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Cellulose

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10.03.2016 | Original Paper

Preparation of hairy cationic nanocrystalline cellulose

verfasst von: Han Yang, Theo G. M. van de Ven

Erschienen in: Cellulose | Ausgabe 3/2016

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Abstract

A hairy cationic nanocellulose (CNCC) was prepared by a two-step reaction. First dialdehyde modified cellulose (DAMC) were prepared by periodate oxidation of cellulose fibers and subsequently DAMC fibers were cationized by a reaction between the aldehyde groups of cellulose and (2-hydrazinyl-2-oxoethyl)-trimethylazanium chloride [Girard’s reagent T (GT)] to produce cationic dialdehyde cellulose (CDAMC) fibers. Subjecting the suspension of CDAMC fibers to a hot-water treatment at 60 °C, resulted in the formation of cationic rod-like nanocellulose (CNCC). Atomic force microscopy and transmission electron microscopy showed the CNCC has a width of 5 nm and a length about 120 nm. Zeta potential measurement, Fourier transform infrared spectroscopy, solid carbon-13 NMR and X-ray photoelectron spectroscopy confirmed the presence of cationic groups on CNCC. The positive charge content of CNCC is about 1.68 mmol/g measured by conductometric titration. CNCC has a crystalline index of 67 % and possesses cellulose I crystalline structure.

Vorheriger Artikel Optimization of sulfuric acid hydrolysis conditions for preparation of nanocrystalline cellulose from enzymatically pretreated fibers

Nächster Artikel Sago seed shell: determination of the composition and isolation of microcrystalline cellulose (MCC)

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Titel: Preparation of hairy cationic nanocrystalline cellulose
verfasst von: Han Yang
Theo G. M. van de Ven
Publikationsdatum: 10.03.2016
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-016-0902-5

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