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Journal of Materials Science
Erschienen in: Journal of Materials Science 18/2019

19.06.2019 | Energy materials

Preparation of PAN-based carbon fiber@MnO2 composite as an anode material for structural lithium-ion batteries

verfasst von: Qigang Han, Wenqiang Zhang, Zhiwu Han, Fangxue Wang, Di Geng, Xiang Li, Yao Li, Xu Zhang

Erschienen in: Journal of Materials Science | Ausgabe 18/2019

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Abstract

Carbon fiber@MnO2 composite (CF@MnO2) has been successfully synthesized based on the redox mechanism, and the morphological and electrochemical features are also studied. As a promising anode material for structural lithium-ion batteries (SLIBs), CF@MnO2 composite presents a coulombic efficiency of over 99% and good cyclic ability. It performs a high reversible capacity of 648 mAh g−1 after 150 cycles at a current density of 100 mA g−1, approximately 2.5 times as high as the pure CF (~ 260 mAh g−1). Moreover, the images of attained composite after the cycle show the fibrous structure do not change much, which verifies it retains good cycle stability. The superior electrochemical performance of the CF@MnO2 composite can be attributed to the unique hierarchy architecture and the synergistic effect between MnO2 and CF, which can effectively alleviate the volume expansion of MnO2 during the lithium insertion/extraction.
Vorheriger Artikel Modification of porous carbon with nitrogen elements to enhance the capacitance of supercapacitors
Nächster Artikel Bifunctional interlayer for capturing polysulfide in Li–S battery

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Metadaten
Titel
Preparation of PAN-based carbon fiber@MnO2 composite as an anode material for structural lithium-ion batteries
verfasst von
Qigang Han
Wenqiang Zhang
Zhiwu Han
Fangxue Wang
Di Geng
Xiang Li
Yao Li
Xu Zhang
Publikationsdatum
19.06.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03751-x

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