Skip to main content
Erschienen in: Cellulose 2/2019

20.11.2018 | Original Paper

Preparation and dielectric properties of porous cyanoethyl cellulose membranes

verfasst von: Bei Wang, Hongliang Kang, Hougui Yang, Jianjun Xie, Ruigang Liu

Erschienen in: Cellulose | Ausgabe 2/2019

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Cyanoethyl cellulose (CEC) with a high degree of substitution of cyanoethyl group was synthesized by using the Michael addition reaction. Porous CEC membranes were successfully prepared by the non-solvent induced phase separation method. The parameters that influence the morphology and properties of the CEC membranes were investigated and discussed. Asymmetric membranes with higher porosity were obtained when water was used for the coagulation bath. On the other hand, dense symmetric CEC membranes with cellular or flat pores were obtained when ethanol or DMF/H2O was used for the coagulation bath. The porosity of the CEC membranes was reduced with increased polymer concentration in the CEC/DMF solutions. Moreover, the morphology of CEC membranes also depended on the molecular weight of CEC. In the case of using water as the coagulation bath, the morphology of the CEC membranes changed from an asymmetric structure with dense thin skin layer to a stick-like intertwined symmetric structure. When ethanol or DMF/H2O was used for the coagulation bath, the morphology of the resultant symmetric CEC membranes changed from cellular or flat pores to stick-like intertwined structure. The dielectric constant of the CEC membranes increased with a decrease in the porosity of CEC membranes.

Graphical abstract

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Abed MRM, Kumbharkar SC, Groth AM, Li K (2012) Ultrafiltration PVDF hollow fibre membranes with interconnected bicontinuous structures produced via a single-step phase inversion technique. J Membr Sci 407:145–154CrossRef Abed MRM, Kumbharkar SC, Groth AM, Li K (2012) Ultrafiltration PVDF hollow fibre membranes with interconnected bicontinuous structures produced via a single-step phase inversion technique. J Membr Sci 407:145–154CrossRef
Zurück zum Zitat Ahmad AL, Ramli WKW (2013) Hydrophobic PVDF membrane via two-stage soft coagulation bath system for membrane gas absorption of CO2. Sep Purif Technol 103:230–240CrossRef Ahmad AL, Ramli WKW (2013) Hydrophobic PVDF membrane via two-stage soft coagulation bath system for membrane gas absorption of CO2. Sep Purif Technol 103:230–240CrossRef
Zurück zum Zitat Bottino A, Cameraroda G, Capannelli G, Munari S (1991) The formation of microporous polyvinylidene difluoride membranes by phase-separation. J Membr Sci 57:1–20CrossRef Bottino A, Cameraroda G, Capannelli G, Munari S (1991) The formation of microporous polyvinylidene difluoride membranes by phase-separation. J Membr Sci 57:1–20CrossRef
Zurück zum Zitat Buonomenna MG, Macchi P, Davoli M, Drioli E (2007) Poly(vinylidene fluoride) membranes by phase inversion: the role the casting and coagulation conditions play in their morphology, crystalline structure and properties. Eur Polym J 43:1557–1572CrossRef Buonomenna MG, Macchi P, Davoli M, Drioli E (2007) Poly(vinylidene fluoride) membranes by phase inversion: the role the casting and coagulation conditions play in their morphology, crystalline structure and properties. Eur Polym J 43:1557–1572CrossRef
Zurück zum Zitat Cao C et al (2014) Wool graft polyacrylamidoxime as the adsorbent for both cationic and anionic toxic ions from aqueous solutions. RSC Adv 4:60609–60616CrossRef Cao C et al (2014) Wool graft polyacrylamidoxime as the adsorbent for both cationic and anionic toxic ions from aqueous solutions. RSC Adv 4:60609–60616CrossRef
Zurück zum Zitat Chakrabarty B, Ghoshal AK, Purkait MK (2008) Effect of molecular weight of PEG on membrane morphology and transport properties. J Membr Sci 309:209–221CrossRef Chakrabarty B, Ghoshal AK, Purkait MK (2008) Effect of molecular weight of PEG on membrane morphology and transport properties. J Membr Sci 309:209–221CrossRef
Zurück zum Zitat Chang HH, Chang LK, Yang CD, Lin DJ, Cheng LP (2017) Effect of solvent on the dipole rotation of poly(vinylidene fluoride) during porous membrane formation by precipitation in alcohol baths. Polymer 115:164–175CrossRef Chang HH, Chang LK, Yang CD, Lin DJ, Cheng LP (2017) Effect of solvent on the dipole rotation of poly(vinylidene fluoride) during porous membrane formation by precipitation in alcohol baths. Polymer 115:164–175CrossRef
Zurück zum Zitat Chen JJ, Kong XQ, Sumida K, Manumpil MA, Long JR, Reimer JA (2013) Ex situ NMR relaxometry of metal-organic frameworks for rapid surface-area screening. Angew Chem Int Ed 52:12043–12046CrossRef Chen JJ, Kong XQ, Sumida K, Manumpil MA, Long JR, Reimer JA (2013) Ex situ NMR relaxometry of metal-organic frameworks for rapid surface-area screening. Angew Chem Int Ed 52:12043–12046CrossRef
Zurück zum Zitat Chen ZL, Rana D, Matsuura T, Yang YF, Lan CQ (2014) Study on the structure and vacuum membrane distillation performance of PVDF composite membranes: I. Influence of blending. Sep Purif Technol 133:303–312CrossRef Chen ZL, Rana D, Matsuura T, Yang YF, Lan CQ (2014) Study on the structure and vacuum membrane distillation performance of PVDF composite membranes: I. Influence of blending. Sep Purif Technol 133:303–312CrossRef
Zurück zum Zitat Chen MY, Kang HL, Gong YM, Guo J, Zhang H, Liu RG (2015a) Bacterial cellulose supported gold nanoparticles with excellent catalytic properties. ACS Appl Mater Interfaces 7:21717–21726CrossRefPubMed Chen MY, Kang HL, Gong YM, Guo J, Zhang H, Liu RG (2015a) Bacterial cellulose supported gold nanoparticles with excellent catalytic properties. ACS Appl Mater Interfaces 7:21717–21726CrossRefPubMed
Zurück zum Zitat Chen ZL, Rana D, Matsuura T, Meng D, Lan CQ (2015b) Study on structure and vacuum membrane distillation performance of PVDF membranes: II. Influence of molecular weight. Chem Eng J 276:174–184CrossRef Chen ZL, Rana D, Matsuura T, Meng D, Lan CQ (2015b) Study on structure and vacuum membrane distillation performance of PVDF membranes: II. Influence of molecular weight. Chem Eng J 276:174–184CrossRef
Zurück zum Zitat Chun KY, Jang SH, Kim HS, Kim YW, Han HS, Joe YI (2000) Effects of solvent on the pore formation in asymmetric 6FDA-4,4′ ODA polyimide membrane: terms of thermodynamics, precipitation kinetics, and physical factors. J Membr Sci 169:197–214CrossRef Chun KY, Jang SH, Kim HS, Kim YW, Han HS, Joe YI (2000) Effects of solvent on the pore formation in asymmetric 6FDA-4,4′ ODA polyimide membrane: terms of thermodynamics, precipitation kinetics, and physical factors. J Membr Sci 169:197–214CrossRef
Zurück zum Zitat Dang ZM, Xu HP, Wang HY (2007) Significantly enhanced low-frequency dielectric permittivity in the BaTiO3/poly(vinylidene fluoride) nanocomposite. Appl Phys Lett 90:3804 Dang ZM, Xu HP, Wang HY (2007) Significantly enhanced low-frequency dielectric permittivity in the BaTiO3/poly(vinylidene fluoride) nanocomposite. Appl Phys Lett 90:3804
Zurück zum Zitat Eykens L, De Sitter K, Stoops L, Dotremont C, Pinoy L, Van der Bruggen B (2017) Development of polyethersulfone phase-inversion membranes for membrane distillation using oleophobic coatings. J Appl Polym Sci 134:45516CrossRef Eykens L, De Sitter K, Stoops L, Dotremont C, Pinoy L, Van der Bruggen B (2017) Development of polyethersulfone phase-inversion membranes for membrane distillation using oleophobic coatings. J Appl Polym Sci 134:45516CrossRef
Zurück zum Zitat Fadhil S et al (2016) Novel PVDF-HFP flat sheet membranes prepared by triethyl phosphate (TEP) solvent for direct contact membrane distillation. Chem Eng Process 102:16–26CrossRef Fadhil S et al (2016) Novel PVDF-HFP flat sheet membranes prepared by triethyl phosphate (TEP) solvent for direct contact membrane distillation. Chem Eng Process 102:16–26CrossRef
Zurück zum Zitat Guillen GR, Pan YJ, Li MH, Hoek EMV (2011) Preparation and characterization of membranes formed by nonsolvent induced phase separation: a review. Ind Eng Chem Res 50:3798–3817CrossRef Guillen GR, Pan YJ, Li MH, Hoek EMV (2011) Preparation and characterization of membranes formed by nonsolvent induced phase separation: a review. Ind Eng Chem Res 50:3798–3817CrossRef
Zurück zum Zitat Jia C, Shao ZQ, Fan HY, Wang JQ (2015) Preparation and dielectric properties of cyanoethyl cellulose/BaTiO3 flexible nanocomposite films. RSC Adv 5:15283–15291CrossRef Jia C, Shao ZQ, Fan HY, Wang JQ (2015) Preparation and dielectric properties of cyanoethyl cellulose/BaTiO3 flexible nanocomposite films. RSC Adv 5:15283–15291CrossRef
Zurück zum Zitat Jia C et al (2016) Barium titanate as a filler for improving the dielectric property of cyanoethyl cellulose/antimony tin oxide nanocomposite films. Compos A Appl Sci Manuf 86:1–8CrossRef Jia C et al (2016) Barium titanate as a filler for improving the dielectric property of cyanoethyl cellulose/antimony tin oxide nanocomposite films. Compos A Appl Sci Manuf 86:1–8CrossRef
Zurück zum Zitat Jin RG, Hua YQ (2013) Polymer physics, 4th edn. Chemical Industry Publisher, Beijing (in Chinese) Jin RG, Hua YQ (2013) Polymer physics, 4th edn. Chemical Industry Publisher, Beijing (in Chinese)
Zurück zum Zitat Kamel S, Hassan EM, El-Sakhawy M (2006) Preparation and application of acrylonitrile-grafted cyanoethyl cellulose for the removal of copper(II) ions. J Appl Polym Sci 100:329–334CrossRef Kamel S, Hassan EM, El-Sakhawy M (2006) Preparation and application of acrylonitrile-grafted cyanoethyl cellulose for the removal of copper(II) ions. J Appl Polym Sci 100:329–334CrossRef
Zurück zum Zitat Kang HL, Liu RG, Huang Y (2015) Graft modification of cellulose: methods, properties and applications. Polymer 70:A1–A16CrossRef Kang HL, Liu RG, Huang Y (2015) Graft modification of cellulose: methods, properties and applications. Polymer 70:A1–A16CrossRef
Zurück zum Zitat Kang HL, Liu RG, Huang Y (2016) Cellulose-based gels. Macromol Chem Phys 217:1322–1334CrossRef Kang HL, Liu RG, Huang Y (2016) Cellulose-based gels. Macromol Chem Phys 217:1322–1334CrossRef
Zurück zum Zitat Kuo CY, Lin HN, Tsai HA, Wang DM, Lai JY (2008) Fabrication of a high hydrophobic PVDF membrane via nonsolvent induced phase separation. Desalination 233:40–47CrossRef Kuo CY, Lin HN, Tsai HA, Wang DM, Lai JY (2008) Fabrication of a high hydrophobic PVDF membrane via nonsolvent induced phase separation. Desalination 233:40–47CrossRef
Zurück zum Zitat Levitt MH (2007) Spin dynamics: basics of nuclear magnetic resonance, 2nd edn. Wiley, Chichester Levitt MH (2007) Spin dynamics: basics of nuclear magnetic resonance, 2nd edn. Wiley, Chichester
Zurück zum Zitat Li WW, Liu RG, Kang HL, Sun YM, Dong FY, Huang Y (2013) Synthesis of amidoxime functionalized cellulose derivatives as a reducing agent and stabilizer for preparing gold nanoparticles. Polym Chem 4:2556–2563CrossRef Li WW, Liu RG, Kang HL, Sun YM, Dong FY, Huang Y (2013) Synthesis of amidoxime functionalized cellulose derivatives as a reducing agent and stabilizer for preparing gold nanoparticles. Polym Chem 4:2556–2563CrossRef
Zurück zum Zitat Lin DJ, Chang HH, Chen TC, Lee YC, Cheng LP (2006) Formation of porous poly(vinylidene fluoride) membranes with symmetric or asymmetric morphology by immersion precipitation in the water/TEP/PVDF system. Eur Polym J 42:1581–1594CrossRef Lin DJ, Chang HH, Chen TC, Lee YC, Cheng LP (2006) Formation of porous poly(vinylidene fluoride) membranes with symmetric or asymmetric morphology by immersion precipitation in the water/TEP/PVDF system. Eur Polym J 42:1581–1594CrossRef
Zurück zum Zitat Matsui H, Shiraishi N (2000) Dielectric properties of cyanoethyl cellulose grafted with fluorine-containing acrylates. Mokuzai Gakkaishi 46:468–474 Matsui H, Shiraishi N (2000) Dielectric properties of cyanoethyl cellulose grafted with fluorine-containing acrylates. Mokuzai Gakkaishi 46:468–474
Zurück zum Zitat Matsuura T (1994) Synthetic membranes and membrane separation processes. CRC Press, Boca Raton Matsuura T (1994) Synthetic membranes and membrane separation processes. CRC Press, Boca Raton
Zurück zum Zitat Mitchell J, Gladden LF, Chandrasekera TC, Fordham EJ (2014) Low-field permanent magnets for industrial process and quality control. Prog Nucl Magn Reson Spectrosc 76:1–60CrossRefPubMed Mitchell J, Gladden LF, Chandrasekera TC, Fordham EJ (2014) Low-field permanent magnets for industrial process and quality control. Prog Nucl Magn Reson Spectrosc 76:1–60CrossRefPubMed
Zurück zum Zitat Morooka T, Norimoto M, Yamada T (1986) Cyanoethylated cellulose prepared by homogeneous reaction in paraformaldehyde-DMSO system. J Appl Polym Sci 32:3575–3587CrossRef Morooka T, Norimoto M, Yamada T (1986) Cyanoethylated cellulose prepared by homogeneous reaction in paraformaldehyde-DMSO system. J Appl Polym Sci 32:3575–3587CrossRef
Zurück zum Zitat Mosqueda-Jimenez DB, Narbaitz RM, Matsuura T, Chowdhury G, Pleizier G, Santerre JP (2004) Influence of processing conditions on the properties of ultrafiltration membranes. J Membr Sci 231:209–224CrossRef Mosqueda-Jimenez DB, Narbaitz RM, Matsuura T, Chowdhury G, Pleizier G, Santerre JP (2004) Influence of processing conditions on the properties of ultrafiltration membranes. J Membr Sci 231:209–224CrossRef
Zurück zum Zitat Nakayama E, Azuma JI (1998) Substituent distribution of cyanoethyl cellulose. Cellulose 5:175–185CrossRef Nakayama E, Azuma JI (1998) Substituent distribution of cyanoethyl cellulose. Cellulose 5:175–185CrossRef
Zurück zum Zitat Pu WH, He XM, Wang L, Jiang CY, Wan CR (2006) Preparation of PVDF-HFP microporous membrane for Li-ion batteries by phase inversion. J Membr Sci 272:11–14CrossRef Pu WH, He XM, Wang L, Jiang CY, Wan CR (2006) Preparation of PVDF-HFP microporous membrane for Li-ion batteries by phase inversion. J Membr Sci 272:11–14CrossRef
Zurück zum Zitat Rahimpour A, Madaeni SS, Mansourpanah Y (2007) High performance polyethersulfone UF membrane for manufacturing spiral wound module: preparation, morphology, performance, and chemical cleaning. Polym Adv Technol 18:403–410CrossRef Rahimpour A, Madaeni SS, Mansourpanah Y (2007) High performance polyethersulfone UF membrane for manufacturing spiral wound module: preparation, morphology, performance, and chemical cleaning. Polym Adv Technol 18:403–410CrossRef
Zurück zum Zitat Saad GR (1994) Dielectric behavior of cyanoethylated cellulose. Polym Int 34:411–415CrossRef Saad GR (1994) Dielectric behavior of cyanoethylated cellulose. Polym Int 34:411–415CrossRef
Zurück zum Zitat Saha AK, Mitra BC (1996) Studies on cyanoethylation of jute fiber. J Appl Polym Sci 62:733–742CrossRef Saha AK, Mitra BC (1996) Studies on cyanoethylation of jute fiber. J Appl Polym Sci 62:733–742CrossRef
Zurück zum Zitat Song ZY, Xing MH, Zhang J, Li BA, Wang SC (2012) Determination of phase diagram of a ternary PVDF/γ-BL/DOP system in TIPS process and its application in preparing hollow fiber membranes for membrane distillation. Sep Purif Technol 90:221–230CrossRef Song ZY, Xing MH, Zhang J, Li BA, Wang SC (2012) Determination of phase diagram of a ternary PVDF/γ-BL/DOP system in TIPS process and its application in preparing hollow fiber membranes for membrane distillation. Sep Purif Technol 90:221–230CrossRef
Zurück zum Zitat Takahashi Y, Kitahama A, Furukawa T (2004) Dielectric properties of the surface layer in ultra-thin films of a VDF/TrFE copolymer. IEEE Trans Dielectr Electr Insul 11:227–231CrossRef Takahashi Y, Kitahama A, Furukawa T (2004) Dielectric properties of the surface layer in ultra-thin films of a VDF/TrFE copolymer. IEEE Trans Dielectr Electr Insul 11:227–231CrossRef
Zurück zum Zitat Takechi S, Teramoto Y, Nishio Y (2016) Improvement of dielectric properties of cyanoethyl cellulose via esterification and film stretching. Cellulose 23:765–777CrossRef Takechi S, Teramoto Y, Nishio Y (2016) Improvement of dielectric properties of cyanoethyl cellulose via esterification and film stretching. Cellulose 23:765–777CrossRef
Zurück zum Zitat Tan DQ, Cao Y, Irwin PC, Cunningham D (2010) High-temperature capacitors and methods of making the same. USA patent application 20100244585 Tan DQ, Cao Y, Irwin PC, Cunningham D (2010) High-temperature capacitors and methods of making the same. USA patent application 20100244585
Zurück zum Zitat Wang XY, Zhang L, Sun DH, An QF, Chen HL (2009) Formation mechanism and crystallization of poly(vinylidene fluoride) membrane via immersion precipitation method. Desalination 236:170–178CrossRef Wang XY, Zhang L, Sun DH, An QF, Chen HL (2009) Formation mechanism and crystallization of poly(vinylidene fluoride) membrane via immersion precipitation method. Desalination 236:170–178CrossRef
Zurück zum Zitat Xu PM, Guo GJ, Liu XL, Wei JZ, Wu ZS (1994) Study on the relation between the thickness and the dielectric and pyroelectric coefficients of PVDF/TGS composite material film by experiment. Ferroelectrics 157:411–414CrossRef Xu PM, Guo GJ, Liu XL, Wei JZ, Wu ZS (1994) Study on the relation between the thickness and the dielectric and pyroelectric coefficients of PVDF/TGS composite material film by experiment. Ferroelectrics 157:411–414CrossRef
Zurück zum Zitat Xu HP, Dang ZM, Bing NC, Wu YH, Yang DD (2010) Temperature dependence of electric and dielectric behaviors of Ni/polyvinylidene fluoride composites. J Appl Phys 107:034105CrossRef Xu HP, Dang ZM, Bing NC, Wu YH, Yang DD (2010) Temperature dependence of electric and dielectric behaviors of Ni/polyvinylidene fluoride composites. J Appl Phys 107:034105CrossRef
Zurück zum Zitat Yen SPS, Lewis CR, Cygan PJ, Jow RT (1996) Cyanoresin, cyanoresin/cellulose triacetate blends for thin film, dielectric capacitors. US patent 5490035 Yen SPS, Lewis CR, Cygan PJ, Jow RT (1996) Cyanoresin, cyanoresin/cellulose triacetate blends for thin film, dielectric capacitors. US patent 5490035
Zurück zum Zitat Yeow ML, Liu YT, Li K (2004) Morphological study of poly(vinylidene fluoride) asymmetric membranes: effects of the solvent, additive, and dope temperature. J Appl Polym Sci 92:1782–1789CrossRef Yeow ML, Liu YT, Li K (2004) Morphological study of poly(vinylidene fluoride) asymmetric membranes: effects of the solvent, additive, and dope temperature. J Appl Polym Sci 92:1782–1789CrossRef
Zurück zum Zitat Young TH, Cheng LP, Lin DJ, Fane L, Chuang WY (1999) Mechanisms of PVDF membrane formation by immersion-precipitation in soft (1-octanol) and harsh (water) nonsolvents. Polymer 40:5315–5323CrossRef Young TH, Cheng LP, Lin DJ, Fane L, Chuang WY (1999) Mechanisms of PVDF membrane formation by immersion-precipitation in soft (1-octanol) and harsh (water) nonsolvents. Polymer 40:5315–5323CrossRef
Zurück zum Zitat Zhang L, Cheng ZY (2011) Development of polymer-based 0–3 composites with high dielectric constant. J Adv Dielectr 1:389–406CrossRef Zhang L, Cheng ZY (2011) Development of polymer-based 0–3 composites with high dielectric constant. J Adv Dielectr 1:389–406CrossRef
Zurück zum Zitat Zhang C et al (2016) Hierarchical porous structures in cellulose: NMR relaxometry approach. Polymer 98:237–243CrossRef Zhang C et al (2016) Hierarchical porous structures in cellulose: NMR relaxometry approach. Polymer 98:237–243CrossRef
Zurück zum Zitat Zhou C, Hou ZC, Lu XF, Liu ZY, Bian XK, Shi LQ, Li LA (2010) Effect of polyethersulfone molecular weight on structure and performance of ultrafiltration membranes. Ind Eng Chem Res 49:9988–9997CrossRef Zhou C, Hou ZC, Lu XF, Liu ZY, Bian XK, Shi LQ, Li LA (2010) Effect of polyethersulfone molecular weight on structure and performance of ultrafiltration membranes. Ind Eng Chem Res 49:9988–9997CrossRef
Metadaten
Titel
Preparation and dielectric properties of porous cyanoethyl cellulose membranes
verfasst von
Bei Wang
Hongliang Kang
Hougui Yang
Jianjun Xie
Ruigang Liu
Publikationsdatum
20.11.2018
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 2/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-018-2132-5

Weitere Artikel der Ausgabe 2/2019

Cellulose 2/2019 Zur Ausgabe