Introduction
Experimental section
Materials
Preparation of neat TWS and TWS/CNC nanocomposites
Characterization techniques
Scanning electron microscopy (SEM)
X-ray diffraction (XRD)
Attenuated total reflectance Fourier transform infrared spectroscopy (ATR/FTIR)
Dynamic mechanical analysis (DMA)
Thermogravimetric analysis (TGA)
Water absorption
Permeability
Results and discussion
Morphological aspects
X-ray diffraction analysis (XRD)
ATR-FTIR analysis
Dynamic mechanical analysis (DMA)
SAMPLE CODE | E´0 (MPa) | E´20 (MPa) | E´50 (MPa) | T1 (ºC) | T2 (°C) |
---|---|---|---|---|---|
TWS | 27.4 | 22.4 | 19.7 | −62.1 | 10.1 |
TWS1CNC | 93.6 | 73.5 | 74.8 | −62.8 | 22.4 |
TWS2CNC | 152.0 | 112.7 | 140.7 | −58.3 | 24.0 |
TWS5CNC | 307.5 | 225.3 | 214.9 | −56.5 | 30.4 |
Thermal stability
Water absorption
Film code | Water uptake at equilibrium, Weq (wt%) | D (m2s−1 × 10–14) (95% RH) | WVTR g·m/(m2·day) | OTR cc/(m2·day) | ||
---|---|---|---|---|---|---|
54% RH | 75% RH | 95% RH | ||||
TWS | 11.7 | 23.4 | 72.8 | 3.0 | 427.3 | 339.6 |
TWS1CNC | 9.7 | 22.0 | 61.6 | 2.1 | – | – |
TWS2CNC | 7.6 | 21.2 | 53.6 | 2.0 | – | – |
TWS5CNC | 5.5 | 19.8 | 48.3 | 2.0 | 395.8 | 279.3 |