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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 12/2019

22.05.2019

Proton transport and dielectric properties of high molecular weight polyvinylpyrrolidone (PVPK90) based solid polymer electrolytes for portable electrochemical devices

verfasst von: T. Regu, C. Ambika, K. Karuppasamy, Hashikaa Rajan, Dhanasekaran Vikraman, Ji-Hoon Jeon, Hyun-Seok Kim, T. Ajith Bosco Raj

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 12/2019

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Abstract

A simple solution cast route was used to prepare proton conducting solid polymer electrolytes using poly(methyl methacrylate) and poly(vinylpyrrolidone) as polymer hosts and methanesulfonic acid as a proton provider. Fourier transform infrared spectra confirmed functional group interactions between polymers, blended polymers, and acid. Polymer glass transition temperature shifted with increasing acid content in the blend electrolytes provide thermal stability up to 290 °C, verified by differential scanning calorimetry and thermogravimetry analyses. Proton conductivity achieved = 1.16 × 10−4 S/cm at room temperature with an ionic transport number of 0.98. Discharge profiles verified oxidation current < 10 μA for 2 V applied potential for the highly conductive electrolyte, confirming the prepared electrolytes as prime candidates for primary proton cells.
Vorheriger Artikel Enhanced electrical properties in A-site K/Ce and B-site W/Cr co-substituted CaBi2Nb2O9 high temperature piezoelectric ceramic
Nächster Artikel Existence of exchange bias and large coercivity in NiFe2O4/CoO core–shell structured nanoparticles

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Metadaten
Titel
Proton transport and dielectric properties of high molecular weight polyvinylpyrrolidone (PVPK90) based solid polymer electrolytes for portable electrochemical devices
verfasst von
T. Regu
C. Ambika
K. Karuppasamy
Hashikaa Rajan
Dhanasekaran Vikraman
Ji-Hoon Jeon
Hyun-Seok Kim
T. Ajith Bosco Raj
Publikationsdatum
22.05.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 12/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01535-2

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