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Erschienen in: Journal of Materials Science 19/2018

24.05.2018 | Mechanochemical Synthesis

Rapid mechanochemical synthesis of titanium and hafnium carbides

verfasst von: Nikolay Lyakhov, Tatiana Grigoreva, Vladimir Šepelák, Boris Tolochko, Aleksey Ancharov, Sergey Vosmerikov, Evgeniya Devyatkina, Tatyana Udalova, Sofia Petrova

Erschienen in: Journal of Materials Science | Ausgabe 19/2018

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Abstract

The mechanically triggered interactions in the Ti–C and Hf–C systems performed in a high-energy planetary ball mill are studied. The formation of carbides (TiC and HfC) in the course of mechanochemical synthesis at the different stages is followed by both conventional and synchrotron X-ray diffraction analyses and high-resolution scanning and transmission electron microscopy. The mechanism of the mechanochemically induced reactions in the Ti–C and Hf–C systems leading to the relatively rapid formation of TiC and HfC, respectively, is proposed. The interaction between metallic Ti (Hf) and C proceeds through the formation of mechanocomposites Ti/C (Hf/C) at the first stage, followed by the melting of titanium (hafnium), the spreading it over the carbon particle surface and the crystallization of titanium (hafnium) carbides. It is demonstrated that the mechanosynthesis of ultra-fine TiC and HfC is completed after 20 and 8 min of mechanical activation, respectively.

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Metadaten
Titel
Rapid mechanochemical synthesis of titanium and hafnium carbides
verfasst von
Nikolay Lyakhov
Tatiana Grigoreva
Vladimir Šepelák
Boris Tolochko
Aleksey Ancharov
Sergey Vosmerikov
Evgeniya Devyatkina
Tatyana Udalova
Sofia Petrova
Publikationsdatum
24.05.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2450-x

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