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2014 | OriginalPaper | Buchkapitel

10. Properties and Performance of Polymer Blends

verfasst von : S. F. Xavier

Erschienen in: Polymer Blends Handbook

Verlag: Springer Netherlands

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Abstract

This chapter presents an overview of properties and performance of polymer blends. It is structured into nine sections dealing with aspects required for assessing the performance of a polymer blend. These are mechanical properties comprising of both low-speed and high-speed popularly studied properties; chemical and solvent effects; thermal and thermodynamic properties; flammability; electrical, optical, and sound transmission properties; and some special test methods which assumed prominence recently because of their utility.
Each section opens up with standard test methods such as ASTM, BS, DIN, and ISO for each property evaluation and is summarized. Since presentation of all test methods for each property is beyond the scope of this chapter, one popular test method is described in detail while others are discussed with reference to it. The factors controlling each property are also examined. Each section concludes with an outline of the state of the art pertinent to the aspect in focus. Definitions of all terms from each section are grouped together in Table 10.36.
Toughening plays an important role in designing polymer blends. Due emphasis has been given to this aspect by presenting the different methods of determining blend toughness, specially using ductile fracture mechanics; the mechanisms of toughening; and also the factors influencing toughness. Flammability aspect assumed a great deal of interest ever since the US Federal Trade Commission’s (FTC) action in 1972. Commercial exploitation of a polymer blend is regulated, since then, by its flammability characteristics. A brief review on factors affecting flammability is presented, and a list of fire-retardant chemicals is provided in Table 10.37.
The recent advances in optical properties, sound transmission properties, and certain “special testing methods” are presented at the closing of the chapter. These “special test methods” are not yet matured into international test methods but, nevertheless, are popularly used for meeting the requirements of certain applications. Hence, awareness of these methods is considered to be essential. The chapter concludes with perspectives for the future developments.

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Glossar
ABS
Poly(acrylonitrile-co-butadiene styrene)
ASTM
American Standard Test Method
BS
British Standard
CAB
Cellulose acetate butyrate
DGEBA
Diglycidyl ether of bisphenol A
DSC
Differential scanning calorimetry
ENR
Epoxidized natural rubber
EVA
Ethylene-co-vinylacetate
EPDM
Ethylene propylene diene monomer
ESC
Environmental stress cracking
HDT
Heat deflection/distortion temperature
HDPE
High-density polyethylene
HIPS
High-impact polystyrene
HTBN
Hydroxyl terminated poly(butadiene/acrylonitrile)
IGC
Inverse gas chromatography
LCST
Lower critical solution temperature
LEFM
Linear elastic fracture mechanics
LLDPE
Linear low-density polyethylene
OIT
Oxidative induction time
PA-6
Polyamide-6
PA-66
Polyamide-66
PBMA
Poly(butyl methacrylate)
PBT
Polybutylene terephthalate
PC
Polycarbonate
PCL
Poly(ε-caprolactone)
PE
Polyethylene
PEEK
Polyether ether ketone
PEI
Polyetherimide
PEO
Polyethylene oxide
PEOx
Poly(ethyl oxazoline)
PES
Polyethylene sulphide
PET
Poly ethylene terephthalate
PLLA
Poly(l-lactic acid)
PMMA
Poly(methyl methacrylate)
POM
Polyoxymethylene
PPBC
Polypropylene block copolymer
PPHP
Polypropylene homopolymer
PPS
Polyphenylene sulphide
PPO
Polyphenylene oxide
PS
Poly styrene
PSMA
Poly(styrene-co-maleic anhydride)
PTFE
Poly tetra fluoro ethylene
PTT
Poly(trimethylene terephthalate)
PVAc
Polyvinyl acetate
PVB
Polyvinyl butyral
PVC
Polyvinyl chloride
PVDF
Polyvinylidene fluoride
PVME
Poly(vinyl methyl ether)
PVP
Polyvinyl pyrrolidone
PVPh
Poly(4-vinylphenol)
SAN
Poly(styrene-co-acrylonitrile)
SANS
Small-angle neutron scattering
SAXS
Small-angle X-ray scattering
SF
Silk fibroin
SMA
Styrene-co-maleic anhydride
SPEEK
Sulfonated poly(ether ether ketone)
TGA
Thermogravimetric analyzer
TMOS
Tetramethyl bisphenol A oligosulfones
UCST
Upper critical solution temperature
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Zurück zum Zitat M.M. Coleman, J.T. Graf, P.C. Painter, Specific Interactions and the Miscibility of Polymer Blends (Technomic, Lancaster, 1991) M.M. Coleman, J.T. Graf, P.C. Painter, Specific Interactions and the Miscibility of Polymer Blends (Technomic, Lancaster, 1991)
Zurück zum Zitat B.F. Conaghan, S.L. Rosen, Polym. Eng. Sci. 12, 134 (1972) B.F. Conaghan, S.L. Rosen, Polym. Eng. Sci. 12, 134 (1972)
Zurück zum Zitat P.R. Couchman, Macromolecules 11, 1156 (1978) P.R. Couchman, Macromolecules 11, 1156 (1978)
Zurück zum Zitat J. Crank, G.S. Park, in Diffusion of Polymers, ed. by J. Crank, G.S. Park (Academic, New York, 1968). Chapter 1 J. Crank, G.S. Park, in Diffusion of Polymers, ed. by J. Crank, G.S. Park (Academic, New York, 1968). Chapter 1
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Zurück zum Zitat T. Daniels, Thermal Analysis (Kogan Page, London, 1973) T. Daniels, Thermal Analysis (Kogan Page, London, 1973)
Zurück zum Zitat K.C. Dao, J. Appl. Polym. Sci. 27, 4799 (1982) K.C. Dao, J. Appl. Polym. Sci. 27, 4799 (1982)
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Zurück zum Zitat A. Dasari, Z.Z. Yu, Y.W. Mai, S. Liu, Nanotechnology 18, 445602 (2007) A. Dasari, Z.Z. Yu, Y.W. Mai, S. Liu, Nanotechnology 18, 445602 (2007)
Zurück zum Zitat D.S. Davis, U.S. Patent 7,439,306, 2008 to ExxonMobil Chemical Patents Inc. D.S. Davis, U.S. Patent 7,439,306, 2008 to ExxonMobil Chemical Patents Inc.
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Zurück zum Zitat DIN 53435, Testing of Plastics Determination of Flexural Properties and Impact Resistance with Dynstat Test Specimens (1977) DIN 53435, Testing of Plastics Determination of Flexural Properties and Impact Resistance with Dynstat Test Specimens (1977)
Zurück zum Zitat DIN 53442, Testing of Plastics: Fatigue Test in the Field of Bending Strain of Flat Specimens (1975) DIN 53442, Testing of Plastics: Fatigue Test in the Field of Bending Strain of Flat Specimens (1975)
Zurück zum Zitat DIN 53452, Testing of Plastics Bending Test (1977) DIN 53452, Testing of Plastics Bending Test (1977)
Zurück zum Zitat DIN 53453, Testing of Plastics; Determination of Impact Resistance (1975) DIN 53453, Testing of Plastics; Determination of Impact Resistance (1975)
Zurück zum Zitat DIN 53454, Testing of Plastics Compression Test (1971) DIN 53454, Testing of Plastics Compression Test (1971)
Zurück zum Zitat DIN 53456, Testing of Plastics Indentation Hardness (1979) DIN 53456, Testing of Plastics Indentation Hardness (1979)
Zurück zum Zitat DIN 53461, Testing of Plastics-Determination of Temperature of Deflection Under Load According to ISO 75 (1979) DIN 53461, Testing of Plastics-Determination of Temperature of Deflection Under Load According to ISO 75 (1979)
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Zurück zum Zitat DIN 53491, Testing of Plastics Determination of Refractive Index and Dispersion (1955) DIN 53491, Testing of Plastics Determination of Refractive Index and Dispersion (1955)
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Metadaten
Titel
Properties and Performance of Polymer Blends
verfasst von
S. F. Xavier
Copyright-Jahr
2014
Verlag
Springer Netherlands
DOI
https://doi.org/10.1007/978-94-007-6064-6_12

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