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Erschienen in: Journal of Materials Science: Materials in Electronics 12/2015

10.04.2015

PLZT film capacitors for power electronics and energy storage applications

verfasst von: Beihai Ma, Zhongqiang Hu, Rachel E. Koritala, Tae H. Lee, Stephen E. Dorris, Uthamalingam Balachandran

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 12/2015

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Abstract

Ceramic film capacitors with high dielectric constant and high breakdown strength hold special promise for applications demanding high power density. By means of chemical solution deposition, we deposited ≈2-μm-thick films of lanthanum-doped lead zirconate titanate (PLZT) on LaNiO3-buffered Ni (LNO/Ni) foils and platinized silicon (PtSi) substrates. The dielectric properties and energy storage performance of the resulting samples were determined under a high level of applied electric field. X-ray diffraction stress analysis revealed that PLZT on LNO/Ni bears a compressive stress of ≈370 MPa while PLZT on PtSi endures a tensile stress of ≈250 MPa. Compressive stress was found to lead to heightened polarization, improved tunability, increased irreversible domain wall motion, and enhanced breakdown strength for PLZT deposited on the LNO/Ni as compared with the PtSi substrate. We observed a tunability of ≈55 and ≈40 % at room temperature under 100 kV/cm applied field, remanent polarization of ≈23.5 and ≈7.4 µC/cm2, coercive electric field of ≈25.6 and ≈21.1 kV/cm, and dielectric breakdown strength of ≈2.6 and ≈1.5 MV/cm for PLZT deposited on LNO/Ni foils and PtSi substrates, respectively. A high recoverable energy density of ≈85 J/cm3 and energy conversion efficiency of ≈65 % were measured on the PLZT film grown on LNO/Ni.

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Metadaten
Titel
PLZT film capacitors for power electronics and energy storage applications
verfasst von
Beihai Ma
Zhongqiang Hu
Rachel E. Koritala
Tae H. Lee
Stephen E. Dorris
Uthamalingam Balachandran
Publikationsdatum
10.04.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 12/2015
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-3025-0

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