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Journal of Coatings Technology and Research

Erschienen in:

18.10.2016

Poly(ethylene) glycol-modified, amphiphilic, siloxane–polyurethane coatings and their performance as fouling-release surfaces

verfasst von: Teluka P. Galhenage, Dean C. Webster, Augusto M. S. Moreira, Ryan J. Burgett, Shane J. Stafslien, Lyndsi Vanderwal, John A. Finlay, Sofia C. Franco, Anthony S. Clare

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 2/2017

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Abstract

Amphiphilic siloxane–polyurethane (AmSiPU) coatings were prepared using a series of polyisocyanate prepolymers modified with polydimethyl siloxane (PDMS) and poly(ethylene glycol) (PEG). Fouling-release performance of the AmSiPU coatings was evaluated through laboratory biological assays using several representative marine organisms. First, polyisocyanate prepolymers with compositional variation in PDMS and PEG were synthesized and characterized using Fourier transform infrared spectroscopy (FTIR) and isocyanate titrations. Then, the prepolymers were incorporated into coatings. Surface wettability of the coatings was evaluated using contact angle and surface energy measurements. Coatings’ surfaces were also characterized using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). ATR-FTIR and XPS experiments revealed that both PDMS and PEG moieties were present on the surface suggesting amphiphilic character. AFM phase images show microphase separation. AmSiPU coatings show excellent fouling-release performance toward bacteria (Cellulophaga lytica), the diatoms (Navicula incerta), and the green algae (Ulva linza), demonstrating comparable or superior performance to many commercial amphiphilic fouling-release coatings. Despite the incorporation of hydrophilic PEG, AmSiPU coatings show good macrofouling release which is often challenging with amphiphilic coating systems. AmSiPU coatings are a nontoxic and tough fouling-release solution with comparable performance to benchmarks in the fouling-release coatings market.

Vorheriger Artikel Acid-resistant organic coatings for the chemical industry: a review

Nächster Artikel Influence of heat-stable filler on the thermal shielding performance of water-based intumescent fire-resistive coating for structural steel applications

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Titel: Poly(ethylene) glycol-modified, amphiphilic, siloxane–polyurethane coatings and their performance as fouling-release surfaces
verfasst von: Teluka P. Galhenage
Dean C. Webster
Augusto M. S. Moreira
Ryan J. Burgett
Shane J. Stafslien
Lyndsi Vanderwal
John A. Finlay
Sofia C. Franco
Anthony S. Clare
Publikationsdatum: 18.10.2016
Verlag: Springer US
Erschienen in: Journal of Coatings Technology and Research / Ausgabe 2/2017
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-016-9862-9

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