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Polymer Bulletin
Erschienen in: Polymer Bulletin 4/2018

05.07.2017 | Original Paper

Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application

verfasst von: Buket Bezgin Carbas, Burak Tekin

Erschienen in: Polymer Bulletin | Ausgabe 4/2018

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Abstract

Poly(3,4-ethylenedioxythiophene) polymer film (PEDOT-IL) was electrosynthesized in the ionic liquid (IL) 1-ethyl-3-methylimidazolium hydrogen sulphate (EMIMHSO4) medium, which also contains 0.1 M LiClO4 in ACN. For comparison reasons in terms of structure and electrode capacitance performance, PEDOT film was also synthesized electrochemically without IL. The SEM results show that PEDOT-IL film has more porous surface and fine textures with nanometer-diameter than PEDOT polymer. Different electrochemical methods including galvanostatic charge–discharge (CD) experiments, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were carried out to investigate the applicability of the system as a redox supercapacitor for both polymers. PEDOT-IL electrode shows higher optimum specific capacitance than PEDOT film. Additionally, the symmetrical supercapacitor was assembled from two PEDOT-IL electrodes in LiClO4/ACN medium and exhibited a maximum specific capacitance of 107 F g−1, an energy density of 11.5 Wh kg−1 at a power density 13 kW kg−1, and an excellent cycle life of 96% specific capacitance retention after 1000 cycles.
Vorheriger Artikel Refraction and polarization properties of some fluorinated imidic polymers
Nächster Artikel CoCl2-doped polyaniline composites as electrode materials with enhanced electrochemical performance for supercapacitor application

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Metadaten
Titel
Poly(3,4-ethylenedioxythiophene) electrode grown in the presence of ionic liquid and its symmetrical electrochemical supercapacitor application
verfasst von
Buket Bezgin Carbas
Burak Tekin
Publikationsdatum
05.07.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 4/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2111-2

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