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Erschienen in: Polymer Bulletin 7/2018

11.10.2017 | Original Paper

Preparation and characterization of novel and selective polyacrylamide-graft-poly(2-methoxyaniline) adsorbent for lead removal

verfasst von: H. M. Abd El-Salam, Reham A. Mohamed, Asmaa Shokry

Erschienen in: Polymer Bulletin | Ausgabe 7/2018

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Abstract

Polyacrylamide-graft-poly(2-methoxyaniline) [PACM-gr-P2-MeOANI] was synthesized by the oxidative chemical grafting copolymerization of 2-methoxyaniline (2-MeOANI) onto polyacrylamide (PACM). The grafting was performed in aqueous HCl using ammonium persulfate (APS) as oxidant. The optimum conditions of the grafting based on the yield were achieved. The kinetic grafting copolymerization rate equation was given. Also, the thermodynamic activation parameters of the copolymerization reaction are calculated to be \(E_{a}\) = 23.3833 kJ mol−1, ∆H = 38.7010 KJ mol−1, ∆S = −251507 J mol−1 K−1 and ∆G = 46.1959 kJ mol−1. The obtained polymer samples at optimum conditions were characterized by IR, EM, XRD and TGA to confirm the suggested structure of obtained polymers. The efficiency of the prepared polymeric samples to remove some metal ions from contaminated water was investigated. The obtained graft is a selective adsorbent for Pb(II) ion present in mixture with Mn(II) and Cr(II) ions.

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Literatur
1.
Zurück zum Zitat Martins BL, Cruz CCV, Luna AS, Henriques CA (2006) Sorption and desorption of Pb2+ ions by dead Sargassum sp. biomass. Biochem Eng J 27:310–314CrossRef Martins BL, Cruz CCV, Luna AS, Henriques CA (2006) Sorption and desorption of Pb2+ ions by dead Sargassum sp. biomass. Biochem Eng J 27:310–314CrossRef
2.
Zurück zum Zitat Aroua MK, Leong SPP, Teo LY, Yin CY, Daud WMAW (2008) Real-time determination of kinetics of adsorption of lead(II) onto palm shell-based activated carbon using ion selective electrode. Bioresour Technol 99:5786–5792CrossRefPubMed Aroua MK, Leong SPP, Teo LY, Yin CY, Daud WMAW (2008) Real-time determination of kinetics of adsorption of lead(II) onto palm shell-based activated carbon using ion selective electrode. Bioresour Technol 99:5786–5792CrossRefPubMed
3.
Zurück zum Zitat Manchon-Vizuete E, Macías-García A, Gisbert AN, Fernandez-Gonzalez C, Gomez-Serrano V (2005) Adsorption of mercury by carbonaceous adsorbents prepared from rubber of tyre wastes. J Hazard Mater B 119:231–238CrossRef Manchon-Vizuete E, Macías-García A, Gisbert AN, Fernandez-Gonzalez C, Gomez-Serrano V (2005) Adsorption of mercury by carbonaceous adsorbents prepared from rubber of tyre wastes. J Hazard Mater B 119:231–238CrossRef
4.
Zurück zum Zitat Hartono SB, Qiao SZ, Jack K, Ladewig BP, Hao Z, Lu GQ (2009) Improving adsorbent properties of cage-like ordered amine functionalized mesoporous silica with very large pores for bioadsorption. Langmuir 25:6413–6424CrossRef Hartono SB, Qiao SZ, Jack K, Ladewig BP, Hao Z, Lu GQ (2009) Improving adsorbent properties of cage-like ordered amine functionalized mesoporous silica with very large pores for bioadsorption. Langmuir 25:6413–6424CrossRef
5.
Zurück zum Zitat Abd El-Rehim HA, Hegazy EA, El-Hag Ali A (2000) Selective removal of some heavy metal ions from sing treated polyethylene-g-styrene/maleic anhydride membranes. React Funct Polym 43:105–116CrossRef Abd El-Rehim HA, Hegazy EA, El-Hag Ali A (2000) Selective removal of some heavy metal ions from sing treated polyethylene-g-styrene/maleic anhydride membranes. React Funct Polym 43:105–116CrossRef
6.
Zurück zum Zitat Abdel-Aal SE, Gad YH, Dessouki AM (2006) Use of rice straw and radiation-modified maize starch/acrylonitrile in the treatment of wastewater. J Hazard Mater B129:204–215CrossRef Abdel-Aal SE, Gad YH, Dessouki AM (2006) Use of rice straw and radiation-modified maize starch/acrylonitrile in the treatment of wastewater. J Hazard Mater B129:204–215CrossRef
7.
Zurück zum Zitat El-Zawawy WK, Ibrahim MM (2012) Preparation and characterization of novel polymer hydrogel from industrial waste and copolymerization of poly(vinyl alcohol) and polyacrylamide. J Appl Polym Sci 124:4362–4370CrossRef El-Zawawy WK, Ibrahim MM (2012) Preparation and characterization of novel polymer hydrogel from industrial waste and copolymerization of poly(vinyl alcohol) and polyacrylamide. J Appl Polym Sci 124:4362–4370CrossRef
8.
Zurück zum Zitat Ivanov RV, Lozinsky VI, Noh SK, Lee YR, Han SS, Lyoo WS (2008) Preparation and characterization of polyacrylamide cryogels produced from a high-molecular-weight precursor. II. The influence of the molecular weight of the polymeric precursor. J Appl Polym Sci 107:382–390CrossRef Ivanov RV, Lozinsky VI, Noh SK, Lee YR, Han SS, Lyoo WS (2008) Preparation and characterization of polyacrylamide cryogels produced from a high-molecular-weight precursor. II. The influence of the molecular weight of the polymeric precursor. J Appl Polym Sci 107:382–390CrossRef
9.
Zurück zum Zitat H Zhang, H Guo, B Wang, L Xiong, S Shi, X Chen (2016) Homogeneous synthesis and characterization of polyacrylamide-grafted cationic cellulose flocculants. J Appl Polym Sci 133. doi:10.1002/app.43106 H Zhang, H Guo, B Wang, L Xiong, S Shi, X Chen (2016) Homogeneous synthesis and characterization of polyacrylamide-grafted cationic cellulose flocculants. J Appl Polym Sci 133. doi:10.​1002/​app.​43106
10.
Zurück zum Zitat Amano K, Ishikawa H, Kobayashi A et al (1994) Thermal stability of chemically synthesized polyaniline. Synth Met 62:229–232CrossRef Amano K, Ishikawa H, Kobayashi A et al (1994) Thermal stability of chemically synthesized polyaniline. Synth Met 62:229–232CrossRef
11.
Zurück zum Zitat Pyo M, Reynolds JR, Warren L et al (1994) Long-term redox switching stability of polypyrrole. Synth Met 68:71–80CrossRef Pyo M, Reynolds JR, Warren L et al (1994) Long-term redox switching stability of polypyrrole. Synth Met 68:71–80CrossRef
12.
Zurück zum Zitat Thieblemunt JC, Plache MF, Petrescu C et al (1993) Stability of chemically synthesized polypyrrole films. Synth Met 59:81–96CrossRef Thieblemunt JC, Plache MF, Petrescu C et al (1993) Stability of chemically synthesized polypyrrole films. Synth Met 59:81–96CrossRef
13.
Zurück zum Zitat Neoh KG, Kang ET, Khor SH et al (1990) Stability studies of polyaniline. Polym Degrad Stab 27:107–117CrossRef Neoh KG, Kang ET, Khor SH et al (1990) Stability studies of polyaniline. Polym Degrad Stab 27:107–117CrossRef
14.
Zurück zum Zitat Yalcinkaya S, Cakmak D (2017) Electrochemical synthesis of poly(pyrrole-co-o-anisidine)/chitosan composite films. J Mol Struct 1135:32–43CrossRef Yalcinkaya S, Cakmak D (2017) Electrochemical synthesis of poly(pyrrole-co-o-anisidine)/chitosan composite films. J Mol Struct 1135:32–43CrossRef
15.
Zurück zum Zitat Chiang CK, Fincher CR Jr, Park YW et al (1977) Electrical conductivity in doped polyacetylene. Phys Rev Lett 39:1098CrossRef Chiang CK, Fincher CR Jr, Park YW et al (1977) Electrical conductivity in doped polyacetylene. Phys Rev Lett 39:1098CrossRef
16.
Zurück zum Zitat Skotheim T (ed) (1986) Handbook of conducting polymer. I and II. Marcel Dekker, New York Skotheim T (ed) (1986) Handbook of conducting polymer. I and II. Marcel Dekker, New York
17.
Zurück zum Zitat Nalwa HS (ed) (1997) Handbook of organic conducting molecules and polymers I–IV. Wiley, Chicester Nalwa HS (ed) (1997) Handbook of organic conducting molecules and polymers I–IV. Wiley, Chicester
18.
Zurück zum Zitat Palaniapan S, Amarnath C (2006) A novel polyaniline–maleicacid–dodecylhydrogensulfate salt: soluble polyaniline powder. React Funct Polym 66:1741–1748CrossRef Palaniapan S, Amarnath C (2006) A novel polyaniline–maleicacid–dodecylhydrogensulfate salt: soluble polyaniline powder. React Funct Polym 66:1741–1748CrossRef
19.
Zurück zum Zitat Ray E, Esturias GE, Kershner DL et al (1989) Polyaniline doping structure and derivatives. Synth Met 29(1):141–150CrossRef Ray E, Esturias GE, Kershner DL et al (1989) Polyaniline doping structure and derivatives. Synth Met 29(1):141–150CrossRef
20.
Zurück zum Zitat Khor SH, Neoh KG, Kang ET (1990) Synthesis and characterization of some polyaniline–organic acceptor complexes. J Appl Polym Sci 40:2015–2025CrossRef Khor SH, Neoh KG, Kang ET (1990) Synthesis and characterization of some polyaniline–organic acceptor complexes. J Appl Polym Sci 40:2015–2025CrossRef
21.
Zurück zum Zitat Reddy KR, Sin BC, Ryu KS, Kim J-C, Chung H, Lee Y (2009) Conducting polymer functionalized multi-walled carbon nanotubes with noble metal nanoparticles: synthesis, morphological characteristics and electrical properties. Synth Met 159:595–603CrossRef Reddy KR, Sin BC, Ryu KS, Kim J-C, Chung H, Lee Y (2009) Conducting polymer functionalized multi-walled carbon nanotubes with noble metal nanoparticles: synthesis, morphological characteristics and electrical properties. Synth Met 159:595–603CrossRef
22.
Zurück zum Zitat Arsat R, Yu XF, Li YX, Wlodarski W, Kalantar-zadeh K (2009) Hydrogen gas sensor based on highly ordered polyaniline nanofibers. Sens Actuators B Chem 137:529–532CrossRef Arsat R, Yu XF, Li YX, Wlodarski W, Kalantar-zadeh K (2009) Hydrogen gas sensor based on highly ordered polyaniline nanofibers. Sens Actuators B Chem 137:529–532CrossRef
23.
Zurück zum Zitat Xie D, Jiang Y, Pan W, Dan Li ZWu, Li Y (2002) Fabrication and characterization of polyaniline-based gas sensor by ultra-thin film technology. Sens Actuators B Chem 81:158–164CrossRef Xie D, Jiang Y, Pan W, Dan Li ZWu, Li Y (2002) Fabrication and characterization of polyaniline-based gas sensor by ultra-thin film technology. Sens Actuators B Chem 81:158–164CrossRef
24.
Zurück zum Zitat Huang J, Virji S, Weiller BH, Kaner RB (2004) Nanostructured polyaniline sensors. Chem A Eur J 10:1314–1319CrossRef Huang J, Virji S, Weiller BH, Kaner RB (2004) Nanostructured polyaniline sensors. Chem A Eur J 10:1314–1319CrossRef
25.
Zurück zum Zitat Li W, Li D, Xiao H, He B (2016) Facile preparation of gold nanoparticles-decorated poly(o-phenylenediamine) hollow microspheres and their application for the detection of dopamine. High Perform Polym 28(8):993–1002CrossRef Li W, Li D, Xiao H, He B (2016) Facile preparation of gold nanoparticles-decorated poly(o-phenylenediamine) hollow microspheres and their application for the detection of dopamine. High Perform Polym 28(8):993–1002CrossRef
26.
Zurück zum Zitat Li Q, Wu J, Tang Q, Lan Z, Li P, Lin J, Fan L (2008) Application of microporous polyaniline counter electrode for dye-sensitized solar cells. Electrochem Commun 10:1299–1302CrossRef Li Q, Wu J, Tang Q, Lan Z, Li P, Lin J, Fan L (2008) Application of microporous polyaniline counter electrode for dye-sensitized solar cells. Electrochem Commun 10:1299–1302CrossRef
27.
Zurück zum Zitat Chena J, Lia B, Zhenga J, Zhao J, Jing H, Zhu Z (2011) Polyaniline nanofiber/carbon film as flexible counter electrodes in platinum-free dyesensitized solar cells. Electrochem Acta 56:4624–4630CrossRef Chena J, Lia B, Zhenga J, Zhao J, Jing H, Zhu Z (2011) Polyaniline nanofiber/carbon film as flexible counter electrodes in platinum-free dyesensitized solar cells. Electrochem Acta 56:4624–4630CrossRef
28.
Zurück zum Zitat Kim BR, Lee HK, Park SH, Kim HK (2011) Electromagnetic interference shielding characteristics and shielding effectiveness of polyaniline-coated films. Thin Solid Films 519:3492–3496CrossRef Kim BR, Lee HK, Park SH, Kim HK (2011) Electromagnetic interference shielding characteristics and shielding effectiveness of polyaniline-coated films. Thin Solid Films 519:3492–3496CrossRef
29.
Zurück zum Zitat Kim BR, Lee HK, Kim E, Lee S-H (2010) Intrinsic electromagnetic radiation shielding/absorbing characteristics of polyaniline coated transparent thin films. Synth Met 160:1838–1842CrossRef Kim BR, Lee HK, Kim E, Lee S-H (2010) Intrinsic electromagnetic radiation shielding/absorbing characteristics of polyaniline coated transparent thin films. Synth Met 160:1838–1842CrossRef
30.
Zurück zum Zitat Yoshida K, Ning T, Masahiro Y (2011) Conductive composition and production method thereof, antistatic coating material, antistatic coating, antistatic film, optical filter, and optical information recording medium, and capacitors and production method thereof. Patent US 7916455 B2, USA Yoshida K, Ning T, Masahiro Y (2011) Conductive composition and production method thereof, antistatic coating material, antistatic coating, antistatic film, optical filter, and optical information recording medium, and capacitors and production method thereof. Patent US 7916455 B2, USA
31.
Zurück zum Zitat Amaya T, Abea Y, Yamamoto H, Kozawa T, Hirao T (2014) Conductivity of poly(2-methoxyaniline-5-phosphonic acid)/amine complex and its charge dissipation property in electron beam lithography. Synth Met 198:88–92CrossRef Amaya T, Abea Y, Yamamoto H, Kozawa T, Hirao T (2014) Conductivity of poly(2-methoxyaniline-5-phosphonic acid)/amine complex and its charge dissipation property in electron beam lithography. Synth Met 198:88–92CrossRef
32.
Zurück zum Zitat Fehse K, Schwartz G, Walzer K, Leo K (2007) Combination of a polyaniline anode and doped charge transport layers for high-efficiency organic light emitting diodes. J Appl Phys 101:124509CrossRef Fehse K, Schwartz G, Walzer K, Leo K (2007) Combination of a polyaniline anode and doped charge transport layers for high-efficiency organic light emitting diodes. J Appl Phys 101:124509CrossRef
33.
Zurück zum Zitat Jang J, Ha J, Kim K (2008) Organic light-emitting diode with polyaniline- poly(styrene sulfonate) as a hole injection layer. Thin Solid Films 516:3152–3156CrossRef Jang J, Ha J, Kim K (2008) Organic light-emitting diode with polyaniline- poly(styrene sulfonate) as a hole injection layer. Thin Solid Films 516:3152–3156CrossRef
34.
Zurück zum Zitat Sayyah SM, Abd El-Khalek AA, Bahgat AA et al (2001) Kinetic studies of the chemical polymerization of substituted aniline in aqueous solutions and characterization of the polymer obtained part 2: 3-Methylaniline. Int J Polym Mater 49:25CrossRef Sayyah SM, Abd El-Khalek AA, Bahgat AA et al (2001) Kinetic studies of the chemical polymerization of substituted aniline in aqueous solutions and characterization of the polymer obtained part 2: 3-Methylaniline. Int J Polym Mater 49:25CrossRef
35.
Zurück zum Zitat Sayyah SM, Bahgat AA, Abd El-Salam HM (2001) Kinetic studies of the chemical polymerization of substituted aniline in aqueous solutions and characterization of the polymer obtained part 1: 3-Chloroaniline. Polym Int 50:197CrossRef Sayyah SM, Bahgat AA, Abd El-Salam HM (2001) Kinetic studies of the chemical polymerization of substituted aniline in aqueous solutions and characterization of the polymer obtained part 1: 3-Chloroaniline. Polym Int 50:197CrossRef
36.
Zurück zum Zitat Sayyah SM, Abd El-Salam HM (2003) Aqueous oxidative chemical polymerization of N-methylaniline in acid medium and characterization of the obtained polymer. Int J Polym Mater 52:1087CrossRef Sayyah SM, Abd El-Salam HM (2003) Aqueous oxidative chemical polymerization of N-methylaniline in acid medium and characterization of the obtained polymer. Int J Polym Mater 52:1087CrossRef
37.
Zurück zum Zitat Sayyah SM, Bahgat AA, Abd El-Salam HM (2002) Kinetic studies of the aqueous oxidative polymerization of 3-hydroxyaniline and characterization of the polymer obtained. Int J Polym Mater 51:291CrossRef Sayyah SM, Bahgat AA, Abd El-Salam HM (2002) Kinetic studies of the aqueous oxidative polymerization of 3-hydroxyaniline and characterization of the polymer obtained. Int J Polym Mater 51:291CrossRef
38.
Zurück zum Zitat Sayyah SM, Abd El-Salam HM, Bahgat AA (2002) Aqueous oxidative chemical polymerization of 3-methoxyaniline and characterization of its polymer. Int J Polym Mater 51:915CrossRef Sayyah SM, Abd El-Salam HM, Bahgat AA (2002) Aqueous oxidative chemical polymerization of 3-methoxyaniline and characterization of its polymer. Int J Polym Mater 51:915CrossRef
39.
Zurück zum Zitat Sayyah SM, Abd El-Salam HM, Wahba YS (2005) Oxidative chemical polymerization of p-sulphanilamide and characterization of the obtained polymer. Int J Polym Mater 54:1 Sayyah SM, Abd El-Salam HM, Wahba YS (2005) Oxidative chemical polymerization of p-sulphanilamide and characterization of the obtained polymer. Int J Polym Mater 54:1
40.
Zurück zum Zitat Sayyah SM, Abd El-Salam HM, Azzam EMS (2006) Oxidative chemical polymerization of some 3-alkoxyaniline surfactants and characterization of the obtained polymer. Int J Polym Mater 55:1 Sayyah SM, Abd El-Salam HM, Azzam EMS (2006) Oxidative chemical polymerization of some 3-alkoxyaniline surfactants and characterization of the obtained polymer. Int J Polym Mater 55:1
41.
Zurück zum Zitat Raghava RK, Lee K-P, Iyenger GA (2007) Self-assembly directed synthesis of poly(ortho-toluidine)-metal (gold and palladium) composite nanospheres. J Nanosci Nanotechnol 7:3117–3125CrossRef Raghava RK, Lee K-P, Iyenger GA (2007) Self-assembly directed synthesis of poly(ortho-toluidine)-metal (gold and palladium) composite nanospheres. J Nanosci Nanotechnol 7:3117–3125CrossRef
42.
Zurück zum Zitat Reddy KR, Lee K-P et al (2008) Facile synthesis of conducting polymer metal hybrid nanocomposite by in situ chemical oxidative polymerization with negatively charged metal nanoparticles. Mater Lett 62:1815–1818CrossRef Reddy KR, Lee K-P et al (2008) Facile synthesis of conducting polymer metal hybrid nanocomposite by in situ chemical oxidative polymerization with negatively charged metal nanoparticles. Mater Lett 62:1815–1818CrossRef
43.
Zurück zum Zitat Reddy KR, Lee K-P et al (2006) Facile synthesis of hollow spheres of sulfonated polyanilines. Polym J 38:349–354CrossRef Reddy KR, Lee K-P et al (2006) Facile synthesis of hollow spheres of sulfonated polyanilines. Polym J 38:349–354CrossRef
44.
Zurück zum Zitat Reddy KR, Lee K-P et al (2007) Novel electrically conductive and ferromagnetic composites of poly(aniline-co-aminonaphthalenesulfonic acid) with iron oxide nanoparticles: synthesis and characterization. Appl Polym Sci 106:1181–1191CrossRef Reddy KR, Lee K-P et al (2007) Novel electrically conductive and ferromagnetic composites of poly(aniline-co-aminonaphthalenesulfonic acid) with iron oxide nanoparticles: synthesis and characterization. Appl Polym Sci 106:1181–1191CrossRef
45.
Zurück zum Zitat Zhang Y-P, Lee S-H, Reddy KR, Gopalan AI, Lee K-P (2007) Synthesis and characterization of core-shell SiO2 nanoparticles/poly(3-aminophenylboronic acid) composites. J Appl Polym Sci 104:2743–2750CrossRef Zhang Y-P, Lee S-H, Reddy KR, Gopalan AI, Lee K-P (2007) Synthesis and characterization of core-shell SiO2 nanoparticles/poly(3-aminophenylboronic acid) composites. J Appl Polym Sci 104:2743–2750CrossRef
46.
Zurück zum Zitat Xiang Q, Xie H-Q (1996) preparation and characterization of alkali soluble polyacrelamide-g-polyaniline. Eur Polym J. 32(7):865–868CrossRef Xiang Q, Xie H-Q (1996) preparation and characterization of alkali soluble polyacrelamide-g-polyaniline. Eur Polym J. 32(7):865–868CrossRef
47.
Zurück zum Zitat Sharma K, Kumar V, Kait BS, Kumar V, Som S, Kalia S, Swart HC (2015) Synthesis, characterization and water retention study of biodegradable Gum ghatti-poly(acrylic acid–aniline) hydrogels. Polym Degrad Stab J 111:20–31CrossRef Sharma K, Kumar V, Kait BS, Kumar V, Som S, Kalia S, Swart HC (2015) Synthesis, characterization and water retention study of biodegradable Gum ghatti-poly(acrylic acid–aniline) hydrogels. Polym Degrad Stab J 111:20–31CrossRef
48.
Zurück zum Zitat Bajpai AK, Bajpai J, Soni SN (2008) preparation and characterization of electrically conductive composites of poly(vinyl alcohol)-g-poly(acrylic acid) hydrogels impregnated with polyaniline. Express Polym Lett 2(1):26–39CrossRef Bajpai AK, Bajpai J, Soni SN (2008) preparation and characterization of electrically conductive composites of poly(vinyl alcohol)-g-poly(acrylic acid) hydrogels impregnated with polyaniline. Express Polym Lett 2(1):26–39CrossRef
49.
Zurück zum Zitat Abd El-Salam HMA, Kamal EHM, Ibrahim MS (2016) Synthesis and characterization of Chitosan-Grafted-Poly(2-Hydroxyaniline) microstructures for water decontamination. J Polym Environ. doi:10.1007/s10924-016-0847-7 CrossRef Abd El-Salam HMA, Kamal EHM, Ibrahim MS (2016) Synthesis and characterization of Chitosan-Grafted-Poly(2-Hydroxyaniline) microstructures for water decontamination. J Polym Environ. doi:10.​1007/​s10924-016-0847-7 CrossRef
50.
Zurück zum Zitat Nagara S, Santhosh P, Sankarasubramanian M et al (2005) UV-vis. spectroscopy for following the kinetics of homogeneous polymerization of diphenylamine in p-toluene sulfonic acid. Spectrochim Acta Biomol Spectrosc 62:1–3CrossRef Nagara S, Santhosh P, Sankarasubramanian M et al (2005) UV-vis. spectroscopy for following the kinetics of homogeneous polymerization of diphenylamine in p-toluene sulfonic acid. Spectrochim Acta Biomol Spectrosc 62:1–3CrossRef
52.
Zurück zum Zitat Silverstein RM, Bassler CG, Morill TC (1974) Spectroscopic identification of organic compounds. Wiley, New York Silverstein RM, Bassler CG, Morill TC (1974) Spectroscopic identification of organic compounds. Wiley, New York
53.
Zurück zum Zitat Shaker MA (2015) Adsorption of Co(II), Ni(II) and Cu(II) ions onto chitosan-modified poly(methacrylate) nanoparticles: dynamics, equilibrium and thermodynamics studies. J Taiwan Inst Chem Eng 57:111–112CrossRef Shaker MA (2015) Adsorption of Co(II), Ni(II) and Cu(II) ions onto chitosan-modified poly(methacrylate) nanoparticles: dynamics, equilibrium and thermodynamics studies. J Taiwan Inst Chem Eng 57:111–112CrossRef
54.
Zurück zum Zitat Lagergren S (1898) Zur theorie der sogenannten adsorption gel oster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar 25:1–39 Lagergren S (1898) Zur theorie der sogenannten adsorption gel oster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar 25:1–39
55.
Zurück zum Zitat Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465CrossRef Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465CrossRef
Metadaten
Titel
Preparation and characterization of novel and selective polyacrylamide-graft-poly(2-methoxyaniline) adsorbent for lead removal
verfasst von
H. M. Abd El-Salam
Reham A. Mohamed
Asmaa Shokry
Publikationsdatum
11.10.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2188-7

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