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Adsorption

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25.08.2020

Potentials and challenges of high-field PFG NMR diffusion studies with sorbates in nanoporous media

verfasst von: Amineh Baniani, Samuel J. Berens, Matthew P. Rivera, Ryan P. Lively, Sergey Vasenkov

Erschienen in: Adsorption | Ausgabe 3/2021

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Abstract

High magnetic fields (up to 17.6 T) in combination with large magnetic field gradients (up to 25 T/m) were successfully utilized in pulsed field gradient (PFG) NMR studies of gas and liquid diffusion in nanoporous materials. In this mini-review, we present selected examples of such studies demonstrating the ability of high field PFG NMR to gain unique insights and differentiate between various types of diffusion. These examples include identifying and explaining an anomalous relationship between molecular size and self-diffusivity of gases in a zeolitic imidazolate framework (ZIF), as well as revealing and explaining an influence of mixing different linkers in a ZIF on gas self-diffusion. Different types of normal and restricted self-diffusion were quantified in hybrid membranes formed by dispersing ZIF crystals in polymers. High field PFG NMR studies of such membranes allowed observing and explaining an influence of the ZIF crystal confinement in a polymer on intra-ZIF self-diffusion of gases. This technique also allowed measuring and understanding anomalous single-file diffusion (SFD) of mixed sorbates. Furthermore, the presented examples demonstrate a high potential of combining high field PFG NMR with single-crystal infrared microscopy (IRM) for obtaining greater physical insights into the studied diffusion processes.

Vorheriger Artikel Pulsed field gradient NMR diffusion measurement in nanoporous materials

Nächster Artikel NMR imaging and diffusion

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Titel: Potentials and challenges of high-field PFG NMR diffusion studies with sorbates in nanoporous media
verfasst von: Amineh Baniani
Samuel J. Berens
Matthew P. Rivera
Ryan P. Lively
Sergey Vasenkov
Publikationsdatum: 25.08.2020
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 3/2021
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-020-00255-y

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