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12.01.2016

Removal of ronidazole and sulfamethoxazole from water solutions by adsorption on granular activated carbon: equilibrium and intraparticle diffusion mechanisms

verfasst von: A. I. Moral-Rodríguez, R. Leyva-Ramos, R. Ocampo-Pérez, J. Mendoza-Barron, I. N. Serratos-Alvarez, J. J. Salazar-Rabago

Erschienen in: Adsorption | Ausgabe 1/2016

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Abstract

The equilibrium and intraparticle diffusion of ronidazole (RNZ) and sulfamethoxazole (SMX) during the adsorption on granular activated carbon (GAC) from aqueous solution was investigated in this work. The solution pH, temperature, ionic strength and water matrix affected the adsorption capacity of GAC towards SMX, but no effect was observed for the adsorption of RNZ. This behavior was due to the different mechanism involved in the adsorption of both antibiotics. The adsorption capacity of GAC towards RNZ was greater than that towards SMX. Molecular computation allowed the estimation of the binding free energy and confirmed that the adsorption of RNZ was more favorable than the adsorption of SMX. The adsorption mechanism of both antibiotics is governed by π–π dispersive interactions, and molecular simulation demonstrated that the coulombic interactions did not affect, but the solvation and nonpolar interactions play a significant role on the adsorption of both antibiotics. The application of diffusional models revealed that the overall adsorption rate of both antibiotics is controlled by intraparticle diffusion. Moreover, the surface diffusion was more predominant than the pore volume diffusion. Besides, surface diffusion coefficient, D_s, for RNZ was not a function of the aqueous matrix, whereas D_s for SMX was highly dependent on the water matrix.

Vorheriger Artikel Effect of the addition of a second phenol on the textural properties of carbon aerogels

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Titel: Removal of ronidazole and sulfamethoxazole from water solutions by adsorption on granular activated carbon: equilibrium and intraparticle diffusion mechanisms
verfasst von: A. I. Moral-Rodríguez
R. Leyva-Ramos
R. Ocampo-Pérez
J. Mendoza-Barron
I. N. Serratos-Alvarez
J. J. Salazar-Rabago
Publikationsdatum: 12.01.2016
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 1/2016
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-016-9758-0

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