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2020 | OriginalPaper | Buchkapitel

5. Reinforcing Mechanism of Rubber by Nanofiller

verfasst von: Shinzo Kohjiya, Atsushi Kato, Yuko Ikeda

Erschienen in: Reinforcement of Rubber

Verlag: Springer Singapore

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Abstract

CB is highlighted for the reinforcement of NR. Firstly, some historical considerations on the rubber reinforcement by nanofillers are given. Secondly, the most recent relevant studies on the aggregation of CB were critically reviewed, and the semiflexible CB network structure in the rubber matrix is proposed, which has unified the traditional ideas on bound rubber and structuring or clustering of CB. This CB network has maintained a little flexibility due to the presence of 3 nm rubber layer (intrinsic bound rubber) between the primary CB aggregates, which are rigid. Thirdly, our semiflexible CB network model is applied to explain a mechanical property of CB-loaded rubber vulcanizates, and the crucial utility of the CB structuring involving bound rubber is concluded. In other words, rubber reinforcement is due to a cooperation of the bound rubber absorbed on the nanofiller surface (wetting by rubber, due to rubber-to-filler interaction) and the 3D clustering ability of nanofillers (filler-to-filler interaction) even overcoming the wetting by rubber, suggesting a feature of nanoparticles in general. Nanofiller network formed by intermediation of bound rubber is certainly the most important result obtained by 3D-TEM studies on rubber reinforcement by nanofillers.
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Literatur
1.
Zurück zum Zitat C. Goodyear, Gum-Elastic and Its Varieties, with a Detailed Account of Its Application and Uses and of the Discovery of Vulcanization (Published for the author, New Haven, 1855) C. Goodyear, Gum-Elastic and Its Varieties, with a Detailed Account of Its Application and Uses and of the Discovery of Vulcanization (Published for the author, New Haven, 1855)
2.
Zurück zum Zitat B.N. Zimmerman (ed.), Vignettes from the International Rubber Science Hall of Fame (1958–1988): 36 Major Contributors to Rubber Science (Rubber Division of American Chemical Society, Akron, 1989) B.N. Zimmerman (ed.), Vignettes from the International Rubber Science Hall of Fame (1958–1988): 36 Major Contributors to Rubber Science (Rubber Division of American Chemical Society, Akron, 1989)
3.
Zurück zum Zitat S. Kohjiya, Natural Rubber: From the Odyssey of the Hevea Tree to the Transportation Society (Smithers RAPRA, Shrewsbury, 2015) S. Kohjiya, Natural Rubber: From the Odyssey of the Hevea Tree to the Transportation Society (Smithers RAPRA, Shrewsbury, 2015)
4.
Zurück zum Zitat Y. Ikeda, A. Kato, S. Kohjiya, Y. Nakajima, Rubber Science: A Modern Approach (Springer, Singapore, 2017) Y. Ikeda, A. Kato, S. Kohjiya, Y. Nakajima, Rubber Science: A Modern Approach (Springer, Singapore, 2017)
5.
Zurück zum Zitat C.O. Weber, The Chemistry of India Rubber, Including the Outline of a Theory on Vulcanization (Charles Griffin & Co., London, 1902) C.O. Weber, The Chemistry of India Rubber, Including the Outline of a Theory on Vulcanization (Charles Griffin & Co., London, 1902)
6.
Zurück zum Zitat C.C. Davis, J.T. Blake (eds.), The Chemistry and Technology of Rubber (Reinhold Publishing, New York, 1937) C.C. Davis, J.T. Blake (eds.), The Chemistry and Technology of Rubber (Reinhold Publishing, New York, 1937)
7.
Zurück zum Zitat C.C. Webster, W.J. Baulkwill (eds.), Rubber (Longman, Harlow, 1989) C.C. Webster, W.J. Baulkwill (eds.), Rubber (Longman, Harlow, 1989)
8.
Zurück zum Zitat N.A. Shepard, J.N. Street, C.R. Park, Fillers and reinforcing agents, in The Chemistry and Technology of Rubber, Chap. 11, ed. by C.C. Davis, J.T. Blake (Reinhold Publishing, New York, 1937), pp. 380–413 N.A. Shepard, J.N. Street, C.R. Park, Fillers and reinforcing agents, in The Chemistry and Technology of Rubber, Chap. 11, ed. by C.C. Davis, J.T. Blake (Reinhold Publishing, New York, 1937), pp. 380–413
9.
Zurück zum Zitat G. Kraus (ed.), Reinforcement of Elastomers (Interscience, New York, 1965) G. Kraus (ed.), Reinforcement of Elastomers (Interscience, New York, 1965)
10.
Zurück zum Zitat A. R. Payne, Dynamic properties of filler-loaded rubbers, in Reinforcement of Elastomers, Chap. 3 (Interscience, New York, 1965) A. R. Payne, Dynamic properties of filler-loaded rubbers, in Reinforcement of Elastomers, Chap. 3 (Interscience, New York, 1965)
11.
Zurück zum Zitat D. Stauffer, Introduction to Percolation Theory (Taylor & Francis, London, 1985) CrossRef D. Stauffer, Introduction to Percolation Theory (Taylor & Francis, London, 1985) CrossRef
12.
Zurück zum Zitat R.H. Norman, Conductive Rubbers and Plastics (Applied Science Publisher, London, 1970) R.H. Norman, Conductive Rubbers and Plastics (Applied Science Publisher, London, 1970)
13.
Zurück zum Zitat V.E. Gul, Structure and Properties of Conducting Polymer Composites (VSP, Utrecht, 1996) V.E. Gul, Structure and Properties of Conducting Polymer Composites (VSP, Utrecht, 1996)
14.
Zurück zum Zitat T. Blythe, D. Bloor, Electrical Properties of Polymers (Cambridge University Press, Cambridge, 2005) T. Blythe, D. Bloor, Electrical Properties of Polymers (Cambridge University Press, Cambridge, 2005)
17.
Zurück zum Zitat F. Bueche, Physical Properties of Polymers (Interscience, New York, 1962) F. Bueche, Physical Properties of Polymers (Interscience, New York, 1962)
18.
Zurück zum Zitat F. Bueche, Network theories of reinforcement, in Reinforcement of Elastomers, Chap. 1, ed. by G. Kraus (Interscience, New York, 1965) F. Bueche, Network theories of reinforcement, in Reinforcement of Elastomers, Chap. 1, ed. by G. Kraus (Interscience, New York, 1965)
20.
Zurück zum Zitat G. Kraus, Interactions between elastomers and reinforcing fillers, in Reinforcement of Elastomers, Chap. 4, ed. by G. Kraus (Interscience, New York, 1965) G. Kraus, Interactions between elastomers and reinforcing fillers, in Reinforcement of Elastomers, Chap. 4, ed. by G. Kraus (Interscience, New York, 1965)
21.
Zurück zum Zitat W.F. Watson, Chemical interaction of fillers and rubbers during cold milling, in Reinforcement of Elastomers, Chap. 8, ed. by G. Kraus (Interscience, New York, 1965) W.F. Watson, Chemical interaction of fillers and rubbers during cold milling, in Reinforcement of Elastomers, Chap. 8, ed. by G. Kraus (Interscience, New York, 1965)
22.
Zurück zum Zitat M.L. Studebaker, Compounding with carbon black, in Reinforcement of Elastomers, Chap. 12, ed. by G. Kraus (Interscience, New York, 1965) M.L. Studebaker, Compounding with carbon black, in Reinforcement of Elastomers, Chap. 12, ed. by G. Kraus (Interscience, New York, 1965)
23.
Zurück zum Zitat S. Kaufman, W.P. Slichter, D.D. Davis, J. Polym. Sci. Part A-2 Polym. Phys. 9, 829 (1971) S. Kaufman, W.P. Slichter, D.D. Davis, J. Polym. Sci. Part A-2 Polym. Phys. 9, 829 (1971)
24.
25.
Zurück zum Zitat K. Nakajima, T. Nishi, Recent developments in rubber research using atomic force microscopy, in Current Topics in Elastomers Research, Chap. 21, ed. by A.K. Bhowmick (CRC Press, Boca Raton, 2008) K. Nakajima, T. Nishi, Recent developments in rubber research using atomic force microscopy, in Current Topics in Elastomers Research, Chap. 21, ed. by A.K. Bhowmick (CRC Press, Boca Raton, 2008)
26.
27.
28.
Zurück zum Zitat Y. Ishikawa, Y. Yamaguchi, N. Amino, A. Awagon, Nippon Gomu Kyokaishi 69, 716 (1996) (in Japanese) CrossRef Y. Ishikawa, Y. Yamaguchi, N. Amino, A. Awagon, Nippon Gomu Kyokaishi 69, 716 (1996) (in Japanese) CrossRef
29.
31.
Zurück zum Zitat P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell University Press, Cornell, 1979) P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell University Press, Cornell, 1979)
32.
Zurück zum Zitat B.B. Manelbrot, Fractals: Form, Chance and Dimension (W. H. Freeman, San Francisco, 1977) B.B. Manelbrot, Fractals: Form, Chance and Dimension (W. H. Freeman, San Francisco, 1977)
33.
Zurück zum Zitat D.J. Kohls, G. Beaucage, Curr. Opin. Solid State Mater. Sci. 6, 183 (2002) CrossRef D.J. Kohls, G. Beaucage, Curr. Opin. Solid State Mater. Sci. 6, 183 (2002) CrossRef
34.
Zurück zum Zitat M. Gerspacher, L. Nikiel, H.H. Yang, C.P. O’Farrell, K.G.K. Kaut, Gummi Kunst. 55, 596 (2002) M. Gerspacher, L. Nikiel, H.H. Yang, C.P. O’Farrell, K.G.K. Kaut, Gummi Kunst. 55, 596 (2002)
35.
Zurück zum Zitat Y. Ikeda, A. Kato, S. Kohjiya, Macromol. Rapid Commun. 25, 1186 (2004) CrossRef Y. Ikeda, A. Kato, S. Kohjiya, Macromol. Rapid Commun. 25, 1186 (2004) CrossRef
36.
37.
Zurück zum Zitat S. Kohjiya, A. Kato, J. Shimanuki, T. Hasegawa, Y. Ikeda, J. Mater. Sci. Lett. 40, 2553 (2005) S. Kohjiya, A. Kato, J. Shimanuki, T. Hasegawa, Y. Ikeda, J. Mater. Sci. Lett. 40, 2553 (2005)
38.
Zurück zum Zitat S. Kohjiya, A. Kato, J. Shimanuki, T. Hasegawa, Y. Ikeda, Polymer 46, 4440 (2005) CrossRef S. Kohjiya, A. Kato, J. Shimanuki, T. Hasegawa, Y. Ikeda, Polymer 46, 4440 (2005) CrossRef
39.
Zurück zum Zitat A. Kato, Y. Ikeda, S. Kohjiya, Nippon Gomu Kyokaishi 78, 180 (2005) (in Japanese) CrossRef A. Kato, Y. Ikeda, S. Kohjiya, Nippon Gomu Kyokaishi 78, 180 (2005) (in Japanese) CrossRef
40.
Zurück zum Zitat S. Kohjiya, A. Kato, Kobunshi Ronbunshu 62, 467 (2005) (in Japanese) CrossRef S. Kohjiya, A. Kato, Kobunshi Ronbunshu 62, 467 (2005) (in Japanese) CrossRef
41.
Zurück zum Zitat S. Kohjiya, A. Kato, T. Suda, J. Shimanuki, Y. Ikeda, Polymer 47, 3298 (2006) CrossRef S. Kohjiya, A. Kato, T. Suda, J. Shimanuki, Y. Ikeda, Polymer 47, 3298 (2006) CrossRef
42.
Zurück zum Zitat A. Kato, J. Shimanuki, S. Kohjiya, Y. Ikeda, Rubber Chem. Technol. 79, 653 (2006) CrossRef A. Kato, J. Shimanuki, S. Kohjiya, Y. Ikeda, Rubber Chem. Technol. 79, 653 (2006) CrossRef
43.
Zurück zum Zitat A. Kato, S. Kohjiya, Y. Ikeda, Kobunshi 55, 616 (2006) (in Japanese) CrossRef A. Kato, S. Kohjiya, Y. Ikeda, Kobunshi 55, 616 (2006) (in Japanese) CrossRef
44.
Zurück zum Zitat Y. Ikeda, A. Kato, J. Shimanuki, S. Kohjiya, M. Tosaka, S. Poompradub, S. Toki, B.S. Hsiao, Rubber Chem. Technol. 80, 251 (2007) CrossRef Y. Ikeda, A. Kato, J. Shimanuki, S. Kohjiya, M. Tosaka, S. Poompradub, S. Toki, B.S. Hsiao, Rubber Chem. Technol. 80, 251 (2007) CrossRef
45.
46.
Zurück zum Zitat A. Kato, Y. Ikeda, Y. Kasahara, J. Shimanuki, T. Suda, T. Hasegawa, H. Sawabe, S. Kohjiya, J. Opt. Soc. Am. B 25, 1602 (2008) CrossRef A. Kato, Y. Ikeda, Y. Kasahara, J. Shimanuki, T. Suda, T. Hasegawa, H. Sawabe, S. Kohjiya, J. Opt. Soc. Am. B 25, 1602 (2008) CrossRef
47.
Zurück zum Zitat S. Kohjiya, Y. Ikeda, A. Kato, Visualization of nano-filler dispersion and morphology in rubbery matrix by 3D-TEM, in Current Topics in Elastomers Research, Chap. 19, ed. by A.K. Bhowmick (CRC Press, Boca Raton, 2008) S. Kohjiya, Y. Ikeda, A. Kato, Visualization of nano-filler dispersion and morphology in rubbery matrix by 3D-TEM, in Current Topics in Elastomers Research, Chap. 19, ed. by A.K. Bhowmick (CRC Press, Boca Raton, 2008)
48.
Zurück zum Zitat A. Kato, Y. Ikeda, S. Kohjiya, Carbon black-filled natural rubber composites: physical chemistry and reinforcing mechanism, in Polymer Composites volume 1: Macro- and Microcomposites, Chap. 17, ed. by S. Thomas, K. Joseph, S.K. Malhotra, K. Goda, M.S. Streekala (Wiley-VCH, Weinheim, 2012) A. Kato, Y. Ikeda, S. Kohjiya, Carbon black-filled natural rubber composites: physical chemistry and reinforcing mechanism, in Polymer Composites volume 1: Macro- and Microcomposites, Chap. 17, ed. by S. Thomas, K. Joseph, S.K. Malhotra, K. Goda, M.S. Streekala (Wiley-VCH, Weinheim, 2012)
49.
Zurück zum Zitat A. Kato, Y. Ikeda, R. Tsushi, Y. Kokubo, N. Kojima, Colloid Polym. Sci. 291, 2101 (2013) CrossRef A. Kato, Y. Ikeda, R. Tsushi, Y. Kokubo, N. Kojima, Colloid Polym. Sci. 291, 2101 (2013) CrossRef
50.
Zurück zum Zitat A. Kato, Y. Ikeda, R. Tsushi, Y. Kokubo, J. Appl. Polym. Sci. 130, 2594 (2013) CrossRef A. Kato, Y. Ikeda, R. Tsushi, Y. Kokubo, J. Appl. Polym. Sci. 130, 2594 (2013) CrossRef
51.
Zurück zum Zitat A. Kato, Y. Kokubo, R. Tsushi, Y. Ikeda, Hydrophilic and hydrophobic silica-filled cross-linked natural rubber: structure and properties, in Chemistry, Manufacture and Applications of Natural Rubber, Chap. 7, ed. by S. Kohjiya, Y. Ikeda (Woodhead/Elsevier, Cambridge, 2014) A. Kato, Y. Kokubo, R. Tsushi, Y. Ikeda, Hydrophilic and hydrophobic silica-filled cross-linked natural rubber: structure and properties, in Chemistry, Manufacture and Applications of Natural Rubber, Chap. 7, ed. by S. Kohjiya, Y. Ikeda (Woodhead/Elsevier, Cambridge, 2014)
52.
Zurück zum Zitat A. Kato, Y. Isono, K. Nagata, A. Asano, Y. Ikeda, Study on polymeric nano-composites by 3D-TEM and related techniques, in Characterization Tools for Nanoscience & Nanotechnology, Chap. 4, ed. by C.S.S.R. Kumar (Springer, Berlin, 2014) A. Kato, Y. Isono, K. Nagata, A. Asano, Y. Ikeda, Study on polymeric nano-composites by 3D-TEM and related techniques, in Characterization Tools for Nanoscience & Nanotechnology, Chap. 4, ed. by C.S.S.R. Kumar (Springer, Berlin, 2014)
53.
Zurück zum Zitat A. Kato, Y. Ikeda, Nippon Gomu Kyokaishi 87, 351 (2014) (in Japanese) CrossRef A. Kato, Y. Ikeda, Nippon Gomu Kyokaishi 87, 351 (2014) (in Japanese) CrossRef
54.
Zurück zum Zitat A. Kato, Kobunshi 63, 632 (2014) (in Japanese) A. Kato, Kobunshi 63, 632 (2014) (in Japanese)
55.
Zurück zum Zitat A. Kato, Y. Ikeda, S. Kohjiya, Nippon Gomu Kyokaisi 88, 3 (2015) (in Japanese) CrossRef A. Kato, Y. Ikeda, S. Kohjiya, Nippon Gomu Kyokaisi 88, 3 (2015) (in Japanese) CrossRef
56.
Zurück zum Zitat A. Kato, A. Tohsan, S. Kohjiya, T. Phakkeeree, P. Phinyocheep, Y. Ikeda, Manufacturing and structure of rubber nanocomposites, in Progress in Rubber Nanocomposites, Chap. 12, ed. by S. Thomas, H.J. Maria (Woodhead/Elsevier, Amsterdam, 2016) A. Kato, A. Tohsan, S. Kohjiya, T. Phakkeeree, P. Phinyocheep, Y. Ikeda, Manufacturing and structure of rubber nanocomposites, in Progress in Rubber Nanocomposites, Chap. 12, ed. by S. Thomas, H.J. Maria (Woodhead/Elsevier, Amsterdam, 2016)
57.
Zurück zum Zitat A. Kato, Y. Ikeda, S. Kohjiya, Polym.-Plastics Technol. Eng. 57, 1418 (2017) A. Kato, Y. Ikeda, S. Kohjiya, Polym.-Plastics Technol. Eng. 57, 1418 (2017)
58.
Zurück zum Zitat J. Basti, F. Boue, M. Buzier, A. Baumgaertner, in Molecular Basis of Polymer Networks, ed. by C.E. Picot (Springer, Berlin, 1989) pp. 48–64 J. Basti, F. Boue, M. Buzier, A. Baumgaertner, in Molecular Basis of Polymer Networks, ed. by C.E. Picot (Springer, Berlin, 1989) pp. 48–64
59.
Zurück zum Zitat S. Kohjiya, Kgaku Kogyo 38, 579 (1987) (in Japanese) S. Kohjiya, Kgaku Kogyo 38, 579 (1987) (in Japanese)
60.
Zurück zum Zitat M. Tosaka, S. Murakami, S. Poompradub, S. Kohjiya, Y. Ikeda, S. Toki, I. Sics, B.S. Hsiao, Macromolecules 37, 3299 (2004) CrossRef M. Tosaka, S. Murakami, S. Poompradub, S. Kohjiya, Y. Ikeda, S. Toki, I. Sics, B.S. Hsiao, Macromolecules 37, 3299 (2004) CrossRef
61.
Zurück zum Zitat Y. Ikeda, S. Kohjiya, Nihon Reoroji Gakkaishi 36, 9 (2008) (in Japanese) CrossRef Y. Ikeda, S. Kohjiya, Nihon Reoroji Gakkaishi 36, 9 (2008) (in Japanese) CrossRef
63.
Zurück zum Zitat V.M. Litvinov, R.A. Orza, M. Klüppel, M. van Duin, P.C.M. Magusin, Macromolecules 44, 4887 (2011) CrossRef V.M. Litvinov, R.A. Orza, M. Klüppel, M. van Duin, P.C.M. Magusin, Macromolecules 44, 4887 (2011) CrossRef
64.
Zurück zum Zitat Y. Amamiya, Y. Shinohara, J. Jpn. Soc. Synchro. Rad. Res. 19, 338 (2006) (in Japanese) Y. Amamiya, Y. Shinohara, J. Jpn. Soc. Synchro. Rad. Res. 19, 338 (2006) (in Japanese)
65.
Zurück zum Zitat A. Guinier, in X-Ray Diffraction on Crystals, Imperfect Crystals, and Amorphous Bodies (The original French edition was published in 1956, and the translated ed. by P. Lorrain, D. Lorrain in 1963) (Dover, New York, 1994) A. Guinier, in X-Ray Diffraction on Crystals, Imperfect Crystals, and Amorphous Bodies (The original French edition was published in 1956, and the translated ed. by P. Lorrain, D. Lorrain in 1963) (Dover, New York, 1994)
67.
Zurück zum Zitat T. Koga, T. Hashimoto, M. Takenaka, K. Aizawa, N. Amino, M. Nakamura, D. Yamaguchi, S. Koizumi, Macromolecules 41, 453 (2008) CrossRef T. Koga, T. Hashimoto, M. Takenaka, K. Aizawa, N. Amino, M. Nakamura, D. Yamaguchi, S. Koizumi, Macromolecules 41, 453 (2008) CrossRef
68.
69.
Zurück zum Zitat Y. Ikeda, N. Higashitani, K. Hijikata, Y. Kokubo, Y. Morita, M. Shibayama, N. Osaka, T. Suzuki, H. Endo, S. Kohjiya, Macromolecules 42, 2741 (2009) CrossRef Y. Ikeda, N. Higashitani, K. Hijikata, Y. Kokubo, Y. Morita, M. Shibayama, N. Osaka, T. Suzuki, H. Endo, S. Kohjiya, Macromolecules 42, 2741 (2009) CrossRef
70.
Zurück zum Zitat K. Hagita, T. Arai, H. Kishimoto, N. Umesaki, Y. Shinohara, Y. Amemiya, J. Phys. Condens. Matter 19, 330017 (2007) CrossRef K. Hagita, T. Arai, H. Kishimoto, N. Umesaki, Y. Shinohara, Y. Amemiya, J. Phys. Condens. Matter 19, 330017 (2007) CrossRef
71.
Zurück zum Zitat K. Hagita, T. Arai, H. Kishimoto, N. Usuki, H. Sano, Y. Shinohara, Y. Amemiya, Rheol. Acta 47, 537 (2008) CrossRef K. Hagita, T. Arai, H. Kishimoto, N. Usuki, H. Sano, Y. Shinohara, Y. Amemiya, Rheol. Acta 47, 537 (2008) CrossRef
72.
Zurück zum Zitat L. Chen, Z. Zhou, J. Jing, W. Zhang, N. Huang, L. Wu, L. Li, Macromolecules 48, 7923 (2015) CrossRef L. Chen, Z. Zhou, J. Jing, W. Zhang, N. Huang, L. Wu, L. Li, Macromolecules 48, 7923 (2015) CrossRef
73.
Zurück zum Zitat T. Hashimoto, Principle and Applications of X-Ray, Light, and Neutron Scatterings (Kodansha, Tokyo, 2017) (in Japanese) T. Hashimoto, Principle and Applications of X-Ray, Light, and Neutron Scatterings (Kodansha, Tokyo, 2017) (in Japanese)
75.
76.
Zurück zum Zitat A.Y. Coran, K. Boustany, P. Hamed, Rubber Chem. Technol. 47, 396 (1974) CrossRef A.Y. Coran, K. Boustany, P. Hamed, Rubber Chem. Technol. 47, 396 (1974) CrossRef
Metadaten
Titel
Reinforcing Mechanism of Rubber by Nanofiller
verfasst von
Shinzo Kohjiya
Atsushi Kato
Yuko Ikeda
Copyright-Jahr
2020
Verlag
Springer Singapore
DOI
https://doi.org/10.1007/978-981-15-3789-9_5

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