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2017 | OriginalPaper | Buchkapitel

2. Platforms for Functionalization of Cellulose

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Abstract

The shaping, chemical modification, and functionalization of cellulose are largely depended on the process of dissolution in an efficient solvent. Viscose process as the most important method for production of cellulose-regenerated materials was introduced. The dissolution of cellulose in several other most frequently used eco-friendly solvents was also discussed, including cellulose carbamate, N-methylmorpholine-N-oxide, aqueous alkali system, and ionic liquids. These processes provide efficient platforms for development of new regenerated materials and other products based on cellulose.

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Literatur
1.
Zurück zum Zitat Hermanutz F, Gähr F, Uerdingen E et al (2008) New developments in dissolving and processing of cellulose in ionic liquids. Macromol Symp 262:23–27CrossRef Hermanutz F, Gähr F, Uerdingen E et al (2008) New developments in dissolving and processing of cellulose in ionic liquids. Macromol Symp 262:23–27CrossRef
2.
Zurück zum Zitat Klemm D, Heublein B, Fink H-P et al (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44:3358–3393CrossRef Klemm D, Heublein B, Fink H-P et al (2005) Cellulose: fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44:3358–3393CrossRef
3.
Zurück zum Zitat Cross CF, Bevan EJ, Beadle C (1894) US Patent 520770 Cross CF, Bevan EJ, Beadle C (1894) US Patent 520770
4.
Zurück zum Zitat Hill JW, Jacobson RA (1938) Method for manufacturing cellulose carbamate. US Patent 2134825 Hill JW, Jacobson RA (1938) Method for manufacturing cellulose carbamate. US Patent 2134825
5.
Zurück zum Zitat Fink H-P, Ganster J, Lehmann A (2014) Progress in cellulose shaping: 20 years industrial case studies at Fraunhofer IAP. Cellulose 21:31–51CrossRef Fink H-P, Ganster J, Lehmann A (2014) Progress in cellulose shaping: 20 years industrial case studies at Fraunhofer IAP. Cellulose 21:31–51CrossRef
6.
Zurück zum Zitat Yin C, Shen X (2007) Synthesis of cellulose carbamate by supercritical CO2-assisted impregnation: structure and rheological properties. Eur Polym J 43:2111–2116CrossRef Yin C, Shen X (2007) Synthesis of cellulose carbamate by supercritical CO2-assisted impregnation: structure and rheological properties. Eur Polym J 43:2111–2116CrossRef
7.
Zurück zum Zitat Guo Y, Zhou J, Song Y et al (2009) An efficient and environmentally friendly method for the synthesis of cellulose carbamate by microwave heating. Macromol Rapid Commun 30:1504–1508CrossRef Guo Y, Zhou J, Song Y et al (2009) An efficient and environmentally friendly method for the synthesis of cellulose carbamate by microwave heating. Macromol Rapid Commun 30:1504–1508CrossRef
8.
Zurück zum Zitat Fu F, Zhou J, Zhou X et al (2014) Green method for the production of cellulose multifilament from cellulose carbamate on a pilot-scale. ACS Sustain Chem Eng 2:2363–2370CrossRef Fu F, Zhou J, Zhou X et al (2014) Green method for the production of cellulose multifilament from cellulose carbamate on a pilot-scale. ACS Sustain Chem Eng 2:2363–2370CrossRef
9.
Zurück zum Zitat Fu F, Guo Y, Wang Y et al (2014) Structure and properties of the regenerated cellulose membranes prepared from cellulose carbamate in NaOH/ZnO aqueous solution. Cellulose 212:819–830 Fu F, Guo Y, Wang Y et al (2014) Structure and properties of the regenerated cellulose membranes prepared from cellulose carbamate in NaOH/ZnO aqueous solution. Cellulose 212:819–830
10.
Zurück zum Zitat Fu F, Yang Q, Zhou J et al (2014) Structure and properties of regenerated cellulose filaments prepared from cellulose carbamate−NaOH/ZnO aqueous Solution. ACS Sustain Chem Eng 2:2604–2612CrossRef Fu F, Yang Q, Zhou J et al (2014) Structure and properties of regenerated cellulose filaments prepared from cellulose carbamate−NaOH/ZnO aqueous Solution. ACS Sustain Chem Eng 2:2604–2612CrossRef
11.
Zurück zum Zitat Graenacher C, Sallmann R (1936) Assisting agents for the textile industry. US patent 2060568 A Graenacher C, Sallmann R (1936) Assisting agents for the textile industry. US patent 2060568 A
12.
Zurück zum Zitat Johnson DL (1969) Compounds dissolved in cyclic amine oxides. US patent 3447939 A Johnson DL (1969) Compounds dissolved in cyclic amine oxides. US patent 3447939 A
13.
Zurück zum Zitat Fink H-P, Weigel P, Purz H et al (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473–1524CrossRef Fink H-P, Weigel P, Purz H et al (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473–1524CrossRef
14.
Zurück zum Zitat Rosenau T, Potthast A, Sixta H et al (2001) The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process). Prog Polym Sci 26:1763–1837CrossRef Rosenau T, Potthast A, Sixta H et al (2001) The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process). Prog Polym Sci 26:1763–1837CrossRef
15.
Zurück zum Zitat Maia E, Peguy A, Perez S (1981) Cellulose organic solvents. I. the structures of anhydrous N-methylmorpholine N-oxide and N-methylmorpholine N-oxide monohydrate. Acta Cryst B37:1858–1862CrossRef Maia E, Peguy A, Perez S (1981) Cellulose organic solvents. I. the structures of anhydrous N-methylmorpholine N-oxide and N-methylmorpholine N-oxide monohydrate. Acta Cryst B37:1858–1862CrossRef
16.
Zurück zum Zitat Rosenau T, Potthast A, Adorjan I et al (2002) Cellulose solutions in N-methylmorpholine-N-oxide (NMMO)—degradation processes and stabilizers. Cellulose 9:283–291CrossRef Rosenau T, Potthast A, Adorjan I et al (2002) Cellulose solutions in N-methylmorpholine-N-oxide (NMMO)—degradation processes and stabilizers. Cellulose 9:283–291CrossRef
17.
Zurück zum Zitat Sobue H, Kiessig H, Hess K (1939) The system: cellulose-sodium hydroxide-water in relation to the temperature. Z Phys Chem B43:309–328 Sobue H, Kiessig H, Hess K (1939) The system: cellulose-sodium hydroxide-water in relation to the temperature. Z Phys Chem B43:309–328
18.
Zurück zum Zitat Kamide K, Okajima K, Matsui T et al (1984) Study on the solubility of cellulose in aqueous alkali solution by deuteration IR and 13C NMR. Polymer 16:857–866CrossRef Kamide K, Okajima K, Matsui T et al (1984) Study on the solubility of cellulose in aqueous alkali solution by deuteration IR and 13C NMR. Polymer 16:857–866CrossRef
19.
Zurück zum Zitat Yamane C, Saito M, Okajima K (1996) Manufacture of new cellulosic fibers from a spinning bath of an aqueous solution of alkali—soluble cellulose and caustic soda. Part 1. Development of a method for industrial preparation of an aqueous solution of highly soluble cellulose and caustic soda. Sen’i Gakkaish Yamane C, Saito M, Okajima K (1996) Manufacture of new cellulosic fibers from a spinning bath of an aqueous solution of alkali—soluble cellulose and caustic soda. Part 1. Development of a method for industrial preparation of an aqueous solution of highly soluble cellulose and caustic soda. Sen’i Gakkaish
20.
Zurück zum Zitat Isogai A, Atalla RH (1998) Dissolution of cellulose in aqueous solutions. Cellulose 5:309–319CrossRef Isogai A, Atalla RH (1998) Dissolution of cellulose in aqueous solutions. Cellulose 5:309–319CrossRef
21.
Zurück zum Zitat Egal M, Budtova T, Navard P (2008) The dissolution of microcrystalline cellulose in sodium hydroxide-urea aqueous solutions. Cellulose 15:361–370CrossRef Egal M, Budtova T, Navard P (2008) The dissolution of microcrystalline cellulose in sodium hydroxide-urea aqueous solutions. Cellulose 15:361–370CrossRef
22.
Zurück zum Zitat Zhou J, Zhang L (2000) The solubility of cellulose in NaOH/ urea aqueous solution. Polym J 10:866–870CrossRef Zhou J, Zhang L (2000) The solubility of cellulose in NaOH/ urea aqueous solution. Polym J 10:866–870CrossRef
23.
Zurück zum Zitat Cai J, Zhang L (2005) Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions. Macromol Biosci 5:539–548CrossRef Cai J, Zhang L (2005) Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions. Macromol Biosci 5:539–548CrossRef
24.
Zurück zum Zitat Qi H, Chang C, Zhang L (2009) Properties and applications of biodegradable transparent and photoluminescent cellulose films prepared via a green process. Green Chem 11:177–184CrossRef Qi H, Chang C, Zhang L (2009) Properties and applications of biodegradable transparent and photoluminescent cellulose films prepared via a green process. Green Chem 11:177–184CrossRef
25.
Zurück zum Zitat Ruan D, Zhang L, Zhou J et al (2004) Structure and properties of novel fibers spun from cellulose in NaOH/thiourea aqueous solution. Macromol Biosci 4:1105–1112CrossRef Ruan D, Zhang L, Zhou J et al (2004) Structure and properties of novel fibers spun from cellulose in NaOH/thiourea aqueous solution. Macromol Biosci 4:1105–1112CrossRef
26.
Zurück zum Zitat Yan L, Gao Z (2008) Dissolving of cellulose in PEG/NaOH aqueous solution. Cellulose 15:789–796CrossRef Yan L, Gao Z (2008) Dissolving of cellulose in PEG/NaOH aqueous solution. Cellulose 15:789–796CrossRef
27.
Zurück zum Zitat Qi H, Yang Q, Zhang L et al (2011) The dissolution of cellulose in NaOH-based aqueous system by two-step process. Cellulose 18:237–245CrossRef Qi H, Yang Q, Zhang L et al (2011) The dissolution of cellulose in NaOH-based aqueous system by two-step process. Cellulose 18:237–245CrossRef
28.
Zurück zum Zitat Cai J, Zhang L, Liu S et al (2008) Dynamic self-assembly induced rapid dissolution of cellulose at low temperatures. Macromolecules 41:9345–9351CrossRef Cai J, Zhang L, Liu S et al (2008) Dynamic self-assembly induced rapid dissolution of cellulose at low temperatures. Macromolecules 41:9345–9351CrossRef
29.
Zurück zum Zitat Cai J, Zhang L, Zhou J et al (2007) Multifilament fibers based on dissolution of cellulose in NaOH/urea aqueous solution: structure and properties. Adv Mater 19:821–825CrossRef Cai J, Zhang L, Zhou J et al (2007) Multifilament fibers based on dissolution of cellulose in NaOH/urea aqueous solution: structure and properties. Adv Mater 19:821–825CrossRef
30.
Zurück zum Zitat Zhu S, Wu Y, Chen Q et al (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8:325–327CrossRef Zhu S, Wu Y, Chen Q et al (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8:325–327CrossRef
31.
Zurück zum Zitat Bentivoglio G, Röder T, Fasching M et al (2006) Cellulose processing with chloride-based ionic liquids. Lenzinger Ber 86:154–161 Bentivoglio G, Röder T, Fasching M et al (2006) Cellulose processing with chloride-based ionic liquids. Lenzinger Ber 86:154–161
32.
Zurück zum Zitat Swatloski RP, Spear SK, Holbrey JD et al (2002) Dissolution of cellulose with ionic liquids. J Am Chem Soc 124:4974–4975CrossRef Swatloski RP, Spear SK, Holbrey JD et al (2002) Dissolution of cellulose with ionic liquids. J Am Chem Soc 124:4974–4975CrossRef
33.
Zurück zum Zitat Gericke M, Fardim P, Heinze T (2012) Ionic liquids—promising but challenging solvents for homogeneous derivatization of cellulose. Molecules 17:7458–7502CrossRef Gericke M, Fardim P, Heinze T (2012) Ionic liquids—promising but challenging solvents for homogeneous derivatization of cellulose. Molecules 17:7458–7502CrossRef
34.
Zurück zum Zitat Pinkert A, Marsh KN, Pang S et al (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712–6728CrossRef Pinkert A, Marsh KN, Pang S et al (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712–6728CrossRef
35.
Zurück zum Zitat Feng L, Chen Z (2008) Research progress on dissolution and functional modification of cellulose in ionic liquids. J Mol Liq 142:1–5CrossRef Feng L, Chen Z (2008) Research progress on dissolution and functional modification of cellulose in ionic liquids. J Mol Liq 142:1–5CrossRef
36.
Zurück zum Zitat King AWT, Asikkala J, Mutikainen I et al (2011) Distillable acid–base conjugate ionic liquids for cellulose dissolution and processing. Angew Chem Int Ed 50:6301–6305CrossRef King AWT, Asikkala J, Mutikainen I et al (2011) Distillable acid–base conjugate ionic liquids for cellulose dissolution and processing. Angew Chem Int Ed 50:6301–6305CrossRef
37.
Zurück zum Zitat Abe M, Fukaya Y, Ohno H (2012) Fast and facile dissolution of cellulose with tetrabutylphosphonium hydroxide containing 40 wt% water. Chem Commun 48:1808–1810CrossRef Abe M, Fukaya Y, Ohno H (2012) Fast and facile dissolution of cellulose with tetrabutylphosphonium hydroxide containing 40 wt% water. Chem Commun 48:1808–1810CrossRef
38.
Zurück zum Zitat Kosan B, Michels C, Meister F (2008) Dissolution and forming of cellulose with ionic liquids. Cellulose 15:59–66CrossRef Kosan B, Michels C, Meister F (2008) Dissolution and forming of cellulose with ionic liquids. Cellulose 15:59–66CrossRef
39.
Zurück zum Zitat Heinze T, Schwikal K, Barthel S (2005) Ionic liquids as reaction medium in cellulose functionalization. Macromol Biosci 5:520–525CrossRef Heinze T, Schwikal K, Barthel S (2005) Ionic liquids as reaction medium in cellulose functionalization. Macromol Biosci 5:520–525CrossRef
40.
Zurück zum Zitat Sun N, Rahman M, Qin Y et al (2009) Complete dissolution and partial delignification of wood in the ionic liquid 1-ethyl-3-methylimidazolium acetate. Green Chem 11:646–655CrossRef Sun N, Rahman M, Qin Y et al (2009) Complete dissolution and partial delignification of wood in the ionic liquid 1-ethyl-3-methylimidazolium acetate. Green Chem 11:646–655CrossRef
Metadaten
Titel
Platforms for Functionalization of Cellulose
verfasst von
Haisong Qi
Copyright-Jahr
2017
DOI
https://doi.org/10.1007/978-3-319-49592-7_2

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