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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 1/2015

01.01.2015 | Original Contribution

Preparation of polymer microspheres with reactive epoxy group and amino groups as stabilizers for gold nanocolloids with recoverable catalysis

verfasst von: Tao Song, Meijun Zhou, Wei Liu, Guomin Bian, Yonglin Qi, Feng Bai, Xinlin Yang

Erschienen in: Colloid and Polymer Science | Ausgabe 1/2015

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Abstract

Narrow disperse poly(divinylbenzene-co-glycidyl methacrylate) (P(DVB-co-GMA)) microspheres with reactive epoxy group were prepared by distillation precipitation copolymerization of divinylbenzene (DVB) and glycidyl methacrylate (GMA) with benzoyl peroxide (BPO) as initiator in neat acetonitrile. The epoxy group was modified with ethylenediamine (EDA) for transferring to amino group, which was used as a stabilizer for the gold metallic nanocolloids during the in situ reduction of gold chloride trihydrate (HAuCl4) with sodium borohydride (NaBH4) as a reductant. The catalytic properties of the microsphere-stabilized gold nanocolloids (P(DVB-co-GMA)-NH2@Au) were investigated by the reduction of aqueous 4-nitrophenol (4-NP) to 4-aminophenol (4-AnP) with NaBH4 as reductant. The resultant microspheres were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectra (FT-IR), elemental analysis (EA), Zeta potential, X-ray photoelectron spectroscopy (XPS), inductively coupled plasma (ICP) mission spectrum, and ultraviolet–visible spectroscopy.
Vorheriger Artikel Escherichia coli adhesion to surfaces–a thermodynamic assessment
Nächster Artikel Relationship between helical aggregates and polymorphs in a 12-hydroxystearic acid gel: their thermal stability and formation kinetics

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Metadaten
Titel
Preparation of polymer microspheres with reactive epoxy group and amino groups as stabilizers for gold nanocolloids with recoverable catalysis
verfasst von
Tao Song
Meijun Zhou
Wei Liu
Guomin Bian
Yonglin Qi
Feng Bai
Xinlin Yang
Publikationsdatum
01.01.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 1/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3408-4

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