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Clean Technologies and Environmental Policy

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02.05.2019 | Original Paper

Quaternary ammonium-functionalized rice straw hydrochar as efficient adsorbents for methyl orange removal from aqueous solution

verfasst von: Xiong Peng, Zongcheng Yan, Xi Cheng, Yu Li, Aili Wang, Li Chen

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 6/2019

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Abstract

In this study, a series of quaternary ammonium-modified hydrochars was fabricated using rice straw as raw material. The physicochemical properties of the hydrochars before and after modification were characterized by FTIR, XPS and CHN element analysis, and an adsorption mechanism was proposed. Results showed the quaternary ammonium groups were successfully grafted onto the hydrochar. The modified hydrochar showed favorable capacity for methyl orange (MO) elimination from aqueous solution with a maximum value of 849 mg/g, which was an order of magnitude higher than that of pristine hydrochar (49 mg/g). Besides, the MO adsorption of all the adsorbents fitted well with the pseudo-second-order and Langmuir models, and the adsorption process was exothermal. Analysis of the adsorption mechanism showed that the decontamination process was primarily controlled by electrostatic attractions and ion exchange.

Graphical abstract

Utilization of rice straw to produce quaternary ammonium-functionalized hydrochars for the efficient removal of methyl orange.

Vorheriger Artikel Photocatalytic decomposition of VOCs by AC–TiO2 and EG–TiO2 nanocomposites

Nächster Artikel Gasification of waste tires in a circulating fixed-bed reactor within the scope of waste to energy

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Titel: Quaternary ammonium-functionalized rice straw hydrochar as efficient adsorbents for methyl orange removal from aqueous solution
verfasst von: Xiong Peng
Zongcheng Yan
Xi Cheng
Yu Li
Aili Wang
Li Chen
Publikationsdatum: 02.05.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Clean Technologies and Environmental Policy / Ausgabe 6/2019
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI: https://doi.org/10.1007/s10098-019-01703-2

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Abstract

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