Skip to main content

2015 | OriginalPaper | Buchkapitel

Removal of Cu (II) from Aqueous Solutions Using Colloidal Pyrite Calcined Under Inert Atmosphere

verfasst von : Yan Yang, Tianhu Chen, Ping Li, Haibo Liu, Yadan Shi, Xinmin Zhan

Erschienen in: Proceedings of the 11th International Congress for Applied Mineralogy (ICAM)

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A natural colloidal pyrite calcined in N2 atmosphere was utilized to remove Cu (II) from aqueous solutions in the present work. Under the effect of calcination temperature, initial solution pH, reaction time, initial Cu(II) concentration, sorption temperature, foreign ions, and the dissolved oxygen (DO) on Cu(II) removal were investigated. The results showed that colloidal pyrite calcined at 500–550 °C (CCPy) has a most promising potential for Cu(II) removal. The increase of pH, initial Cu(II) concentration, and reaction time benefited the improvement of Cu(II) removal efficiency. The isothermal adsorption data of CCPy were well described by Langmuir isotherms and the thermodynamic parameters (ΔG < 0, ΔH > 0), indicating the endothermic nature of Cu(II) sorption on CCPy. The presence of most common ions in acid mine drainage and DO just had little influence on the Cu(II) uptake. The observation implied that CCPy is a low-cost, abundant material for Cu removal from Cu waters.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Wei X, Viadero RC, Bhojappa JS (2008) Phosphorus removal by acid mine drainage sludge from secondary effluents of municipal wastewater treatment plants. Water Res 42:3275–3284CrossRef Wei X, Viadero RC, Bhojappa JS (2008) Phosphorus removal by acid mine drainage sludge from secondary effluents of municipal wastewater treatment plants. Water Res 42:3275–3284CrossRef
2.
Zurück zum Zitat Cheng SA, Dempsey BA, Logan BE (2007) Electricity generation from synthetic acid-mine drainage (AMD) water using fuel cell technologies. Environ Sci Technol 41:8149–8153CrossRef Cheng SA, Dempsey BA, Logan BE (2007) Electricity generation from synthetic acid-mine drainage (AMD) water using fuel cell technologies. Environ Sci Technol 41:8149–8153CrossRef
3.
Zurück zum Zitat Buzzia DC, Viegasb LS, Rodriguesc MAS, Bernardesb AM, Tenórioa JAS (2013) Water recovery from acid mine drainage by electrodialysis. Miner Eng 40:82–89CrossRef Buzzia DC, Viegasb LS, Rodriguesc MAS, Bernardesb AM, Tenórioa JAS (2013) Water recovery from acid mine drainage by electrodialysis. Miner Eng 40:82–89CrossRef
4.
Zurück zum Zitat Lin YT, Huang CP (2008) Reduction of chromium (VI) by pyrite in dilute aqueous solutions. Sep Purif Technol 63:191–199CrossRef Lin YT, Huang CP (2008) Reduction of chromium (VI) by pyrite in dilute aqueous solutions. Sep Purif Technol 63:191–199CrossRef
5.
Zurück zum Zitat Descostes M, Schlegel ML, Eglizaud N, Descamps F, Miserque F, Simoni E (2010) Uptake of uranium and trace elements in pyrite (FeS2) suspensions. Geochim Cosmochim Acta 74:1551–1562CrossRef Descostes M, Schlegel ML, Eglizaud N, Descamps F, Miserque F, Simoni E (2010) Uptake of uranium and trace elements in pyrite (FeS2) suspensions. Geochim Cosmochim Acta 74:1551–1562CrossRef
6.
Zurück zum Zitat Han DS, Batchelor B, Abdel-Wahab A (2012) Sorption of selenium (IV) and selenium (VI) onto synthetic pyrite (FeS2): spectroscopic and microscopic analyses. J Colloid Interface Sci 368:496–504CrossRef Han DS, Batchelor B, Abdel-Wahab A (2012) Sorption of selenium (IV) and selenium (VI) onto synthetic pyrite (FeS2): spectroscopic and microscopic analyses. J Colloid Interface Sci 368:496–504CrossRef
7.
Zurück zum Zitat Jeong HY, Han YS, Park SW, Hayes KF (2010) Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization. Geochim Cosmochim Acta 74:3182–3198CrossRef Jeong HY, Han YS, Park SW, Hayes KF (2010) Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization. Geochim Cosmochim Acta 74:3182–3198CrossRef
8.
Zurück zum Zitat Lu AH, Zhong SJ, Chen J, Shi JX, Tang JL, Lu XY (2006) Removal of Cr (VI) and Cr (III) from aqueous solutions and industrial wastewaters by natural clino-pyrrhotite. Environ Sci Technol 40:3064–3069CrossRef Lu AH, Zhong SJ, Chen J, Shi JX, Tang JL, Lu XY (2006) Removal of Cr (VI) and Cr (III) from aqueous solutions and industrial wastewaters by natural clino-pyrrhotite. Environ Sci Technol 40:3064–3069CrossRef
9.
Zurück zum Zitat Ozverdi A, Erdem M (2006) Cu2+, Cd2+ and Pb2+ adsorption from aqueous solutions by pyrite and synthetic iron sulphide. J Hazard Mater 137:626–632CrossRef Ozverdi A, Erdem M (2006) Cu2+, Cd2+ and Pb2+ adsorption from aqueous solutions by pyrite and synthetic iron sulphide. J Hazard Mater 137:626–632CrossRef
10.
Zurück zum Zitat Jeong HY, Sun K, Hayes KF (2010) Microscopic and spectroscopic characterization of Hg (II) immobilization by Mackinawite (FeS). Environ Sci Technol 44:7476–7483CrossRef Jeong HY, Sun K, Hayes KF (2010) Microscopic and spectroscopic characterization of Hg (II) immobilization by Mackinawite (FeS). Environ Sci Technol 44:7476–7483CrossRef
11.
Zurück zum Zitat Erdem M, Ozverdi A (2006) Kinetics and thermodynamics of Cd (II) adsorption onto pyrite and synthetic iron sulphide. Sep Purif Technol 51:240–246CrossRef Erdem M, Ozverdi A (2006) Kinetics and thermodynamics of Cd (II) adsorption onto pyrite and synthetic iron sulphide. Sep Purif Technol 51:240–246CrossRef
12.
Zurück zum Zitat Coles CA, Rao R, Yong RN (2000) Lead and cadmium interactions with Mackinawite: retention mechanisms and the role of pH. Environ Sci Technol 34:996–1000CrossRef Coles CA, Rao R, Yong RN (2000) Lead and cadmium interactions with Mackinawite: retention mechanisms and the role of pH. Environ Sci Technol 34:996–1000CrossRef
13.
Zurück zum Zitat Chandra AP, Puskar L, Simpson DJ, Gerson AR (2012) Copper and xanthate adsorption onto pyrite surfaces: implications for mineral separation through flotation. Int J Miner Process 114–117:16–26CrossRef Chandra AP, Puskar L, Simpson DJ, Gerson AR (2012) Copper and xanthate adsorption onto pyrite surfaces: implications for mineral separation through flotation. Int J Miner Process 114–117:16–26CrossRef
14.
Zurück zum Zitat Awual MR, Yaita T, El-Safty SA, Shiwaku H, Suzuki S, Okamoto Y (2013) Copper (II) ions capturing from water using ligand modified a new type mesoporous adsorbent. Chem Eng J 221:322–330CrossRef Awual MR, Yaita T, El-Safty SA, Shiwaku H, Suzuki S, Okamoto Y (2013) Copper (II) ions capturing from water using ligand modified a new type mesoporous adsorbent. Chem Eng J 221:322–330CrossRef
15.
Zurück zum Zitat Larous S, Meniai AH, Lehocine MB (2005) Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination 185:483–490CrossRef Larous S, Meniai AH, Lehocine MB (2005) Experimental study of the removal of copper from aqueous solutions by adsorption using sawdust. Desalination 185:483–490CrossRef
16.
Zurück zum Zitat Integrated wastewater discharge Standard (1996) GB 8978-1996, China. Integrated wastewater discharge Standard (1996) GB 8978-1996, China.
17.
Zurück zum Zitat Chen TH, Yang Y, Chen D, Li P, Shi YD, Zhu X (2012) The structural evolution of heat-treated colloidal pyrite under inert atmosphere and its application for the purification of Cu (II) ion from wastewater. Environ Eng Manag 12(7):1411–1416. Chen TH, Yang Y, Chen D, Li P, Shi YD, Zhu X (2012) The structural evolution of heat-treated colloidal pyrite under inert atmosphere and its application for the purification of Cu (II) ion from wastewater. Environ Eng Manag 12(7):1411–1416.
18.
Zurück zum Zitat Arnold RG (1967) Range in composition and structure of 82 natural terrestrial pyrrhotites. Can Mineral 9:31–50 Arnold RG (1967) Range in composition and structure of 82 natural terrestrial pyrrhotites. Can Mineral 9:31–50
19.
Zurück zum Zitat Janzen MP, Nicholson RV, Scharer JM (2000) Pyrrhotite reaction kinetics: reaction rates for oxidation by oxygen, ferric iron, and for nonoxidative dissolution. Geochim Cosmochim Acta 64:1511–1522CrossRef Janzen MP, Nicholson RV, Scharer JM (2000) Pyrrhotite reaction kinetics: reaction rates for oxidation by oxygen, ferric iron, and for nonoxidative dissolution. Geochim Cosmochim Acta 64:1511–1522CrossRef
20.
Zurück zum Zitat Nicholson RV, Scharer JM (1994) Laboratory studies of pyrrhotite oxidation kinetics. Environ Geochem Sulfide Oxid 550:14–30CrossRef Nicholson RV, Scharer JM (1994) Laboratory studies of pyrrhotite oxidation kinetics. Environ Geochem Sulfide Oxid 550:14–30CrossRef
21.
Zurück zum Zitat Thomas JE, Skinner WM, Smart RSC (2003) A comparison of the dissolution behavior of troilite with other iron (II) sulfides; implications of structure. Geochim Cosmochim Acta 67:831–843CrossRef Thomas JE, Skinner WM, Smart RSC (2003) A comparison of the dissolution behavior of troilite with other iron (II) sulfides; implications of structure. Geochim Cosmochim Acta 67:831–843CrossRef
22.
Zurück zum Zitat Jackson E (1986) Hydrometallurgical extraction and reclamation. Wiley, New York Jackson E (1986) Hydrometallurgical extraction and reclamation. Wiley, New York
23.
Zurück zum Zitat Ma W, Tobin JM (2004) Determination and modelling of effects of pH on peat biosorption of chromium, copper and cadmium. Biochem Eng J 18:33–40CrossRef Ma W, Tobin JM (2004) Determination and modelling of effects of pH on peat biosorption of chromium, copper and cadmium. Biochem Eng J 18:33–40CrossRef
24.
Zurück zum Zitat Fornasiero D, Eijt V, Ralston J (1992) An electrokinetic study of pyrite oxidation. J Colloid Interface Sci 62:63–73 Fornasiero D, Eijt V, Ralston J (1992) An electrokinetic study of pyrite oxidation. J Colloid Interface Sci 62:63–73
25.
Zurück zum Zitat Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295CrossRef Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295CrossRef
26.
Zurück zum Zitat Freundlich HMF (1906) Uber die adsorption in lasungen. J Phys Chem 57:385–470 Freundlich HMF (1906) Uber die adsorption in lasungen. J Phys Chem 57:385–470
27.
Zurück zum Zitat Li N, Zhang LD, Chen YZ, Tian Y, Wang HM (2011) Adsorption behavior of Cu(II) onto titanate nanofibers prepared by alkali treatment. J Hazard Mater 189:265–272CrossRef Li N, Zhang LD, Chen YZ, Tian Y, Wang HM (2011) Adsorption behavior of Cu(II) onto titanate nanofibers prepared by alkali treatment. J Hazard Mater 189:265–272CrossRef
28.
Zurück zum Zitat Martinez CE, Mcbride MB (1998) Solubility of Cd2+, Cu2+, Pb2+, and Zn2+ in aged coprecipitates with amorphous iron hydroxides. Environ Sci Technol 32:743–748CrossRef Martinez CE, Mcbride MB (1998) Solubility of Cd2+, Cu2+, Pb2+, and Zn2+ in aged coprecipitates with amorphous iron hydroxides. Environ Sci Technol 32:743–748CrossRef
Metadaten
Titel
Removal of Cu (II) from Aqueous Solutions Using Colloidal Pyrite Calcined Under Inert Atmosphere
verfasst von
Yan Yang
Tianhu Chen
Ping Li
Haibo Liu
Yadan Shi
Xinmin Zhan
Copyright-Jahr
2015
DOI
https://doi.org/10.1007/978-3-319-13948-7_44