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2014 | OriginalPaper | Buchkapitel

24. Production of Renewable Hydrogen by Aqueous-Phase Reforming of Glycerol Over Ni-Cu Catalysts Derived from Hydrotalcite Precursors

verfasst von : Pablo Tuza, Robinson L. Manfro, Nielson F. P. Ribeiro, Mariana M.V.M. Souza

Erschienen in: Progress in Sustainable Energy Technologies: Generating Renewable Energy

Verlag: Springer International Publishing

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Abstract

Ni-Cu catalysts derived from hydrotalcite-like compounds were prepared and evaluated in aqueous-phase reforming of glycerol. The catalysts were characterized by chemical composition, textural analysis, crystalline structure and reducibility. The reaction was carried out in a batch reactor with solution of 10 wt. % glycerol, at 250 and 270 °C. A maximum glycerol conversion of 60 % was achieved at 270 °C. In the gas phase, the H₂ selectivity was always higher than 80 % and formation of CO was very low (< 3 %) at 250 °C. The addition of Cu decreased the formation of methane. H₂ is consumed during the reaction at 270 °C, mainly for Cu-containing catalysts, with simultaneous formation of propylene glycol in the liquid phase. Acetol, lactic acid and acetaldehyde were also formed in the liquid phase, at both temperatures.

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Dunn S (2002) Hydrogen futures: toward a sustainable energy system. Int J Hydrog Energy 27:235–264CrossRef

Huber GW, Iborra S, Corma A (2006) Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev 106:4044–4098CrossRef

Adhikari S, Fernando SD, Haryanto A (2009) Hydrogen production from glycerol: an update. Energy Conv Manage 50:2600–2604CrossRef

Cortright RD, Davda RR, Dumesic JA (2002) Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water. Nature 418:964–967CrossRef

Davda RR, Shabaker JW, Huber GW, Cortright, RD, Dumesic JA (2005) A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts. Appl Catal B 56:171–186CrossRef

Shabaker JW, Davda RR, Huber GW, Cortright RD, Dumesic JA (2003) Aqueous-phase reforming of methanol and ethylene glycol over alumina-supported platinum catalysts. J Catal 215:344–352CrossRef

Cruz IO, Ribeiro NFP, Aranda DAG, Souza MMVM (2008) Hydrogen production by aqueous-phase reforming of ethanol over nickel catalysts prepared from hydrotalcite precursors. Catal Comm 9:2606–2611CrossRef

Behr A, Eilting J, Irawadi K, Leschinski J, Lindner F (2008) Improved utilisation of renewable resources: new important derivatives of glycerol. Green Chem.10:13–30CrossRef

Shabaker JW, Huber GW, Dumesic JA (2004) Aqueous-phase reforming of oxygenated hydrocarbons over Sn-modified Ni catalysts. J Catal 222:180–191CrossRef

10.

Cavani F, Trifiró F, Vaccari A (1991) Hydrotalcite-type anionic clays: preparation, properties and applications. Catal Today 11:173–301CrossRef

11.

Basile F, Basini L, D’Amore M, Fornasari G, Guarinoni A, Matteuzzi D, Del Piero G, Trifiro F, Vaccari A (1998) Ni/Mg/Al anionic clay derived catalysts for the catalytic partial oxidation of methane: residence time dependence of the reactivity features. J Catal 173:247–256CrossRef

12.

Tsyganok AI, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T (2003) Dry reforming of methane over catalysts derived from nickel-containing Mg–Al layered double hydroxides. J Catal 213:191–203CrossRef

13.

Ferreira KA, Ribeiro NFP, Souza MMVM, Schmal M (2009) Structural transformation of Cu–Mg–Al mixed oxide catalysts derived from hydrotalcites during shift reaction. Catal Lett 132:58–63CrossRef

14.

Dussault L, Dupin JC, Dumitriu E, Auroux A, Guimon C (2005) Microcalorimetry, TPR and XPS studies of acid–base properties of NiCuMgAl mixed oxides using LDHs as precursors. Thermochimica Acta 434:93–99CrossRef

15.

Kannan S, Dubey A, Knozinger H (2005) Synthesis and characterization of CuMgAl ternary hydrotalcites as catalysts for the hydroxylation of phenol. J Catal 231:381–392CrossRef

16.

Chmielarz L, Kustrowski P, Rafalska-Łasocha A, Majda D, Dziembaj R (2002) Catalytic activity of Co-Mg-Al, Cu-Mg-Al and Cu-Co-Mg-Al mixed oxides derived from hydrotalcites in SCR of NO with ammonia. Appl Catal B 35:195–210CrossRef

17.

Kovanda F, Jirátová K, Rymes J, Kolousek D (2001) Characterization of activated Cu/Mg/Al hydrotalcites and their catalytic activity in toluene combustion. Appl Clay Sci 18:71–80CrossRef

18.

Takehira K, Shishido T, Wang P, Kosaka T, Takaki K (2004) Autothermal reforming of CH4 over supported Ni catalysts prepared from Mg–Al hydrotalcite-like anionic clay. J Catal 221:43–54CrossRef

19.

Fornasari G, Gazzano M, Matteuzzi D, Trifiró F, Vaccari A (1995) Structure and reactivity of high-surface-area Ni/Mg/Al mixed oxides. Appl Clay Sci 10:69–82CrossRef

20.

Anderson JR (1975) Structure of metallic catalysts. Academic Press New York

21.

Shishido T, Sukenobu M, Morioka H, Furukawa R, Shirahase H, Takehira K (2001) CO₂ reforming of CH4 over Ni/Mg–Al oxide catalysts prepared by solid phase crystallization method from Mg–Al hydrotalcite-like precursors. Catal Letters 73:21–6CrossRef

22.

Ashok J, Subrahmanyam M, Venugopal A (2008) Hydrotalcite structure derived Ni-Cu-Al catalysts for the production of H2 by CH4 decomposition. Int J Hydrog Energy 33:2704–2713CrossRef

23.

Manfro RL, Costa AF, Ribeiro NFP, Souza MMVM (2011) Hydrogen production by aqueous-phase reforming of glycerol over nickel catalysts supported on CeO₂. Fuel Proc Technol 92:330–335CrossRef

24.

Wawrzetz A, Peng B, Hrabar A, Jentys A, Lemonidou AA, Lercher JA (2010) Towards understanding the bifunctional hydrodeoxygenation and aqueous phase reforming of glycerol. J Catal 269:411–420CrossRef

25.

Grenoble DC, Estadt MM, Ollis DF (1981) The chemistry and catalysis of the water gas shift reaction: 1. The kinetics over supported metal catalysts. J Catal 67:90–102CrossRef

26.

Vannice MA (1977) The catalytic synthesis of hydrocarbons from H2/CO mixtures over the Group VIII metals: V. The catalytic behavior of silica-supported metals. J Catal 50:228–236CrossRef

27.

Ramírez-López CA, Ochoa-Gómez JR, Fernández-Santos M, Gómez-Jiménez-Aberasturi O, Alonso-Vicario A, Torrecilla-Soria J (2010) Synthesis of lactic acid by alkaline hydrothermal conversion of glycerol at high glycerol concentration. Ind Eng Chem Res 49:6270–6278CrossRef

28.

Miyazawa T, Kusunoki Y, Kunimori K, Tomishige K (2006) Glycerol conversion in the aqueous solution under hydrogen over Ru/C + an ion-exchange resin and its reaction mechanism. J Catal 240:213–221CrossRef

29.

King DL, Zhang L, Xia G, Karim AM, Heldebrant DJ, Wang X, Peterson T, Wang Y (2010) Aqueous phase reforming of glycerol for hydrogen production over Pt–Re supported on carbon. Appl Catal B 99:206–213CrossRef

30.

Pompeo F, Santori G, Nichio NN (2010) Hydrogen and/or syngas from steam reforming of glycerol: study of platinum catalysts. Int J Hydrog Energy 35:8912–8920CrossRef

31.

Dasari MA, Kiatsimkul PP, Sutterlin WR, Suppes GJ (2005) Low-pressure hydrogenolysis of glycerol to propylene glycol. Appl Catal A 281:225–231CrossRef

32.

Nakagawa Y, Tomishige K (2011) Heterogeneous catalysis of the glycerol hydrogenolysis. Catal Sci Technol 1:179–190CrossRef

33.

Yuan Z Wang J, Wang L Xie W, Chen P Hou Z, Zheng X (2010) Biodiesel derived glycerol hydrogenolysis to 1,2-propanediol on Cu/MgO catalysts. Bioresour Technol 101:7088–7092CrossRef

34.

Meher LC, Gopinath R, Naik SN, Dalai AK (2009) Catalytic hydrogenolysis of glycerol to propylene glycol over mixed oxides derived from a hydrotalcite-type precursor. Ind Eng Chem Res 48:1840–1846CrossRef

Titel: Production of Renewable Hydrogen by Aqueous-Phase Reforming of Glycerol Over Ni-Cu Catalysts Derived from Hydrotalcite Precursors
verfasst von: Pablo Tuza
Robinson L. Manfro
Nielson F. P. Ribeiro
Mariana M.V.M. Souza
Verlag: Springer International Publishing
Buch: Progress in Sustainable Energy Technologies: Generating Renewable Energy
Print ISBN: 978-3-319-07895-3

Electronic ISBN: 978-3-319-07896-0

Copyright-Jahr: 2014
DOI: https://doi.org/10.1007/978-3-319-07896-0_24

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