nach oben

Cellulose

Erschienen in:

27.03.2020 | Original Research

Poly(ethylene glycol)-grafted nanofibrillated cellulose/graphene hybrid aerogels supported phase change composites with superior energy storage capacity and solar-thermal conversion efficiency

verfasst von: Xiaosheng Du, Mi Zhou, Sha Deng, Zongliang Du, Xu Cheng, Haibo Wang

Erschienen in: Cellulose | Ausgabe 8/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The development of organic phase change materials (PCMs) with large energy storage capacity, high thermal conductivity, and satisfactory solar-thermal conversion performance is critical for large-scale solar energy utilization. Here, novel composite PCMs based on poly(ethylene glycol) (PEG), nanofibrillated cellulose (NFC), and graphene were successfully fabricated by impregnating PEG into PEG-grafted NFC/graphene hybrid aerogels (GA/NFC-g-PEG). The GA/NFC-g-PEG with three-dimensional interconnected porous structures well supported the PEG within the nanostructural frameworks and effectively prevented the leakage and diffusion of PEG above its melting point. Grafting of PEG onto NFC was performed to improve the affinity between PEG and NFC/graphene hybrid aerogels, which significantly increased the PEG loading capacity of the CNF-g-PEG/graphene aerogel and prevented the leakage of PEG. Differential scanning calorimetry result showed that the as-prepared composite PCMs possessed extremely high melting enthalpies ranging from 185.5 to 187.4 J/g. The hot stage-digital camera test and thermogravimetric analyses showed that the composite PCMs exhibited excellent form-stability and thermal stability. Moreover, the introduction of graphene significantly increased the thermal conductivity and solar-thermal conversion efficiency of the composite PCMs. In conclusion, the synthesized composite PCMs showed tremendous potential for thermal energy storage applications.

Vorheriger Artikel All-cellulose composite membranes for oil microdroplet collection

Nächster Artikel Superhydrophobic–superoleophilic copper–graphite/styrene–butadiene–styrene based cotton filter for efficient separation of oil derivatives from aqueous mixtures

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Ali HM, Arshad A, Jabbal M, Verdin PG (2018) Thermal management of electronics devices with PCMs filled pin-fin heat sinks: a comparison. Int J Heat Mass Transf 117:1199–1204CrossRef

Chen K, Liu R, Zou C, Shao Q, Lan Y, Cai X (2014) Linear polyurethane ionomers as solid–solid phase change materials for thermal energy storage. Sol Energy Mater Sol Cells 130:466–473CrossRef

Chen C, Liu W, Wang Z, Peng K, Pan W, Xie Q (2015a) Novel form stable phase change materials based on the composites of polyethylene glycol/polymeric solid–solid phase change material. Sol Energy Mater Sol Cells 134:80–88CrossRef

Chen C, Liu W, Wang H, Peng K (2015b) Synthesis and performances of novel solid–solid phase change materials with hexahydroxy compounds for thermal energy storage. Appl Energy 152:198–206CrossRef

Chen Y, Ding H, Gao J, Tang X, Liu Y, Yang M (2020) A novel strategy for enhancing the thermal conductivity of shape-stable phase change materials via carbon-based in situ reduction of metal ions. J Clean Prod 243:118627–118634CrossRef

Du X, Wang S, Du Z, Cheng X, Wang H (2018a) Preparation and characterization of flame-retardant nanoencapsulated phase change materials with poly(methylmethacrylate) shells for thermal energy storage. J Mater Chem A 6:17519–17529CrossRef

Du X, Fang Y, Cheng X, Du Z, Mi Zhou, Wang H (2018b) Fabrication and characterization of flame-retardant nanoencapsulated n-octadecane with melamine-formaldehyde shell for thermal energy storage. ACS Sustain Chem Eng 6:15541–15549CrossRef

Du X, Xu J, Deng S, Du Z, Cheng X, Wang H (2019) Amino-functionalized single-walled carbon nanotubes-integrated polyurethane phase change composites with superior photothermal conversion efficiency and thermal conductivity. ACS Sustain Chem Eng 7:17682–17690CrossRef

Fu X, Xiao Y, Hu K, Wang J, Lei J, Zhou C (2016) Thermosetting solid–solid phase change materials composed of poly(ethylene glycol)-based two components: flexible application for thermal energy storage. Chem Eng J 291:138–148CrossRef

Huang X, Liu Z, Xia W, Zou R, Han R (2015) Alkylated phase change composites for thermal energy storage based on surface-modified silica aerogels. J Mater Chem A 3:1935–1940CrossRef

Kammen DM, Sunter DA (2016) City-integrated renewable energy for urban sustainability. Science 352:922–928CrossRef

Kuznik F, David D, Johannes K, Roux J (2011) A review on phase change materials integrated in building walls. Renew Sustain Energy Rev 15:379–391CrossRef

Li Y, Samad YA, Polychronopoulou K, Alhassan SM, Liao K (2014a) From biomass to high performance solar-thermal and electric-thermal energy conversion and storage materials. J Mater Chem A 2:7759–7765CrossRef

Li Y, Wang S, Liu H, Meng F, Ma H, Zheng W (2014b) Preparation and characterization of melamine/formaldehyde/polyethylene glycol crosslinking copolymers as solid–solid phase change materials. Sol Energy Mater Sol Cells 127:92–97CrossRef

Li G, Hong G, Dong D, Song W, Zhang X (2018) Multiresponsive graphene-aerogel-directed phase-change smart fibers. Adv Mater 30:1801754–1801761CrossRef

Liu A, Medina L, Berglund L (2017) High-strength nanocomposite aerogels of ternary composition: poly(vinyl alcohol), clay, and cellulose nanofibrils. ACS Appl Mater Interfaces 9:6453–6461CrossRef

Lyu J, Liu Z, Wu X, Li G, Fang D, Zhang X (2019) Nanofibrous Kevlar aerogel films and their phase-change composites for highly efficient infrared stealth. ACS Nano 13:2236–2245CrossRef

Peng K, Chen C, Pan W, Liu W, Wang Z, Zhu L (2016) Preparation and properties of β-cyclodextrin/4,4′-diphenylmethane diisocyanate/polyethylene glycol (β-CD/MDI/PEG) crosslinking copolymers as polymeric solid–solid phase change materials. Sol Energy Mater Sol Cells 145:238–247CrossRef

Qian T, Zhu S, Wang H, Li A, Fan B (2019) Comparative study of single-walled carbon nanotubes and graphene nanoplatelets for improving the thermal conductivity and solar-to-light conversion of PEG-infiltrated phase-change material composites. ACS Sustain Chem Eng 7:2446–2458CrossRef

Ren H, Tang M, Guan B, Wang K, Yang J, Wang F, Wang M, Shan J, Chen Z, Wei D, Peng H, Liu Z (2017) Hierarchical graphene foam for efficient omnidirectional solar-thermal energy conversion. Adv Mater 29:1702590–1702596CrossRef

Tang Y, Yeo K, Chen Y, Yap L, Xiong W, Cheng W (2013) Ultralow-density copper nanowire aerogel monoliths with tunable mechanical and electrical properties. J Mater Chem A 1:6723–6726CrossRef

Tang G, Jiang Z, Li X, Zhang H, Dasari A, Yu Z (2014) Three dimensional graphene aerogels and their electrically conductive composites. Carbon 77:592–599CrossRef

Tang L, Yang J, Bao R, Liu Z, Xie B, Yang M, Yang W (2017) Polyethylene glycol/graphene oxide aerogel shape-stabilized phase change materials for photo-to-thermal energy conversion and storage via tuning the oxidation degree of graphene oxide. Energy Convers Manag 146:253–264CrossRef

Tumirah K, Hussein M, Zulkarnain Z, Rafeadah R (2014) Nano-encapsulated organic phase change material based on copolymer nanocomposites for thermal energy storage. Energy 66:881–890CrossRef

Wan Y, Zhu P, Yu S, Sun R, Wong C, Liao W (2017) Ultralight, super-elastic and volume-preserving cellulose fiber/graphene aerogel for high-performance electromagnetic interference shielding. Carbon 115:629–639CrossRef

Wei Y, Li J, Sun F, Wu J, Zhao L (2018) Leakage-proof phase change composites supported by biomass carbon aerogels from succulents. Green Chem 20:1858–1865CrossRef

Wei X, Xue F, Qi X, Yang J, Zhou Z, Yuan Y, Wang Y (2019) Photo- and electro-responsive phase change materials based on highly anisotropic microcrystalline cellulose/graphene nanoplatelet structure. Appl Energy 236:70–80CrossRef

Xiong W, Chen Y, Hao M, Zhang L, Mei T, Wang J, Li J (2015) Facile synthesis of PEG based shape-stabilized phase change materials and their photo-thermal energy conversion. Appl Therm Eng 91:630–637CrossRef

Xu Y, Fleischer A, Feng G (2017) Reinforcement and shape stabilizaition of phase-change material via graphene oxide aerogel. Carbon 114:334–346CrossRef

Yang J, Qi G, Tang L, Bao R, Bai L, Liu Z, Yang W, Xie B, Yang M (2016a) Novel photodriven composite phase change materials with bioinspired modification of BN for solar-thermal energy conversion and storage. J Mater Chem A 4:9625–9634CrossRef

Yang J, Tang L, Bao R, Bai L, Liu Z, Yang W, Xie B, Yang M (2016b) An ice-templated assembly strategy to construct graphene oxide/boron nitride hybrid porous scaffolds in phase change materials with enhanced thermal conductivity and shape stability for light-thermal-electric energy conversion. J Mater Chem A 4:18841–18851CrossRef

Yang J, Zhang E, Li X, Zhang Y, Qu J, Yu Z (2016c) Cellulose/graphene aerogel supported phase change composites with high thermal conductivity and good shape stability for thermal energy storage. Carbon 98:50–57CrossRef

Yang J, Qi G, Liu Y, Bao R, Liu Z, Yang W, Xie B, Yang M (2016d) Hybrid graphene aerogels/phase change material composites: thermal conductivity, shape-stabilization and light-to-thermal energy storage. Carbon 100:693–702CrossRef

Yang J, Tang L, Bao R, Bai L, Liu Z, Yang W, Xie B, Yang M (2017) Largely enhanced thermal conductivity of poly(ethylene glycol)/boron nitride composite phase change materials for solar-thermal-electric energy conversion and storage with very low content of graphene nanoplatelets. Chem Eng J 315:481–490CrossRef

Yang J, Qi G, Bao R, Yi K, Li M, Peng L, Cai Z, Yang M, Wei D, Yang W (2018) Hybridizing graphene aerogel into three-dimensional graphene foam for high-performance composite phase change materials. Energy Storage Mater 13:88–95CrossRef

Ye S, Zhang Q, Hu D, Feng J (2015) Core-shell-like structured graphene aerogel encapsulating paraffin: shape-stable phase change material for thermal energy storage. J Mater Chem A 3:4018–4025CrossRef

Zhang L, Li R, Tang B, Wang P (2016a) Solar-thermal conversion and thermal energy storage of graphene foam-based composites. Nanoscale 8:14600–14607CrossRef

Zhang X, Hou L, Samori P (2016b) Coupling carbon nanomaterials with photochromic molecules for the generation of optically responsive materials. Nat Commun 7:11118–11131CrossRef

Zheng Q, Kvit A, Cai Z, Ma Z, Gong S (2017) A freestanding cellulose nanofibril-reduced graphene oxide-molybdenum oxynitride aerogel film electrode for all-solid-state supercapacitors with ultrahigh energy density. J Mater Chem A 5:12528–12541CrossRef

Titel: Poly(ethylene glycol)-grafted nanofibrillated cellulose/graphene hybrid aerogels supported phase change composites with superior energy storage capacity and solar-thermal conversion efficiency
verfasst von: Xiaosheng Du
Mi Zhou
Sha Deng
Zongliang Du
Xu Cheng
Haibo Wang
Publikationsdatum: 27.03.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 8/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03110-z

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 8/2020

Correlation between the concentration and morphology of copper microparticles and their biocidal effect on paper sheets

In-situ fabrication of dynamic and recyclable TiO2 coated bacterial cellulose membranes as an efficient hybrid absorbent for tellurium extraction

Green one-pot preparation of carbon dots (CD)-embedded cellulose transparent film for Fe3+ indicator using ionic liquid

The efficient removal of anionic and cationic dyes from aqueous media using hydroxyethyl starch-based hydrogels

Sunflower oil-based MCC surface modification to achieve improved thermomechanical properties of a polypropylene composite

Deformation mechanisms of wood cell walls under tensile loading: a comparative study of compression wood (CW) and normal wood (NW)