nach oben

Cellulose

Erschienen in:

20.05.2020 | Original Research

Preparation of cellulose nanocrystal-dressed fluorinated polyacrylate latex particles via RAFT-mediated Pickering emulsion polymerization and application on fabric finishing

verfasst von: Jianhua Zhou, Xueli Wang, Yannan Li, Hong Li, Kun Lu

Erschienen in: Cellulose | Ausgabe 11/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Cellulose nanocrystal-dressed fluorinated polyacrylate latex particles were prepared via RAFT-mediated Pickering emulsion polymerization using cellulose nanocrystals (CNCs) modified with amphiphilic polymers as Pickering stabilizers. The main work was to study the effect of pH value and the amount of fluorinated monomer on emulsion polymerization and finished fabric properties. The monomer conversion increased first and then decreased as the pH and the amount of fluorine monomer increased, while a reverse trend was noted for the particle size and particle size distribution. The results obtained from TEM verified that the latex particles presented a spher-like mophology with a well-defined core–shell structure. ¹H-NMR and FT-IR spectroscopy were employed to study the chemical structure of cellulose nanocrystal-dressed fluorinated polyacrylate latex particles. The SEM and EDX analysis indicated that cellulose nanocrystal-dressed fluorinated polyacrylate latex particles were successfully adhered to the fiber surface and the finished fabric presented a relatively rough surface morphology. The contact angle results exhibited the finished fabric had excellent water and oil resistance.

Graphic abstract

Vorheriger Artikel Naturally occurring betaine grafted on cotton fabric for achieving antibacterial and anti-protein adsorption functions

Nächster Artikel Diclofenac release from alginate/carboxymethyl cellulose mono and bilayer films for wound dressing applications

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Baidya A, Das SK, Ras RHA, Pradeep T (2018) Fabrication of a waterborne durable superhydrophobic material functioning in air and under oil. Adv Mater Interfaces. https://doi.org/10.1002/admi.201701523 CrossRef

Chen A, Blakey I, Jack KS, Whittaker AK, Peng H (2015a) Control through monomer placement of surface properties and morphology of fluoromethacrylate copolymers. J Polym Sci, Part A: Polym Chem 53:2633–2641

Chen X, Zhou JH, Ma JZ (2015b) Synthesis of a cationic fluorinated polyacrylate emulsifier-free emulsion via ab initio RAFT emulsion polymerization and its hydrophobic properties of coating films. RSC Adv 5:97231–97238

Chen QH, Zheng J, Xu YT, Yin SW, Liu F, Tang CH (2018) Surface modification improves fabrication of Pickering high internal phase emulsions stabilized by cellulose nanocrystals. Food Hydrocolloids 75:125–130

Cherhal F, Cousin F, Capron I (2016) Structural description of the interface of Pickering emulsions stabilized by cellulose nanocrystals. Biomacromol 17:496–502

Clélia M, Bruno J (2014) Nanocellulose/polymer multilayered thin films: tunable architectures towards tailored physical properties. Nord Pulp Pap Res J 29:19–30

Cunningham MF, Jessop PG (2016) An introduction to the principles and fundamentals of CO₂-switchable polymers and polymer colloids. Eur Polym J 76:208–215

Darabi A, Jessop PG, Cunningham MF (2016) CO₂-responsive polymeric materials: synthesis, self-assembly, and functional applications. Chem Soc Rev 45:4391–4436

Dong XQ, Xu J, Cao CB, Sun DJ, Jiang XR (2010) Aqueous foam stabilized by hydrophobically modified silica particles and liquid paraffin droplets. Colloid Surf A, Physicochem Eng Asp 353:181–188

Du WB, Guo J, Li HM, Gao Y (2017a) Heterogeneously modified cellulose nanocrystals-stabilized Pickering emulsion: preparation and their template application for the creation of PS microspheres with amino-rich surfaces. ACS Sustain Chem Eng 5:7514–7523

Du X, Zhang Z, Liu W, Deng YL (2017b) Nanocellulose-based conductive materials and their emerging applications in energy devices: a review. Nano Energy 35:299–320

Errezma M, Mabrouk AB, Magnin A, Dufresne A, Boufi S (2018) Surfactant-free emulsion Pickering polymerization stabilized by aldehyde-functionalized cellulose nanocrystals. Carbohydr Polym 202:621–630

El-Fattah MA, Hasan AMA, Keshawy M, El Saeed AM (2018) Nanocrystalline cellulose as an eco-friendly reinforcing additive to polyurethane coating for augmented anticorrosive behavior. Carbohydr Polym 183:311–318

Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110:3479–3500

Jiang YJ, Li L, Liu JP, Wang R, Wang HS, Tian Q, Li XY (2016) Hydrophobic films of acrylic emulsion by incorporation of fluorine-based copolymer prepared through the RAFT emulsion copolymerization. J Fluorine Chem 183:82–91

Kannan KC, Corsolini S, Falandysz J, Oehme G, Focardi S, Giesy JP (2002) Perfluorooctanesulfonate and related fluorinated hydrocarbons in marine mammals, fishes, and birds from coasts of the Baltic and the Mediterranean Seas. Environ Sci Technol 36:3210–3216

Khanjani P, Thomas King AW, Partl GJ, Johansson LS, Kostiainen MA, Ras RHA (2018) Superhydrophobic paper from nanostructured fluorinated cellulose esters. ACS Appl Mater Interfaces 10:11280–11288PubMedPubMedCentral

Li F, Mascheroni E, Piergiovanni L (2015) The potential of nanocellulose in the packaging field: a review. Packag Technol Sci 28:475–508

Li X, Li J, Gong J, Kuang YS, Mo LH (2018) Cellulose nanocrystals (CNCs) with different crystalline allomorph for oil in water Pickering emulsions. Carbohydr Polym 183:303–310

Liang JY, He L, Zuo YY, Chen ZY, Peng T (2018) An insight into the amphiphobicity and thermal degradation behavior of PDMS-based block copolymers bearing POSS and fluorinated units. Soft Matter 14:5235–5245

Lizundia E, Fortunati E, Dominici F, Vilas JL, León LM, Armentano I, Torre L, Kenny JM (2016) PLLA-grafted cellulose nanocrystals: role of the CNC content and grafting on the PLA bionanocomposite film properties. Carbohydr Polym 142:105–113

Lv C, Cui K, Li SC, Wu HT, Ma Z (2016) Polystyrene-b-poly(2,2,2-trifluoroethyl acrylate)-b-polystyrene copolymers: synthesis and fabrication of their hydrophobic porous films, spheres, and fibers. J Polym Sci, Part A: Polym Chem 54:678–685

Martin JW, Smithwick MM, Braune BM, Hoekstra PF, Muir DCG, Mabury SA (2004) Identification of long-chain perfluorinated acids in biota from the Canadian Arctic. Environ Sci Technol 38:373–380

Martin S, Bhushan B (2017) Transparent, wear-resistant, superhydrophobic and superoleophobic poly(dimethylsiloxane) (PDMS) surfaces. J Colloid Interface Sci 488:118–126

Mougel JB, Bertoncini P, Cathala B, Chauvet O, Capron I (2019) Macroporous hybrid Pickering foams based on carbon nanotubes and cellulose nanocrystals. J Colloid Interface Sci 544:78–87

Moustafa H, Youssef AM, Darwish NA, Abou-Kandil AI (2019) Eco-friendly polymer composites for green packaging: future vision and challenges. Compos Part B: Eng 172:16–25

Ng HM, Sin LT, Tee TT, Bee ST, Hui D, Low CY, Rahmat AR (2015) Extraction of cellulose nanocrystals from plant sources for application as reinforcing agent in polymers. Compos Part B: Eng 75:176–200

Qiao Z, Qiu T, Liu WW, Zhang LD, Tu JQ, Guo LH, Li XY (2017) A “green” method for preparing ABCBA penta-block elastomers by using RAFT emulsion polymerization. Polym Chem 8:3013–3021

Scaffaro R, Botta L, Lopresti F, Maio A, Sutera F (2016) Polysaccharide nanocrystals as fillers for PLA based nanocomposites. Cellulose 24:447–478

Tang JT, Lee MFX, Zhang W, Zhao BX, Berry RM, Tam KC (2014) Dual responsive Pickering emulsion stabilized by poly[2-(dimethylamino)ethyl methacrylate] grafted cellulose nanocrystals. Biomacromol 15:3052–3060

Tang CX, Chen YM, Luo JH, Low MY, Shi ZQ, Tang JT, Zhang Z, Peng BL, Tam KC (2019) Pickering emulsions stabilized by hydrophobically modified nanocellulose containing various structural characteristics. Cellulose 26:7753–7767

Valdez OG, Brescacin T, Arredondo J, Bouchard J, Jessop PG, Champagne P, Cunningham MF (2017) Grafting CO₂-responsive polymers from cellulose nanocrystals via nitroxide-mediated polymerisation. Polym Chem 8:4124–4131

Wang ZH, Carlsson DO, Tammela P, Hua K, Zhang P, Nyholm L, Strømme M (2015) Surface modified nanocellulose fibers yield conducting polymer-based flexible supercapacitors with enhanced capacitances. ACS Nano 9:7563–7571

Werner A, Schmitt V, Sèbe G, Héroguez V (2017) Synthesis of surfactant-free micro- and nanolatexes from Pickering emulsions stabilized by acetylated cellulose nanocrystals. Polym Chem 8:6064–6072

Xu T, Xiao QQ, Chen JY, Li L, Yang XJ, Liu LF, Yuan WH, Zhang BJ, Wu HJ (2019) Hydrophobicity of polyacrylate emulsion film enhanced by introduction of nano-SiO₂ and fluorine. Polymers. https://doi.org/10.3390/polym11020255 CrossRefPubMedPubMedCentral

Xu W, An QF, Hao LF, Zhang D, Zhang M (2014) Synthesis of self-crosslinking fluorinated polyacrylate soap-free latex and its waterproofing application on cotton fabrics. Fiber Polym 15:457–464

Yan N, Masliyah JH (1996) Effect of pH on adsorption and desorption of clay particles at oil-water interface. J Colloid Interface Sci 181:20–27

Yao HT, Zhou JH, Li H, Zhao JJ (2019) Nanocrystalline cellulose/fluorinated polyacrylate latex via RAFT-mediated surfactant-free emulsion polymerization and its application as waterborne textile finishing agent. J Polym Sci, Part A: Polym Chem 57:1305–1314

Zhang QH, Wang QY, Zhan XL, Chen FQ (2014) Synthesis and performance of novel fluorinated acrylate polymers: preparation and reactivity of short perfluoroalkyl group containing monomers. Ind Eng Chem Res 53:8026–8034

Zhang CF, Xu TT, Bao ZB, Fu ZG, Chen LJ (2016) Synthesis and characterization of polyacrylate latex containing fluorine and silicon via semi-continuous seeded emulsion polymerization. J Adhes Sci Technol 31:1658–1670

Zhi DF, Lu Y, Sathasivam S, Parkin IP, Zhang X (2017) Large-scale fabrication of translucent and repairable superhydrophobic spray coatings with remarkable mechanical, chemical durability and UV resistance. J Mater Chem A 5:10622–10631

Zhou JH, Zhang L, Ma JZ (2013) Fluorinated polyacrylate emulsifier-free emulsion mediated by poly(acrylic acid)-b-poly(hexafluorobutyl acrylate) trithiocarbonate via ab initio RAFT emulsion polymerization. Chem Eng J 223:8–17

Zhou JH, Wang HL, Zhang L, Ma JZ (2014a) Ab initioreversible addition-fragmentation chain transfer emulsion polymerization of styrene/butyl acrylate mediated by poly(acrylic acid)-block-polystyrene trithiocarbonate. Polym Int 63:2098–2104

Zhou JH, Wang LB, Cui YJ, Ma JZ (2014b) Synthesis and properties of nano-TiO₂ modified fluorine-containing polyacrylate soap-free emulsion. Mater Sci Forum 809–810:161–168

Zhou JH, Chen X, Duan H, Ma JZ, Ma YR (2015) Synthesis and characterization of nano-SiO₂ modified fluorine-containing polyacrylate emulsifier-free emulsion. Appl Surf Sci 331:504–511

Zhou JH, Chen X, Ma JZ (2016) Cationic fluorinated polyacrylate emulsifier-free emulsion mediated by poly(2-(dimethylamino) ethyl methacrylate)-b-poly(hexafluorobutyl acrylate) trithiocarbonate via ab initio RAFT emulsion polymerization. Prog Org Coat 100:86–93

Zhou JH, Chen X, Ma JZ (2017) Synthesis of cationic fluorinated polyacrylate copolymer by RAFT emulsifier-free emulsion polymerization and its application as waterborne textile finishing agent. Dyes Pigments 139:102–109

Zhou JH, Yao HT, Ma JZ (2018) Recent advances in RAFT-mediated surfactant-free emulsion polymerization. Polym Chem 9:2532–2561

Zhou JH, Li YN, Li H, Yao HT (2019) Cellulose nanocrystals/fluorinated polyacrylate soap-free emulsion prepared via RAFT-assisted Pickering emulsion polymerization. Colloid Surf B, Biointerfaces 177:321–328

Titel: Preparation of cellulose nanocrystal-dressed fluorinated polyacrylate latex particles via RAFT-mediated Pickering emulsion polymerization and application on fabric finishing
verfasst von: Jianhua Zhou
Xueli Wang
Yannan Li
Hong Li
Kun Lu
Publikationsdatum: 20.05.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 11/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03227-1

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 11/2020

The influence of pre-fibrillation via planetary ball milling on the extraction and properties of chitin nanofibers

Controlling interfacial interactions in LDPE/flax fibre biocomposites by a combined chemical and radiation-induced grafting approach

Fabrication of flexible polyindole/carbon nanotube/bacterial cellulose nanofiber nonwoven electrode doped by D-tartaric acid with high electrochemical performance

A comparative study of depositing Cu-BTC metal–organic framework onto cellulosic filter paper via different procedures

Optimization of cellulase production by a novel endophytic fungus Pestalotiopsis microspora TKBRR isolated from Thalakona forest

Novel linen/polyethyleneimine/sodium decadecanate photochromic fabric prepared by layer-by-layer self-assembly method