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01.02.2015 | Original Paper

Preparation and flame retardancy of 3-(hydroxyphenylphosphinyl)-propanoic acid esters of cellulose and their fibers

verfasst von: Yunbo Zheng, Jun Song, Bowen Cheng, Xiaolin Fang, Ya Yuan

Erschienen in: Cellulose | Ausgabe 1/2015

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Abstract

New 3-(hydroxyphenylphosphinyl)-propanoic acid (3-HPP) esters of cellulose were synthesized in N, N-dimethylacetamide/LiCl homogeneously by the method of in situ activation with p-toluenesulfonyl chloride. Chemical structure and thermal properties of the cellulose esters were investigated by FTIR, ¹³C-NMR, TGA, RT-IR and Py–GC/MS, and their flame retardancy was studied by limiting oxygen index (LOI) test and vertical flammability test. It was found that the degree of substitution (DS) of cellulose esters, in the range from 0.62 to 1.42, had an obvious effect on solubility of cellulose esters. According to the FT-IR and Py–GC/MS results, flame retardant 3-HPP reacting with cellulose could accelerate dehydration action and decrease flammable released products. Besides, ESEM observation also confirmed that flame retardant cellulose (FRC) fibers with 3 wt% cellulose acetate prepared by dry-wet spinning technique possessed good flame resistance.

Vorheriger Artikel Catalytic and catalytic free process for cellulose conversion: fast pyrolysis and microwave induced pyrolysis studies

Nächster Artikel Hydrophobic surface treatments of sunflower pith using eco-friendly processes

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Titel: Preparation and flame retardancy of 3-(hydroxyphenylphosphinyl)-propanoic acid esters of cellulose and their fibers
verfasst von: Yunbo Zheng
Jun Song
Bowen Cheng
Xiaolin Fang
Ya Yuan
Publikationsdatum: 01.02.2015
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2015
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-014-0486-x

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