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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 3/2019

29.10.2018

Preparation of amphiphobically modified poly(vinyl alcohol) film by fluoroalkyl end-capped vinyltrimethoxysilane oligomer

verfasst von: Yuta Aomi, Hideo Sawada

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 3/2019

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Abstract

Hydrophilic poly(vinyl alcohol) (PVA) was chemically modified by using fluoroalkyl end-capped vinyltrimethoxysilane oligomer [RF-(VM)n-RF] to lead the PVA/RF-(VM)n-RF composite films. The PVA/RF-(VM)n-RF composite film obtained under non-catalytic conditions was found to provide the water-soluble property; however, the acidic conditions enabled the composite film to afford no solubility toward water, giving an amphiphobic property on both the surface and reverse sides just after the deposit of an oil or water droplet. RF-(VM)n-RF oligomer was also applied to the fabrication of the PVA/RF-(VM)n-RF/B(OH)3 composite film by using the RF-(VM)n-RF/B(OH)3 nanocomposites, which were prepared by the composite reaction of RF-(VM)n-RF oligomer with boric acid. It was demonstrated that the PVA/RF-(VM)n-RF/B(OH)3 composite film obtained by the interaction of the corresponding nanocomposites with PVA under acidic conditions can afford the perfect water-resistance ability even after immersion of this film into water for 30 min to give the amphiphobic property on both the surface and reverse sides, although the corresponding PVA/RF-(VM)n-RF composite film and the pristine PVA film provided the swelling behavior toward water, respectively. Thermal gravimetric analyses (TGA) and differential thermal analyses (DTA) measurements showed that the PVA/RF-(VM)n-RF/B(OH)3 composite film can give a higher thermal stability than that of the RF-(VM)n-RF/PVA composite film and the pristine PVA film.

Graphical abstract

Vorheriger Artikel Surface modification of polyarylene sulfide sulfone membrane by coating with polydopamine
Nächster Artikel Advances in design and manufacturing of environmentally friendly and biocide-free antifouling/foul-release coatings: replacement of fluorinate species

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Metadaten
Titel
Preparation of amphiphobically modified poly(vinyl alcohol) film by fluoroalkyl end-capped vinyltrimethoxysilane oligomer
verfasst von
Yuta Aomi
Hideo Sawada
Publikationsdatum
29.10.2018
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 3/2019
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-018-0148-2

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