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01.08.2014 | Original Paper

Properties of electrospun PVDF/PMMA/CA membrane as lithium based battery separator

verfasst von: Tusiimire Yvonne, Chuyang Zhang, Changhuan Zhang, Edison Omollo, Sizo Ncube

Erschienen in: Cellulose | Ausgabe 4/2014

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Abstract

Poly vinylidene fluoride:poly methyl methacrylate:cellulose acetate (CA) at ratios of 100:0:0, 90:10:0, 90:5:5 and 90:0:10 respectively, were successfully electrospun. These membranes were mixed to form a 12 wt% solution prepared with volume ratio 7:3 of DMAc:acetone solvents. These membranes were then analyzed using differential scanning calorimetry, scanning electron microscopy, FTIR, WAXD, pore size, porosity% and electrolyte uptake (EU)%. It was observed that the best absorption results were obtained in the presence of CA. The electrospun membrane at ratio of 90:0:10 was observed with the highest porosity of 99.1 % and EU at 323 %. It also had a 43.6 % crystallinity and a 162 °C melting temperature. It was then concluded that addition of CA improved the separator properties.

Vorheriger Artikel Removal of Pb(II) and malachite green from aqueous solution by modified cellulose

Nächster Artikel Structure and properties of the regenerated cellulose membranes prepared from cellulose carbamate in NaOH/ZnO aqueous solution

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Titel: Properties of electrospun PVDF/PMMA/CA membrane as lithium based battery separator
verfasst von: Tusiimire Yvonne
Chuyang Zhang
Changhuan Zhang
Edison Omollo
Sizo Ncube
Publikationsdatum: 01.08.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-014-0296-1

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