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2020 | OriginalPaper | Buchkapitel

11. Reactive and Functional Silicones for Special Applications

verfasst von : Carmen Racles, Mihaela Dascalu, Adrian Bele, Maria Cazacu

Erschienen in: Reactive and Functional Polymers Volume One

Verlag: Springer International Publishing

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Abstract

With a history of almost 100 years, silicones -polymeric or oligomeric siloxanes- are well known as reliable materials with a wide range of applications, from home to the aerospace sector. The constant interest for these polymers is explained by their unique combination of properties, including chemical and physiological inertness, extreme resistance to ozone and corona discharge, film forming capacity, good thermal-oxidative and ultraviolet (UV) stability, high flexibility of the macromolecular chain, low dielectric constant, surface energy and transition temperatures, permeability to various gases, stability towards atomic oxygen and oxygen plasma, and UV-visible radiation transparency. The chemical modification of silicones is an active research area, since the attachment of several organic functional groups to the silicon atom imparts specific properties and triggers new applications. Functional siloxanes represent a bridge between siloxane and organic chemistry and combine valuable properties of silicones with reactivity and specific functions of organic moieties. In this chapter, the recent research progress in the field of functional organic siloxanes and their materials are reviewed, focusing on their applications in science and technology.

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Zurück zum Zitat Racles, C., Filip, D., Cazacu, M., Cozan, V., Tóth, A., & Ioanid, G. (2006a). New siloxane-organic polyesters with azobenzene side chains. Synthesis, thermotropic behavior and surface properties. Macromolecular Chemistry and Physics, 207(17), 1599–1609. https://doi.org/10.1002/macp.200600201.CrossRef Racles, C., Filip, D., Cazacu, M., Cozan, V., Tóth, A., & Ioanid, G. (2006a). New siloxane-organic polyesters with azobenzene side chains. Synthesis, thermotropic behavior and surface properties. Macromolecular Chemistry and Physics, 207(17), 1599–1609. https://​doi.​org/​10.​1002/​macp.​200600201.CrossRef
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Zurück zum Zitat Tao, H., Zhang, X., Sun, Y., Yang, H., & Lin, B. (2017). The influence of molecular weight of siloxane macromere on phase separation morphology, oxygen permeability, and mechanical properties in multicomponent silicone hydrogels. Colloid & Polymer Science, 295(1), 205–213. https://doi.org/10.1007/s00396-016-4001-9.CrossRef Tao, H., Zhang, X., Sun, Y., Yang, H., & Lin, B. (2017). The influence of molecular weight of siloxane macromere on phase separation morphology, oxygen permeability, and mechanical properties in multicomponent silicone hydrogels. Colloid & Polymer Science, 295(1), 205–213. https://​doi.​org/​10.​1007/​s00396-016-4001-9.CrossRef
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Zurück zum Zitat Teyssier, D., & Boileau, S. (2000). Liquid crystalline silicon-containing polymers. In R. G. Jones, W. Ando, & J. Chojnowski (Eds.), Silicon-containing polymers (pp. 593–613). Dordrecht: Kluver Academic Publishers.CrossRef Teyssier, D., & Boileau, S. (2000). Liquid crystalline silicon-containing polymers. In R. G. Jones, W. Ando, & J. Chojnowski (Eds.), Silicon-containing polymers (pp. 593–613). Dordrecht: Kluver Academic Publishers.CrossRef
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Zurück zum Zitat Wan Ibrahim, W. A., Abdul Keyon, A. S., Prastomo, N., & Matsuda, A. (2011). Synthesis and characterization of polydimethylsiloxane-cyanopropyltriethoxysilane-derived hybrid coating for stir bar sorptive extraction. Journal of Sol-Gel Science and Technology, 59(1), 128–134. https://doi.org/10.1007/s10971-011-2470-3.CrossRef Wan Ibrahim, W. A., Abdul Keyon, A. S., Prastomo, N., & Matsuda, A. (2011). Synthesis and characterization of polydimethylsiloxane-cyanopropyltriethoxysilane-derived hybrid coating for stir bar sorptive extraction. Journal of Sol-Gel Science and Technology, 59(1), 128–134. https://​doi.​org/​10.​1007/​s10971-011-2470-3.CrossRef
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Metadaten
Titel
Reactive and Functional Silicones for Special Applications
verfasst von
Carmen Racles
Mihaela Dascalu
Adrian Bele
Maria Cazacu
Copyright-Jahr
2020
DOI
https://doi.org/10.1007/978-3-030-43403-8_11

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.