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Erschienen in: Journal of Polymer Research 8/2014

01.08.2014 | Original Paper

Preparation of pH- and salinity-responsive cellulose copolymer in ionic liquid

verfasst von: Xiaoyi Wei, Gang Chang, Jihua Li, Fei Wang, Lihong Cui, Tiaokun Fu, Lingxue Kong

Erschienen in: Journal of Polymer Research | Ausgabe 8/2014

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Abstract

A novel biodegradable pH- and salinity-responsive cellulose copolymer was prepared by grafting 2-(Dimethylamino) ethylmethacrylate (DMAEMA) onto bagasse cellulose in ionic liquid. The grafting polymerization was achieved in 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) under microwave irradiation. Copolymers were then characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and thermo gravimetric analysis measurements. The results revealed that polymer chains had been successfully bonded to the cellulose backbone. Furthermore, the self-assembly of cellulose-g-DMAEMA copolymers at various salt concentrations and pH solution were investigated by means of swelling behavior measurement. It indicated that the copolymers presented dual pH and salinity-responsive properties. The synthetic strategy showed great potential in the modification of other cellulosic biomass to afford new biomaterials with desired properties.

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Metadaten
Titel
Preparation of pH- and salinity-responsive cellulose copolymer in ionic liquid
verfasst von
Xiaoyi Wei
Gang Chang
Jihua Li
Fei Wang
Lihong Cui
Tiaokun Fu
Lingxue Kong
Publikationsdatum
01.08.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 8/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-014-0535-z

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