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19.02.2018 | Original Paper

Removal of heavy metal and sulfate ions by cellulose derivative-based biosorbents

verfasst von: Xin Gao, Heng Zhang, Keli Chen, Jiali Zhou, Qixing Liu

Erschienen in: Cellulose | Ausgabe 4/2018

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Abstract

A series of environmentally-friendly bagasse pith cellulose-based adsorbents were prepared in an attempt to retain Cu²⁺ and SO₄²⁻ from aqueous solutions. The proof of ion adsorption on the biosorbents was identified from Fourier transform infrared spectroscopy and energy-dispersive X-ray spectroscopy-scanning electron microscope. The adsorption capacities were highly dependent on pH and the maximum uptakes of both ions were obtained at pH 5. An increase of solution temperature resulted in decreasing Cu²⁺ removal but enhancing SO₄²⁻ adsorption. The kinetic studies showed that the adsorptions of copper and sulfate ions followed the pseudo-second-order kinetics. The analysis of isotherm data indicated that the Langmuir and Freundlich models were in good agreement with the sorptions of Cu²⁺ and SO₄²⁻, respectively. The proportion of carboxylate cellulose and quaternary ammonium-functionalized cellulose in biosorbents influenced on adsorption capacity of the above ions. The adsorption mechanism was mainly governed by ion exchange, complexation and electrostatic association.

Vorheriger Artikel Diffusion and phase separation at the morphology formation of cellulose membranes by regeneration from N-methylmorpholine N-oxide solutions

Nächster Artikel Nanoporous cellulose membrane doped with silver for continuous catalytic decolorization of organic dyes

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Titel: Removal of heavy metal and sulfate ions by cellulose derivative-based biosorbents
verfasst von: Xin Gao
Heng Zhang
Keli Chen
Jiali Zhou
Qixing Liu
Publikationsdatum: 19.02.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1690-x

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