Introduction
Systems | Compositions | Tc (°C) | d33 (pC/N) |
K
| References |
---|---|---|---|---|---|
BaTiO3
| BT | 130 | 140 | 1400 | [121] |
BNT | (Bi0.5Na0.5)TiO3
| 310 | 64 | 302.6 | [60] |
BNT–BT | (Na0.5Bi0.5)0.92Ba0.08TiO3
| 280 | 125 | 625 | [28] |
BNT–BT–Nb2O5
| (Na0.5Bi0.5)0.92Ba0.08TiO3 + xNb2O5
| 250 | 149 | 1230 | [47] |
BNT–BT–CeO2 + La2O3
| (Na0.5Bi0.5)0.94–6BaTiO3 + 0.5 mol% CeO2 + 0.5 mol% La2O3
| – | 162 | 831 | [28] |
BNT–BT–MnCO3
| (Na0.5Bi0.5)0.92–Ba0.08TiO3 + x mol% MnCO3
| 243 | 160 | – | [52] |
BKT–BT–MnCO3
| 174 | 117 | 2300 | [10] | |
BNT–BK–BT | (Bi0.5Na0.5)TiO3–(Bi0.5K0.5)TiO3–BaTiO3
(1–3x)BNT–2xBKT–BT | 125 | 150 | – | [65] |
BNT–BZT | (Bi0.5Na0.5)TiO3–Ba(Ti,Zr)O3
| 244 | 147 | 8814 | [60] |
BNT–BKT–SrTiO3
| Bi0.5(Na0.84K0.16)0.5TiO3 + xSrTiO3
| 292 | 185 | 868 | [57] |
BNKLi–BT | Bi1–z(Na1–x–y–zKxLiy)]0.5BazTiO3
| 210 | 205 | 1040 | [27] |
(BN–x/y/z) BN–0.15/0.075/0.02 | |||||
(K,Na)NbO3
| (K0.5Na0.5)1–2yAEyNbO3
AE = Mg, Ca, Sr, Ba | 400 | 95 | 500 | [109] |
Toxic effects of lead
Mild | Moderate | Severe |
---|---|---|
Lethargy | Anemia | Convulsions |
Anorexia | Headache | Coma |
Abdominal discomfort | Abdominal cramps | Encephalopathy |
Arthralgia | Gingival lead line | Renal failure |
Peripheral neuropathy (motor) |
Perovskite-structured lead-free ferroelectrics
BaTiO3 system
BaTiO3 and (Bi0.5K0.5)TiO3 system
(Bi1/2Na1/2)TiO3 system
Effect of dopants on BNT ceramics
Effect of La2O3
Composition | d33 (pC/N) | Tan δ (%) |
K
| Tc (°C) | References |
---|---|---|---|---|---|
(Bi0.5Na0.5)(1–1.5x)LaxTiO3
| 92 | 0.04 | 560 | [42] | |
x = (0–0.6 mol%) | |||||
x = 1 | 80 | 0.015 | 375 | 370 | |
x = 1.72 | 91 | 0.04 | 550 | 345 | |
x = 2 | 89 | 0.033 | 495 | 335 | |
x = 3 | – | 0.036 | 770 | 365 | |
(Bi0.5Na0.5)TiO3–NaNbO3
| [30] | ||||
x = 0.01 | 80 | 5.60 | 637 | – | |
x = 0.02 | 88 | 5.90 | 624 | – | |
x = 0.03 | 60 | 5.96 | 754 | – | |
x = 0.04 | 50 | 6.26 | 753 | – | |
x = 0.05 | 32 | 5.40 | 801 | – |
Effect of NaNbO3
Effect of BaTiO3
Composition | d33 (pC/N) | Tan δ (%) |
K
| Tc (°C) | References |
---|---|---|---|---|---|
(Na0.5Bi0.5)0.94Ba0.06TiO3
| 125 | 1.3 | 625 | 288 | [26] |
(Na0.5Bi0.5)0.92Ba0.08TiO3
| 125 | – | – | 280 | [52] |
(1–x)(Na0.5Bi0.5)TiO3–x BaTiO3
| [47] | ||||
x = 0.02 | 78 | 1.73 | 402 | – | |
x = 0.04 | 87 | 2.07 | 445 | – | |
x = 0.06 | 122 | 1.79 | 601 | – | |
x = 0.08 | 112 | 2.04 | 841 | – | |
x = 0.1 | 94 | 2.39 | 764 | – | |
(Na0.5Bi0.5)TiO3–6BaTiO3
| 117 | 2.5 | 776 | – | [49] |
Effect of Bi2O3 · Sc2O3
Composition | d33 (pC/N) | Tan δ (%) |
K
| Tc (°C) | References |
---|---|---|---|---|---|
(Bi0.51Na0.49)Sc0.02Ti0.98O3
| 74.7 | 5.11 | 431 | 358 | [50] |
Effect of La, Nb, Co
Composition | Density (g/cc) | d33 (pC/N) | Tan δ (%) |
K
| Tc (°C) | References |
---|---|---|---|---|---|---|
(Na0.5Bi0.5)0.92Ba0.08TiO3 + xNb2O5 (NBBT83) |
–
| 149 | 3.90 | 1230 | 250 | [47] |
(Na0.5Bi0.5)0.92–xBa0.08TiO3 + xCo2O3 (NBBT84) |
–
| 108 | 1.50 | 450 | 245 | |
(Na0.5Bi0.5)TiO3–6BaTiO3 + La(BNBT6) + La |
–
| 125 | 4.5 | 1576 | – | [49] |
(Na0.5Bi0.5)TiO3–6BaTiO3 + Nb (BNBT6) + Nb |
–
| 118 | 4.6 | 1614 | – | |
(Na0.5Bi0.5)TiO3–6BaTiO3 + La–Co (BNBT6) + La–Co |
–
| 127 | 2.1 | 1284 | – | |
(Na0.5Bi0.5)TiO3–6BaTiO3 + La–Nb (BNBT6) + La–Nb |
–
| 135 | 2.3 | 1664 | – | |
(Na0.5Bi0.5)TiO3–6BaTiO3 + Co (BNBT6) + Co | – | 139 | 2.3 | 1200 |
–
| |
(Na0.5Bi0.5)0.94–6BaTiO3 + 0.5 mol% CeO2 + 0.25 mol% La2O3
| 5.67 | 158 | 1.7 | 787 | – | [28] |
(Na0.5Bi0.5)0.94–6BaTiO3 + 0.5 mol% CeO2 + 0.5 mol% La2O3
| 5.68 | 162 | 2.0 | 831 | – | |
(Na0.5Bi0.5)0.94–6BaTiO3 + 0.5 mol% CeO2 + 0.75 mol% La2O3
| 5.69 | 65 | 2.4 | 310 | – | |
(Na0.5Bi0.5)0.92–Ba0.08TiO3 + x mol% MnCO3
| – | 160 | – | – | 243 | [52] |
Effect of La2O3 and CeO2
Effect of Mn
Bi0.5(Na0.5,K0.5)TiO3 system
Effect of Strontium (Sr)
Effect of NaNbO3
BNT–Ba(Ti,Zr)O3 system
Bi(Na,K,Li)TiO3 system
Composition | d33 (pC/N) | Tan δ (%) |
K
| References |
---|---|---|---|---|
[Bi0.5(Na1–x–yKxLiy)0.5]TiO3
| [61] | |||
[Bi0.5(Na0.6K0.35Li0.05)0.5]TiO3
| 120 | 5.7 | 1753 | [61] |
[Bi0.5(Na0.7K0.25Li0.05)0.5]TiO3
| 145 | 4.1 | 1276 | [61] |
[Bi0.5(Na0.65K0.25Li0.1)0.5]TiO3
| 100 | 4.9 | 1109 | [61] |
[Bi0.5(Na0.7K0.15Li0.15)0.5]TiO3
| 41 | – | 1179 | [62] |
[Bi0.5(Na0.75K0.05Li0.2)0.5]TiO3
| 51 | – | 800 | [62] |
Composition | d33 (pC/N) | Tan δ(%) |
K
| References |
---|---|---|---|---|
Bi1–z(Na1–x–y–zKxLiy)]5BazTiO3(BN−x/y/z)
| [27] | |||
BN–0.15/0.10/0.02 | 198 | 3.7 | 1170 | |
BN–0.15/0.075/0.02 | 205 | 3.4 | 1040 | |
BN–0.15/0.075/0.01 | 178 | 3.1 | 735 | |
BN–0.10/0.075/0.01 | 130 | 2.1 | 550 |
BNT–BKT–BT system
Alkali niobates
KNbO3-based ceramics
KNbO3–NaNbO3 system
Processing methods | Density (g/cc) | % TD | d33 (pC/N) |
k
p
|
---|---|---|---|---|
Air-sintered (Jaeger–Egerton) K0.5Na0.5NbO3
| 4.25 | 94.24 | 80 | 0.36 |
Air-sintered (Kosec) K0.5Na0.5NbO3
| 4.20 | 93.13 |
–
| 0.23 |
Air-sintered H. (Birol) K0.5Na0.5NbO3
| 4.30 | 95.3 | 110 | 0.39 |
Hot-pressed (Jaeger–Egerton) K0.5Na0.5NbO3
| 4.46 | 98.89 | 160 | 0.45 |
Hot-forged (Schultze) K0.5Na0.5NbO3 + 4 mol% Ba | 4.28 | 94.90 | 115 | 0.37 |
Reactive grain growth (Saito et al.) |
–
|
–
| 416 |
–
|