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Colloid and Polymer Science

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10.03.2017 | Original Contribution

Preparation and thermoresponsive properties of UCST-type glycopolypeptide bearing mannose pendants and 3-methyl-1,2,3-triazolium linkages in ethanol or ethanol/water solvent mixtures

verfasst von: Minjie Li, Jiang Xiao, Chenglong Ge, Ying Ling, Haoyu Tang

Erschienen in: Colloid and Polymer Science | Ausgabe 5/2017

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Abstract

A series of glycopolypeptides with constant main-chain lengths and bearing various mannose pendants and 3-methyl-1,2,3-triazolium linkages were synthesized by N-alkylation, ion-exchange reaction, and subsequent deprotection. ¹H NMR and FTIR analysis verified their molecular structures. Their solubility and thermoresponsive properties were collectively affected by polymer structure, polymer concentration, and the nature of solvent. Glycopolypeptides bearing tetra-O-acetyl-d-(+)-mannopyranoside and 3-methyl-1,2,3-triazolium chloride linkages showed a reversible upper critical solution temperature (UCST)-type phase behavior in ethanol (EtOH) with a solution phase transition temperature (T _pt) in the range of 39.7–47.4 °C depending on polymer concentration. Glycopolypeptides bearing tetra-O-acetyl-d-(+)-mannopyranoside and 3-methyl-1,2,3-triazolium iodide or 3-methyl-1,2,3-triazolium tetrafluoroborate linkages showed a reversible UCST-type phase behavior in EtOH/H₂O solvent mixtures. The T _pt can be adjusted in the range of about 10–50 °C by polymer concentration or the weight percentage of ethanol (f _w). It increased as the polymer concentration or f _w increased.

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Titel: Preparation and thermoresponsive properties of UCST-type glycopolypeptide bearing mannose pendants and 3-methyl-1,2,3-triazolium linkages in ethanol or ethanol/water solvent mixtures
verfasst von: Minjie Li
Jiang Xiao
Chenglong Ge
Ying Ling
Haoyu Tang
Publikationsdatum: 10.03.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 5/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-017-4064-2

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