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2016 | OriginalPaper | Buchkapitel

28. Photocatalytic CO₂ Reduction to CO by ZIF-9/TiO₂

verfasst von : Sibo Wang, Xinchen Wang

Erschienen in: Nanostructured Photocatalysts

Verlag: Springer International Publishing

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Abstract

Cocatalyst is crucial to the surface kinetic promotion of CO₂ photoreduction reaction, because it can accelerate the transport of photoinduced electrons as well as lower the activation energy or overpotential for CO₂ conversion reactions. Herein, we present the use of a cobalt-containing zeolitic imidazolate framework (ZIF-9) as a noble-metal-free multifunctional cocatalyst for enhancing the photocatalytic reduction of CO₂ to CO by TiO₂ photocatalysis. ZIF-9 features the functions of promoting the adsorption/activation of CO₂, and facilitating the transfer of photogenerated electrons. By cooperating with TiO₂ as a semiconductor photocatalyst to generate energized electrons and holes, ZIF-9 effectively boosted the CO₂-to-CO transformation catalysis under simulated sunlight irradiation. Reaction conditions such as the reaction temperature, the reaction solvent, the type of the electron donor, and the water ratio in the reaction medium were investigated and optimized for operating effective CO₂ reduction reactions mediated by the TiO₂ semiconductor.

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Titel: Photocatalytic CO2 Reduction to CO by ZIF-9/TiO2
verfasst von: Sibo Wang
Xinchen Wang
Verlag: Springer International Publishing
Buch: Nanostructured Photocatalysts
Print ISBN: 978-3-319-26077-8

Electronic ISBN: 978-3-319-26079-2

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/978-3-319-26079-2_28

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