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Topics in Catalysis

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04.06.2018 | Original Paper

Process Intensification by Exploiting Diluted 2nd Generation Bio-ethanol in the Low-Temperature Steam Reforming Process

verfasst von: Antonio Tripodi, Matteo Compagnoni, Elnaz Bahadori, Ilenia Rossetti, Gianguido Ramis

Erschienen in: Topics in Catalysis | Ausgabe 18-19/2018

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Abstract

Second generation bioethanol, obtained by the fermentation of lignocellulosic biomass, which is not competitive with the food and feed field, is one of the most interesting promising biofuels, already available in semi-commercial amount. Steam reforming of bioethanol has been used here for sustainable hydrogen and syngas production. Differently purified second generation bioethanol feeds, directly supplied by an industrial plant, for the steam reforming process, assessing the influence of impurities and catalyst formulation. Ni/La₂O₃, Ni/ZrO₂ and Ni/CaO–ZrO₂ prepared by Flame Spray Pyrolysis were used as catalysts. Catalytic performance at high and low temperature was evaluated in order to investigate a broad range of temperature, which is one of the most critical condition in term of catalyst activity and deactivation, besides energy saving. The possible effect of impurities contained in less purified feedstocks is also discussed. Stable performance up to 100 h-on-stream was attained even under stressing reaction conditions.

Vorheriger Artikel First-Principle Microkinetic Modeling of Ethanol Dehydrogenation on Metal Catalyst Surfaces in Non-oxidative Environment: Design of Bimetallic Alloys

Nächster Artikel The Impact of La Doping on Dry Reforming Ni-Based Catalysts Loaded on FSP-Alumina

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Titel: Process Intensification by Exploiting Diluted 2nd Generation Bio-ethanol in the Low-Temperature Steam Reforming Process
verfasst von: Antonio Tripodi
Matteo Compagnoni
Elnaz Bahadori
Ilenia Rossetti
Gianguido Ramis
Publikationsdatum: 04.06.2018
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 18-19/2018
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-018-1002-6

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