Skip to main content
Erschienen in: Journal of Materials Science 18/2015

01.09.2015 | Original Paper

Recognition of biomolecules using gold-polymer composites: metal nanoparticles play the role of the catalyst

verfasst von: Meenakshi Choudhary, Samarjeet Singh Siwal, Abu Taher, Kaushik Mallick

Erschienen in: Journal of Materials Science | Ausgabe 18/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A facile synthesis route has been described for the preparation of gold-polymer supramolecular architecture with interesting physical properties and potential applications. The supramolecular material was investigated by microscopic, optical and surface characterization techniques. The composite architecture shows good colorimetric and voltammetric sensor application for the detection of biomolecules, where the gold nanoparticles play the role of a catalyst for both the applications in two different mechanistic pathways.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat McQuade DT, Pullen AE, Swager TM (2000) Conjugated polymer-based chemical sensors. Chem Rev 100:2537–2574CrossRef McQuade DT, Pullen AE, Swager TM (2000) Conjugated polymer-based chemical sensors. Chem Rev 100:2537–2574CrossRef
2.
Zurück zum Zitat Li D, Haung J, Kaner RB (2009) Polyaniline nanofibers: a unique polymer nanostructure for versatile applications. Acc Chem Res 42:135–145CrossRef Li D, Haung J, Kaner RB (2009) Polyaniline nanofibers: a unique polymer nanostructure for versatile applications. Acc Chem Res 42:135–145CrossRef
3.
Zurück zum Zitat Janata J, Josowich M (2003) Conducting polymers in electronic chemical sensors. Nat Mater 2:19–24CrossRef Janata J, Josowich M (2003) Conducting polymers in electronic chemical sensors. Nat Mater 2:19–24CrossRef
4.
Zurück zum Zitat Gustafsson G, Cao Y, Treacy GM, Klavetter F, Colaneri N, Heeger AJ (1992) Flexible light-emitting diodes made from soluble conducting polymers. Nature 357:477–479CrossRef Gustafsson G, Cao Y, Treacy GM, Klavetter F, Colaneri N, Heeger AJ (1992) Flexible light-emitting diodes made from soluble conducting polymers. Nature 357:477–479CrossRef
5.
Zurück zum Zitat Sailor MJ, Ginsburg EJ, Gorman CB, Kumar A, Grubbs RH, Lewis NS (1990) Thin films of n-Si/poly-(CH3)3Si-cyclooctatetraene: conducting-polymer solar cells and layered structures. Science 249:1146–1149CrossRef Sailor MJ, Ginsburg EJ, Gorman CB, Kumar A, Grubbs RH, Lewis NS (1990) Thin films of n-Si/poly-(CH3)3Si-cyclooctatetraene: conducting-polymer solar cells and layered structures. Science 249:1146–1149CrossRef
6.
Zurück zum Zitat Mallick K, Witcomb M, Erasmus R, Strydom A (2009) Low-temperature magnetic property of polymer encapsulated gold nanoparticles. J Appl Phys 106:074303CrossRef Mallick K, Witcomb M, Erasmus R, Strydom A (2009) Low-temperature magnetic property of polymer encapsulated gold nanoparticles. J Appl Phys 106:074303CrossRef
7.
Zurück zum Zitat Mallick K, Witcomb M, Scurrell M, Strydom A (2009) Optical, microscopic and low temperature electrical property of one-dimensional gold–polyaniline composite networks. J Phys D 42:095409CrossRef Mallick K, Witcomb M, Scurrell M, Strydom A (2009) Optical, microscopic and low temperature electrical property of one-dimensional gold–polyaniline composite networks. J Phys D 42:095409CrossRef
8.
Zurück zum Zitat Mallick K, Witcomb M, Strydom A (2009) Charge transport property of one-dimensional gold–polyaniline composite networks. Phys Stat Solidi (a) 206:2245–2248CrossRef Mallick K, Witcomb M, Strydom A (2009) Charge transport property of one-dimensional gold–polyaniline composite networks. Phys Stat Solidi (a) 206:2245–2248CrossRef
9.
Zurück zum Zitat Choudhary A (2009) Polyaniline/silver nanocomposites: dielectric properties and ethanol vapour sensitivity. Sens Actuators B 138:318–325CrossRef Choudhary A (2009) Polyaniline/silver nanocomposites: dielectric properties and ethanol vapour sensitivity. Sens Actuators B 138:318–325CrossRef
10.
Zurück zum Zitat Islam R, Witcomb M, Scurrell M, van Otterlo W, van der Lingen E, Mallick K (2011) Metal-polymer hybrid material as a catalyst for the Heck coupling reaction under phosphine-free conditions. Synth Commun 41:3561–3572CrossRef Islam R, Witcomb M, Scurrell M, van Otterlo W, van der Lingen E, Mallick K (2011) Metal-polymer hybrid material as a catalyst for the Heck coupling reaction under phosphine-free conditions. Synth Commun 41:3561–3572CrossRef
11.
Zurück zum Zitat Islam R, Witcomb M, Scurrell M, van der Lingen E, van Otterlo W, Mallick K (2011) Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems. Catal Sci Tech 1:308–315CrossRef Islam R, Witcomb M, Scurrell M, van der Lingen E, van Otterlo W, Mallick K (2011) Conjugated polymer stabilized palladium nanoparticles as a versatile catalyst for Suzuki cross-coupling reactions for both aryl and heteroaryl bromide systems. Catal Sci Tech 1:308–315CrossRef
12.
Zurück zum Zitat Islam R, Witcomb M, van der Lingen E, Scurrell M, van Otterlo W, Mallick K (2011) In-situ synthesis of a palladium-polyaniline hybrid catalyst for a Suzuki coupling reaction. J Organomet Chem 696:2206–2210CrossRef Islam R, Witcomb M, van der Lingen E, Scurrell M, van Otterlo W, Mallick K (2011) In-situ synthesis of a palladium-polyaniline hybrid catalyst for a Suzuki coupling reaction. J Organomet Chem 696:2206–2210CrossRef
13.
Zurück zum Zitat Islam R, Witcomb M, Scurrell M, van Otterlo W, Mallick K (2010) In situ synthesis of a Pd–poly (1,8-diaminonaphthalene) nanocomposite: an efficient catalyst for Heck reactions under phosphine-free conditions. Catal Commun 12:116–121CrossRef Islam R, Witcomb M, Scurrell M, van Otterlo W, Mallick K (2010) In situ synthesis of a Pd–poly (1,8-diaminonaphthalene) nanocomposite: an efficient catalyst for Heck reactions under phosphine-free conditions. Catal Commun 12:116–121CrossRef
14.
Zurück zum Zitat Choudhary M, Islam R, Witcomb M, Phali M, Mallick K (2013) Template-less synthesis of polymer hollow spheres: an efficient catalyst for Suzuki coupling reaction. Appl Organomet Chem 27:523–528CrossRef Choudhary M, Islam R, Witcomb M, Phali M, Mallick K (2013) Template-less synthesis of polymer hollow spheres: an efficient catalyst for Suzuki coupling reaction. Appl Organomet Chem 27:523–528CrossRef
15.
Zurück zum Zitat Islam R, Mahato S, Sukla SK, Witcomb M, Mallick K (2013) Palladium–poly(3-aminoquinoline) hollow-sphere composite: application in Sonogashira coupling reactions. ChemCatChem 5:2453–2461CrossRef Islam R, Mahato S, Sukla SK, Witcomb M, Mallick K (2013) Palladium–poly(3-aminoquinoline) hollow-sphere composite: application in Sonogashira coupling reactions. ChemCatChem 5:2453–2461CrossRef
16.
Zurück zum Zitat Mahato S, Islam R, Acharya C, Witcomb M, Mallick K (2014) Polymer-stabilized Palladium nanoparticles for the chemoselective transfer hydrogenation of α, β-unsaturated carbonyls: single-step bottom-up approach. ChemCatChem 6:1419–1426 Mahato S, Islam R, Acharya C, Witcomb M, Mallick K (2014) Polymer-stabilized Palladium nanoparticles for the chemoselective transfer hydrogenation of α, β-unsaturated carbonyls: single-step bottom-up approach. ChemCatChem 6:1419–1426
17.
Zurück zum Zitat Stoyanova A, Ivanov S, Tsakova V, Bund A (2011) Au nanoparticle-polyaniline nanocomposite layers obtained through layer-by-layer adsorption for the simultaneous determination of dopamine and uric acid. Electrochim Acta 56:3693–3699CrossRef Stoyanova A, Ivanov S, Tsakova V, Bund A (2011) Au nanoparticle-polyaniline nanocomposite layers obtained through layer-by-layer adsorption for the simultaneous determination of dopamine and uric acid. Electrochim Acta 56:3693–3699CrossRef
18.
Zurück zum Zitat Huang J, Virji S, Weiller BH, Kaner RB (2003) Polyaniline nanofibers: facile synthesis and chemical sensors. J Am Chem Soc 125:314–315CrossRef Huang J, Virji S, Weiller BH, Kaner RB (2003) Polyaniline nanofibers: facile synthesis and chemical sensors. J Am Chem Soc 125:314–315CrossRef
19.
Zurück zum Zitat Sarma TS, Chowdhury D, Paul A, Chattopadhyay A (2002) Synthesis of Au nanoparticle-conductive polyaniline composite using H2O2 as oxidising as well as reducing agent. Chem Commun 10:1048–1049CrossRef Sarma TS, Chowdhury D, Paul A, Chattopadhyay A (2002) Synthesis of Au nanoparticle-conductive polyaniline composite using H2O2 as oxidising as well as reducing agent. Chem Commun 10:1048–1049CrossRef
20.
Zurück zum Zitat Zhang Z, Deng J, Wan M (2009) Highly crystalline and thin polyaniline nanofibers oxidized by ferric chloride. Mater Chem Phys 115:275–279CrossRef Zhang Z, Deng J, Wan M (2009) Highly crystalline and thin polyaniline nanofibers oxidized by ferric chloride. Mater Chem Phys 115:275–279CrossRef
21.
Zurück zum Zitat Mallick K, Witcomb M, Scurrell M, Strydom A (2010) Paramagnetic polyaniline nanospheres. Chem Phys Lett 494:232–236CrossRef Mallick K, Witcomb M, Scurrell M, Strydom A (2010) Paramagnetic polyaniline nanospheres. Chem Phys Lett 494:232–236CrossRef
22.
Zurück zum Zitat Choudhary M, Siwal S, Islam R, Witcomb M, Mallick K (2014) Polymer stabilized silver nanoparticle: an efficient catalyst for proton-coupled electron transfer reaction and the electrochemical recognition of biomolecule. Chem Phys Lett 608:145–151CrossRef Choudhary M, Siwal S, Islam R, Witcomb M, Mallick K (2014) Polymer stabilized silver nanoparticle: an efficient catalyst for proton-coupled electron transfer reaction and the electrochemical recognition of biomolecule. Chem Phys Lett 608:145–151CrossRef
23.
Zurück zum Zitat Mallick K, Witcomb M, Dinsmore A, Scurrell M (2005) Fabrication of a metal nanoparticles and polymer nanofibers composite material by an in situ chemical synthetic route. Langmuir 21:7964–7967CrossRef Mallick K, Witcomb M, Dinsmore A, Scurrell M (2005) Fabrication of a metal nanoparticles and polymer nanofibers composite material by an in situ chemical synthetic route. Langmuir 21:7964–7967CrossRef
24.
Zurück zum Zitat Wang J, Neoh KG, Kang ET (2001) Preparation of nanosized metallic particles in polyaniline. J Coll Interface Sci 239:78–86CrossRef Wang J, Neoh KG, Kang ET (2001) Preparation of nanosized metallic particles in polyaniline. J Coll Interface Sci 239:78–86CrossRef
25.
Zurück zum Zitat Kinyanjui J, Hatchett D, Smith J, Josowicz M (2004) Chemical synthesis of a polyaniline/gold composite using tetrachloroaurate. Chem Mater 16:3390–3398CrossRef Kinyanjui J, Hatchett D, Smith J, Josowicz M (2004) Chemical synthesis of a polyaniline/gold composite using tetrachloroaurate. Chem Mater 16:3390–3398CrossRef
26.
Zurück zum Zitat Mallick K, Witcomb M, Dinsmore A, Scurrell M (2005) Polymerization of aniline by auric acid: formation of gold decorated polyaniline nanoballs. Macromol Rapid Commun 26:232–235CrossRef Mallick K, Witcomb M, Dinsmore A, Scurrell M (2005) Polymerization of aniline by auric acid: formation of gold decorated polyaniline nanoballs. Macromol Rapid Commun 26:232–235CrossRef
27.
Zurück zum Zitat Wang Y, Liu Z, Han B, Sun Z, Huang Y, Yang G (2005) Facile synthesis of polyaniline nanofibers using chloroaurate acid as the oxidant. Langmuir 21:833–836CrossRef Wang Y, Liu Z, Han B, Sun Z, Huang Y, Yang G (2005) Facile synthesis of polyaniline nanofibers using chloroaurate acid as the oxidant. Langmuir 21:833–836CrossRef
28.
Zurück zum Zitat Hasik M, Wenda E, Paluszkiewicz C, Bernasik A, Camra J (2004) Poly(o-methoxyaniline)–palladium systems: effect of preparation conditions on physico-chemical properties. Synth Met 143:341–350CrossRef Hasik M, Wenda E, Paluszkiewicz C, Bernasik A, Camra J (2004) Poly(o-methoxyaniline)–palladium systems: effect of preparation conditions on physico-chemical properties. Synth Met 143:341–350CrossRef
29.
Zurück zum Zitat Dai X, Tan Y, Xu J (2002) Formation of gold nanoparticles in the presence of o-anisidine and the dependence of the structure of poly(o-anisidine) on synthetic conditions. Langmuir 18:9010–9016CrossRef Dai X, Tan Y, Xu J (2002) Formation of gold nanoparticles in the presence of o-anisidine and the dependence of the structure of poly(o-anisidine) on synthetic conditions. Langmuir 18:9010–9016CrossRef
30.
Zurück zum Zitat Mallick K, Witcomb M, Erasmus R, Scurrell M (2007) Hydrophilic behaviour of gold-poly (o-phenylenediamine) hybrid nanocomposite. Mater Sci Eng B 140:166–171CrossRef Mallick K, Witcomb M, Erasmus R, Scurrell M (2007) Hydrophilic behaviour of gold-poly (o-phenylenediamine) hybrid nanocomposite. Mater Sci Eng B 140:166–171CrossRef
31.
Zurück zum Zitat Miyama T, Yonezawa Y (2004) Aggregation of photolytic gold nanoparticles at the surface of chitosan films. Langmuir 20:5918–5923CrossRef Miyama T, Yonezawa Y (2004) Aggregation of photolytic gold nanoparticles at the surface of chitosan films. Langmuir 20:5918–5923CrossRef
32.
Zurück zum Zitat Cao Y, Smith P, Yang C (1995) Effect of solvent and co-solvents on the processibility of polyaniline: II. Spectroscopic, and diffraction studies. Synth Met 69:191–192CrossRef Cao Y, Smith P, Yang C (1995) Effect of solvent and co-solvents on the processibility of polyaniline: II. Spectroscopic, and diffraction studies. Synth Met 69:191–192CrossRef
33.
Zurück zum Zitat Shuai Z, Wang L, Song C (2012) Theory of charge transport in carbon electronic materials, Springer briefs in molecular science. Springer, Berlin, pp 7–41 Shuai Z, Wang L, Song C (2012) Theory of charge transport in carbon electronic materials, Springer briefs in molecular science. Springer, Berlin, pp 7–41
34.
Zurück zum Zitat Liu F, Khan K, Liang JH, Yan JW, Wu DY, Mao BW, Jensen PS, Zhang J, Ulstrup J (2013) On the hopping efficiency of nanoparticles in the electron transfer across self-assembled monolayers. ChemPhysChem 14:952–957CrossRef Liu F, Khan K, Liang JH, Yan JW, Wu DY, Mao BW, Jensen PS, Zhang J, Ulstrup J (2013) On the hopping efficiency of nanoparticles in the electron transfer across self-assembled monolayers. ChemPhysChem 14:952–957CrossRef
35.
Zurück zum Zitat Feng X, Mao C, Yang G, Hou W, Zhu JJ (2006) Polyaniline/Au composite hollow spheres: synthesis, characterization and application to the detection of Dopamine. Langmuir 22:4384–4389CrossRef Feng X, Mao C, Yang G, Hou W, Zhu JJ (2006) Polyaniline/Au composite hollow spheres: synthesis, characterization and application to the detection of Dopamine. Langmuir 22:4384–4389CrossRef
Metadaten
Titel
Recognition of biomolecules using gold-polymer composites: metal nanoparticles play the role of the catalyst
verfasst von
Meenakshi Choudhary
Samarjeet Singh Siwal
Abu Taher
Kaushik Mallick
Publikationsdatum
01.09.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 18/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9160-4

Weitere Artikel der Ausgabe 18/2015

Journal of Materials Science 18/2015 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.