS in tailoring the interface between the polymer matrix and exfoliated graphene nanoplatelets in hybrid composites. Mater Chem Phys 163:182–189CrossRef
28.
Zurück zum Zitat Parameswaranpillai J, Joseph G, Shinu KP, Jose S, Salim NV, Hameed N (2015) Development of hybrid composites for automotive applications: effect of addition of SEBS on the morphology, mechanical, viscoelastic, crystallization and thermal degradation properties of PP/PS–xGnP composites. RSC Adv 33:25634–25641CrossRef Parameswaranpillai J, Joseph G, Shinu KP, Jose S, Salim NV, Hameed N (2015) Development of hybrid composites for automotive applications: effect of addition of SEBS on the morphology, mechanical, viscoelastic, crystallization and thermal degradation properties of PP/PS–xGnP composites. RSC Adv 33:25634–25641CrossRef
29.
Zurück zum Zitat Van der Wal A, Mulder JJ, Gaymans RJ (1998) Fracture of polypropylene: the effect of crystallinity. Polymer 39:5477–5481CrossRef Van der Wal A, Mulder JJ, Gaymans RJ (1998) Fracture of polypropylene: the effect of crystallinity. Polymer 39:5477–5481CrossRef
30.
Zurück zum Zitat Karger-Kocsis J, Kalló A, Szafner A, Bodor G, Zs Sényei (1979) Morphological study on the effect of elastomeric impact modifiers in polypropylene systems. Polymer 20:37–43CrossRef Karger-Kocsis J, Kalló A, Szafner A, Bodor G, Zs Sényei (1979) Morphological study on the effect of elastomeric impact modifiers in polypropylene systems. Polymer 20:37–43CrossRef
31.
Zurück zum Zitat Tortorella N, Beatty CL (2008) Morphology and mechanical properties of impact modified polypropylene blends. Polym Eng Sci 48:2098–2110CrossRef Tortorella N, Beatty CL (2008) Morphology and mechanical properties of impact modified polypropylene blends. Polym Eng Sci 48:2098–2110CrossRef
32.
Zurück zum Zitat Macau´bas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554CrossRef Macau´bas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554CrossRef
33.
Zurück zum Zitat Ismail HH, Nasir M (2002) Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend. Polym Test 21:263–267CrossRef Ismail HH, Nasir M (2002) Morphological studies of uncompatibilized and compatibilized polystyrene/polypropylene blend. Polym Test 21:263–267CrossRef
34.
Zurück zum Zitat Wildes G, Keskkula H, Paul DR (1999) Coalescence in PC/SAN blends: effect of reactive compatibilization and matrix phase viscosity. Polymer 40:5609–5621CrossRef Wildes G, Keskkula H, Paul DR (1999) Coalescence in PC/SAN blends: effect of reactive compatibilization and matrix phase viscosity. Polymer 40:5609–5621CrossRef
35.
Zurück zum Zitat Welander M, Rigdahl M (1989) Use of an emulsifying block copolymer to improve time-dependent mechanical properties of polyethylene-polystyrene blends. Polymer 30:207–212CrossRef Welander M, Rigdahl M (1989) Use of an emulsifying block copolymer to improve time-dependent mechanical properties of polyethylene-polystyrene blends. Polymer 30:207–212CrossRef
36.
Zurück zum Zitat Manglio G, Palumbo R (1984) Polymer blends, processing, morphology and properties. Plenum press, New York, p 41 Manglio G, Palumbo R (1984) Polymer blends, processing, morphology and properties. Plenum press, New York, p 41
37.
Zurück zum Zitat Bassani A, Pessan LA, Hage E (2001) Toughening of polypropylene with styrene/ethylene-butylene/styrene tri-block copolymer: effects of mixing condition and elastomer content. J Appl Polym Sci 82:2185–2193CrossRef Bassani A, Pessan LA, Hage E (2001) Toughening of polypropylene with styrene/ethylene-butylene/styrene tri-block copolymer: effects of mixing condition and elastomer content. J Appl Polym Sci 82:2185–2193CrossRef
38.
Zurück zum Zitat Mcgrath GC, Fracture and toughening in fiber reinforced polymer composites, in rubber toughened engineering plastics, Chapman & hall, 1994, 61 Mcgrath GC, Fracture and toughening in fiber reinforced polymer composites, in rubber toughened engineering plastics, Chapman & hall, 1994, 61
39.
Zurück zum Zitat Balkan O, Demirer H, Kayali ES (2011) Effects of deformation rates on mechanical properties of PP/SEBS blends. J Achiev Mater Manuf Eng 47:26–33 Balkan O, Demirer H, Kayali ES (2011) Effects of deformation rates on mechanical properties of PP/SEBS blends. J Achiev Mater Manuf Eng 47:26–33
40.
Zurück zum Zitat Brostow W, Grguric TH, Olea-Mejia O, Pietkiewicz D, Rek V (2008) Polypropylene + polystyrene blends with a compatibilizer. Part 2. Tribological and mechanical properties. e-Polymers, no. 034 Brostow W, Grguric TH, Olea-Mejia O, Pietkiewicz D, Rek V (2008) Polypropylene + polystyrene blends with a compatibilizer. Part 2. Tribological and mechanical properties. e-Polymers, no. 034
41.
Zurück zum Zitat Samsudin SA, Hassan A, Mokhtar M, Jamaluddin SMS (2005) Effect of SEBS on the mechanical properties and miscibility of polystyrene rich polystyrene/polypropylene blends. Prog Rubber Plast Recycl Technol 21:261–276 Samsudin SA, Hassan A, Mokhtar M, Jamaluddin SMS (2005) Effect of SEBS on the mechanical properties and miscibility of polystyrene rich polystyrene/polypropylene blends. Prog Rubber Plast Recycl Technol 21:261–276
42.
Zurück zum Zitat Ahmad Z, Kumar KD, Saroop M, Preschilla N, Biswas A, Bellare JB, Bhowmick AK (2010) Highly transparent thermoplastic elastomer from isotactic polypropylene and styrene/ethylene-butylene/styrene triblock copolymer: structure-property correlations. Polym Eng Sci 50:331–341CrossRef Ahmad Z, Kumar KD, Saroop M, Preschilla N, Biswas A, Bellare JB, Bhowmick AK (2010) Highly transparent thermoplastic elastomer from isotactic polypropylene and styrene/ethylene-butylene/styrene triblock copolymer: structure-property correlations. Polym Eng Sci 50:331–341CrossRef
43.
Zurück zum Zitat Zhao X, Huang Y, Kong M, Yang Q, Li G (2014) Retarded stress and morphology relaxation of deformed polymer blends in the presence of a triblock copolymer. RSC Adv 4:59302–59309CrossRef Zhao X, Huang Y, Kong M, Yang Q, Li G (2014) Retarded stress and morphology relaxation of deformed polymer blends in the presence of a triblock copolymer. RSC Adv 4:59302–59309CrossRef
44.
Zurück zum Zitat Liao CZ, Tjong SC (2011) Effects of carbon nanofibers on the fracture, mechanical, and thermal properties of PP/SEBS-g-MA blends. Polym Eng Sci 51:948–958CrossRef Liao CZ, Tjong SC (2011) Effects of carbon nanofibers on the fracture, mechanical, and thermal properties of PP/SEBS-g-MA blends. Polym Eng Sci 51:948–958CrossRef
Metadaten
Titel
Phase morphology, mechanical, dynamic mechanical, crystallization, and thermal degradation properties of PP and PP/PS blends modified with SEBS elastomer
verfasst von
Jyotishkumar Parameswaranpillai
Seno Jose
Suchart Siengchin
Nishar Hameed
Publikationsdatum
24.04.2017
Verlag
Springer India
Erschienen in
International Journal of Plastics Technology / Ausgabe 1/2017
Print ISSN: 0972-656X
Elektronische ISSN: 0975-072X
DOI
https://doi.org/10.1007/s12588-017-9172-9

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